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标题化合物二乙胺合三(5-甲基-2-苯并噻唑基)硼烷(C28H29BN4S3(Mr=527.57)的晶体属于三斜晶系,空间群为P1,晶胞参数a=0.397(8)nm,b=1.1742(6)nm,c=1.3100(2)nm,α=104.29(2)°,β=92.99(3)°,γ=98.58(5)°,V=1.3790nm3,Z=2,Dc=1.270g/cm3,μ(MoKα)=2.804cm-1.结构的偏离因子R=0.0648,Rw=0.0737.结构测定表明,甲基取代基的电子效应导致硼碳键键长的平均化,预示杂环对硼原子的π-电子反馈与胺基氮原子对硼原子的反馈有彼消此长的关系. 相似文献
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S. P. Gromov A. I. Vedernikov Yu. V. Fedorov O. A. Fedorova E. N. Andryukhina N. E. Shepel' Yu. A. Strelenko D. Johnels U. Edlund J. Saltiel M. V. Alfimov 《Russian Chemical Bulletin》2005,54(7):1569-1579
In the presence of Ba2+ ions, (benzothiazolyl)ethenylbenzocrown ether forms the stable sandwich complex 2L⋅Ba2+ with an unusual structure, in which the benzothiazole fragments are arranged one above the other. Irradiation of the sandwich
complex with visible light induces stereoselective [2+2] cycloaddition giving rise to two “head-to-head” isomers of biscrown-cyclobutane.
The addition of dibasic dicarboxylic acids that additionally stabilize the sandwich complex in a favorable conformation affects
the isomer ratio of the cyclobutanes formed. The conformational equilibria for the sandwich complex and cyclobutanes were
studied by 1H NMR spectroscopy.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1524–1533, July, 2005. 相似文献
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The reactivity of polarized ketene dithioacetals to develop a variety of heterocycles under different conditions was studied. 相似文献
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