全文获取类型
收费全文 | 1974篇 |
免费 | 456篇 |
国内免费 | 198篇 |
专业分类
化学 | 549篇 |
晶体学 | 16篇 |
力学 | 305篇 |
综合类 | 19篇 |
数学 | 241篇 |
物理学 | 1498篇 |
出版年
2024年 | 6篇 |
2023年 | 21篇 |
2022年 | 45篇 |
2021年 | 44篇 |
2020年 | 63篇 |
2019年 | 43篇 |
2018年 | 54篇 |
2017年 | 74篇 |
2016年 | 77篇 |
2015年 | 57篇 |
2014年 | 83篇 |
2013年 | 155篇 |
2012年 | 101篇 |
2011年 | 110篇 |
2010年 | 107篇 |
2009年 | 131篇 |
2008年 | 133篇 |
2007年 | 134篇 |
2006年 | 125篇 |
2005年 | 105篇 |
2004年 | 136篇 |
2003年 | 131篇 |
2002年 | 97篇 |
2001年 | 84篇 |
2000年 | 87篇 |
1999年 | 63篇 |
1998年 | 83篇 |
1997年 | 46篇 |
1996年 | 39篇 |
1995年 | 33篇 |
1994年 | 35篇 |
1993年 | 24篇 |
1992年 | 19篇 |
1991年 | 12篇 |
1990年 | 10篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1987年 | 6篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 1篇 |
排序方式: 共有2628条查询结果,搜索用时 31 毫秒
1.
Dr. Zaifa Shi Dr. Yihuang Jiang Dr. Jingxiong Yu Prof. Shanjun Chen Prof. Jun Chen Prof. Zichao Tang Prof. Lansun Zheng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(8):e202103546
At present, the reactivity of cyclic alkanes is estimated by comparison with acyclic hydrocarbons. Due to the difference in the structure of cycloalkanes and acycloalkanes, the thermodynamic data obtained by analogy are not applicable. In this study, a molecular beam sampling vacuum ultraviolet photoionization time-of-flight mass spectrometer (MB-VUV-PI-TOFMS) was applied to study the low-temperature oxidation of cyclopentane (CPT) at a total pressure range from 1–3 atm and low-temperature range between 500 and 800 K. Low-temperature reaction products including cyclic olefins, cyclic ethers, and highly oxygenated intermediates (e. g., ketohydroperoxide KHP, keto-dihydroperoxide KDHP, olefinic hydroperoxides OHP and ketone structure products) were observed. Further investigation of the oxidation of CPT – electronic structure calculations – were carried out at the UCCSD(T)-F12a/aug-cc-pVDZ//B3LYP/6-31+ G(d,p) level to explore the reactivity of O2 molecules adding sequentially to cyclopentyl radicals. Experimental and theoretical observations showed that the dominant product channel in the reaction of CPT radicals with O2 is HO2 elimination yielding cyclopentene. The pathways of second and third O2 addition – the dissociation of hydroperoxide – were further confirmed. The results of this study will develop the low-temperature oxidation mechanism of CPT, which can be used for future research on accurately simulating the combustion process of CPT. 相似文献
2.
采用Cundari和Stevens等推导的有效芯势对镧系金属一氢化物进行了理论计算,以探讨镧系金属元素与氢的相互作用。结果表明所有镧系金属一氢化物基态时理论上是稳定的,最稳定的是SmH,最不稳定的是DyH;键长计算结果显示,基态时镧系金属一招兵买马花物有独立王国 收缩现象发生;红外振动频率理论计算值与实验结果一致;成键轨道中,金属原子轨道的贡献主要是s轨道和d轨道:从CeH至ErH(GdH)例外)随着外层电子的增加s轨道成分逐渐增大d轨道成分逐渐减小;从TmH和LuH(包括GdH),成键轨道中金属原子轨道的贡献主要是d轨道,约为90%;约大多数镧系金属一氧化物的成键轨道中金属原子轨道f成分小于1%。 相似文献
3.
4.
K. Batra V. Prasad M. Mohan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(2):191-198
The scattering of heavy ion with a multilevel Rydberg atom in the presence of an electromagnetic field is studied. The interaction
of Rydberg atom and the e.m field is explored using non-perturbative quasi-energy technique. Although the results are presented
for selected excitations but in actual calculations we have included many levels of the atom. The effect of various parameters
are shown on collisional excitation process. As an illustration detailed calculations are performed for the inelastic proton-Na
Rydberg atom collision accompanied by the transfer of photons and the effects of dressing due to the field are considered.
The emphasis of the present work is on collision induced transitions especially the case that involves change of orbital as
well as principal quantum number.
Received 26 December 2001 / Received in final form 8 April 2002 Published online 19 July 2002 相似文献
5.
6.
研究了Yb3 掺杂铝氟磷酸盐 (AFP)玻璃的吸收光谱、荧光光谱 ,测量了Yb3 离子的荧光有效线宽 (Δλeff>5 5nm)以及2 F5 2 能级的荧光寿命 (τmax=2ms)及随掺杂浓度的变化 .应用倒易法计算了Yb3 的发射截面 ,其发射截面可达 0 6 6 82 3pm2 ,且激光增益系数τfσemi达 1 2 89ms.pm2 .评估了Yb3 在AFP玻璃中的激光性能 ,发现其具有较理想的激发态最小粒子数 (0 15 )、饱和抽运强度 (8 3kW cm2 )和最小抽运强度 (1 2 4 5kW cm2 )值及良好的热稳定性 .研究结果表明掺Yb3 氟磷酸盐玻璃是实现高功率超短可调谐激光器的理想增益介质 . 相似文献
7.
By constructing close-one-cochain density Ω^12n in the gauge group space we get the Wess-Zumino-Witten (WZW) effective Lagrangian on high-dimensional noncommutative space.Especially consistent anomalies derived from this WZW effective action in noncommutative four-dimensional space coincide with those obtained by L.Bonora etc.(het-th/0002210). 相似文献
8.
An effective residual interaction between particles and holes for shell model calculations around 208Pb, derived from the interaction between free nucleons, is compared with the measured properties of proton-hole neutron states
in 208Tl and the interaction between proton holes is adjusted to newly measured level energies in 206Hg. These interaction elements are particularly relevant for neutron-rich nuclei. The adjustment of two mixing elements reproduces
the known γ-decay data in 208Tl.
Received: 2 April 2002 / Accepted: 2 May 2002 相似文献
9.
G. Carelli N. Ioli A. Messina A. Moretti S. Schepis F. Strumia 《International Journal of Infrared and Millimeter Waves》1998,19(9):1191-1199
We measured the dependence of the reflectivity of InSb crystals upon temperature in the submillimeter region using monochromatic radiation from an optically pumped far infrared (FIR) laser. The measures allowed us to determine the value of the electron effective mass at low temperatures with radiations of different frequencies. Our measurements extend the results obtained recently on pure crystals with magneto-optical methods to the low temperatures region where only old measures were available. 相似文献
10.
We study the propagation of the light mesons σ,ω,ρ, and a0(980) in dense hadronic matter in an extended derivative scalar coupling model. Within the scheme proposed it is possible
to unambiguously define effective density-dependent couplings at the Lagrangian level. We first apply the model to study asymmetric
nuclear matter with fixed isospin asymmetry, and then we pay particular attention to hypermatter in β-equilibrium. The equation
of state and the potential contribution to the symmetry coefficient arising from the mean-field approximation are investigated.
Received: 16 October 2001 / Accepted: 10 January 2002 相似文献