A novel design of a levoglucosenone derived chiral auxiliary

A two-step general approach to a new chiral auxiliary starting from levoglucosenone is reported. The compound is obtained by a [4+2] cycloaddition reaction with anthracene followed by a diastereoselective reduction of the C-2 keto function in high overall yield. The auxiliary has been used as chiral template in an asymmetric Diels-Alder reaction of the corresponding acrylic ester derivative with cyclopentadiene and shown to be efficient for asymmetric induction.     

On the Application of the Auxiliary Problem Principle

The auxiliary problem principle (APP) derives from a general theory on decomposition-coordination methods establishing a comprehensive framework for both one-level and two-level methods. In this paper, the results of the two-level methods of APP are specialized for an efficient application to some engineering problems.     

利用全息扫描技术实现条码识别

根据条码识别装置的特点，利用全息扫描技术设计条形码扫描器及相应的辅助部件，从而使学生对全息照相及扫描技术有进一步的理解，掌握物理实验设计的一般要求。     

On General Mixed Quasivariational Inequalities

In this paper, we suggest and analyze several iterative methods for solving general mixed quasivariational inequalities by using the technique of updating the solution and the auxiliary principle. It is shown that the convergence of these methods requires either the pseudomonotonicity or the partially relaxed strong monotonicity of the operator. Proofs of convergence is very simple. Our new methods differ from the existing methods for solving various classes of variational inequalities and related optimization problems. Various special cases are also discussed.     

双曲函数型辅助方程构造具5次强非线性项的波方程的新精确孤波解

在辅助方程法的基础上利用两种函数变换和一种双曲函数型辅助方程，通过符号计算系统Mathematica构造了在力学当中一个重要的模型，有5次强非线性项的波方程的新三角函数型和双曲函数型精确孤波解.这种方法寻找其他具5次强非线性项的非线性发展方程的新精确解方面具有普遍意义. 关键词： 双曲函数型辅助方程 函数变换 具5次强非线性项的波方程 精确孤波解     

Fractional extensions of some boundary value problems in oil strata

In the present paper, we solve three boundary value problems related to the temperature field in oil strata — the fractional extensions of the incomplete lumped formulation and lumped formulation in the linear case and the fractional generalization of the incomplete lumped formulation in the radial case. By using the Caputo differintegral operator and the Laplace transform, the solutions are obtained in integral forms where the integrand is expressed in terms of the convolution of some auxiliary functions of Wright function type. A generalization of the Laplace transform convolution theorem, known as Efros’ theorem is widely used.     

充分发挥计算机辅助教学作用

本文就计算机在物理实验方面的辅助教学进行了较为深刻的研究和探索，并提出可行性的方案。     

Diastereoselective Three Component Reaction of N‐Glyoxyloyl Camphorpyrazolidinone,Amine and Allyltributylstannane: Facile Synthesis of Homoallylic Amines

Diastereoselective allylation of imine derived from N‐glyoxyloyl camphorpyrazolidinone and amines was treated with allyltributylstannane in the presence of triflic acid. The corresponding optically enriched homoallylic amines were obtained in reasonable to high material yields and with practical levels of stereoselectivity in 10 min at ambient temperature.     

新的手性配体促进的二芳基二酸和联萘酚的不对称合成

由手性配体α-D-葡萄糖衍生物5，6，7以及薄荷醇（8）和葑醇（9），经 Ulmann偶联反应得到光学活性的（R）－和（S）－6，6′－二硝基联苯－2，2′－ 二甲酸（4a),(R)-6,6′-二甲基联苯－2，2′-二甲酸（4b),(R)-1,1′－联萘－2 ，2′－二甲酸（13）。以三个手性膦酰胺16，17，18和CuCl组成的手性络合物为 催化剂，通过2－萘酚直接氧化偶联得到（S）－2，2′－联萘酚（15）。产物4， 13，15具有中等ee值的光学活性。