适用于RTM成型聚酰亚胺材料研究进展

综述了适用于RTM成型耐高温聚酰亚胺材料的研究进展，主要包括降冰片烯酸酐（NA）封端的PMR聚酰亚胺树脂和使用苯乙炔基封端剂合成的酰亚胺低聚物，在这其中采用苯乙炔基封端剂合成的酰亚胺低聚物具有低的熔体粘度和良好的熔体稳定性，固化交联后的聚合物及树脂基复合材料具有良好的热性能和力学性能。本文介绍了上述聚合物化学合成、结构与性能之间的关系，并对适用于RTM成型耐高温聚酰亚胺材料的应用进行了简单介绍。     

Effects of atomic-scale contacts on transport properties through single molecules - ab initio study

Using the RTM/NEGF method, which is a first-principles calculation tool for the quantum transport through nanostructures between electrodes, we study the effects of atomic-scale contacts on the transport properties through single molecules. Electronic states and current-voltage (I-V) characteristics are investigated in various contact conditions with and without single molecules between electrodes. We find that similar nonlinear behaviors appear in the I-V characteristics. Such nonlinear behaviors are determined not only by the HOMO-LUMO electronic states of single molecules between electrodes, but also by the atomic-scale contact conditions. We show that the transitions from tunneling to ballistic regimes affect the I-V characteristics significantly.     

Chemorheology and Curing Kinetics of a New RTM Benzoxazine Resin

The chemorheology and curing kinetics of a new high performance resin transfer molding benzoxazine resin was investigated. A chemorheological model based on a modified Arrhenius equation that describes the resin viscosity as a function of temperature and time was proposed. The model, which agreed well with the experimental data, can provide theoretical support for the mold-filling stage in the resin transfer molding process. The average activation energies of the polymerization reaction were obtained by means of gelation times at different temperatures based on the Arrhenius equation and from dynamic differential scanning calorimetry (DSC) results based on the Kissinger and Ozawa methods; the values were 96.0,84.0 and 87.8 KJ/mol, respectively. A plot of activation energy vs. conversion in the curing process was obtained using the Flynn-Wall-Ozawa model. The reaction orders were estimated from isothermal DSC based on a modified Kamal kinetics model which can describe both the autocatalytic and diffusion-controlled curing mechanism.     

Theory for electron hopping through nanometer-scale contacts: From tunneling regime to ballistic regime

Using the recursion-transfer-matrix (RTM) method combined with nonequilibrium Green's function (NEGF) method, we study the electronic states and current–voltage (I–V) characteristics of junction systems with atomic-scale nanocontacts as a function of the distance between electrodes. We observe a strong nonlinear behavior in the I–V characteristics and correspondingly a gap structure appears in conductance. We find that such a nonlinear behavior emerges when the transport properties change from tunneling to ballistic regimes.     

The SC property of an expected residual function arising from stochastic complementarity problems

The stochastic nonlinear complementarity problem has been recently reformulated as an expected residual minimization problem which minimizes an expected residual function defined by an NCP function. In this work, we show that the expected residual function defined by the Fischer–Burmeister function is an RTM2SW-1-11/0?wchp=dGLzVlz-zSkzV" alt="View the MathML source" title="View the MathML source" align="absbottom" border="0" height=13 width="24"/> function.     

Smoothed Particle Hydrodynamics Modeling of Transverse Flow in Randomly Aligned Fibrous Porous Media

The Lagrangian smoothed particle hydrodynamics (SPH) method is employed to obtain a meso-/micro-scopic pore-scale insight into the transverse flow across the randomly aligned fibrous porous media in a 2D domain. Fluid is driven by an external body force, and a square domain with periodic boundary conditions imposed at both the streamwise and transverse flow direction is assumed. The porous matrix is established by randomly embedding a certain number of fibers in the square domain. Fibers are represented by position-fixed SPH particles, which exert viscous forces upon, and contribute to the density variations of, the nearby fluid particles. An additional repulsive force, similar in form to the 12-6 Lennard-Jones potential between atoms, is introduced to consider the no-penetrating restraint prescribed by the solid pore structure. This force is initiated from the fixed solid material particle and may act on its neighboring moving fluid particles. Fluid flow is visualized by plotting the local velocity vector field; the meandering fluid flow around the porous microstructures always follow the paths of least resistance. The simulated steady-state flow field is further used to calculate the macroscopic permeability. The dimensionless permeability (normalized by the squared characteristic dimension of the fiber cross section) exhibits an exponential dependence on the porosity within the intermediate porosity range, and the derived dimensionless permeability—porosity relation is found to have only minor dependence on either the relative arrangement condition among fibers or the fiber cross section (shape or area).     

RTM充模分析的隐式控制体积法及其迭代方法

RTM充模分析的隐式方法需要迭代来决定树脂注满的区域。为了改善隐式方法的迭代过程,在本文中提出了一种基于界面更新的隐式方法。该方法只对已注满结点进行求解,然后更新界面结点的体积函数以便决定是否要更新界面。采用不同求解方法对该方法进行了试算。计算表明了本文的方法性能良好,计算速度比显式方法有明显改进。     

Novel high performance RTM bismaleimide resin with low cure temperature for advanced composites

A novel performance matrix, coded as LCRTM, with low cure and post‐cure temperature (≤ 200°C) for fabricating advanced polymer composites via resin transfer molding (RTM), was successfully developed, made up of 4,4′‐bismaleimidodiphenylmethane (BDM) and N‐allyl diaminodiphenylether (ADDE). Investigations show that the stoichiometry of BDM and ADDE has great effect on the processing and performance parameters of the resultant resins. In the case of the optimum formulation (the mole ratio of BDM and ADDE is 1:0.55), the injection temperature range is between 70–82°C, and the pot life at 80°C is 300 min, moreover, the cured resin has desirable thermal and mechanical properties after being cured at 200°C for 6 hr, reflecting a great potential as high performance matrices for fabricating advanced composites via the RTM technique. Copyright © 2005 John Wiley & Sons, Ltd.     

Effect of Layering Pattern on the Mechanical Properties of Bark Cloth (Ficus natalensis) Epoxy Composites

The quest for sustainable materials as a consequence of a global drive to mitigate climate change has led to a focus on natural fiber–reinforced composite materials. In this study, skillful ply angle arrangement of bark cloth–reinforced laminar epoxy composites was carried out for the first time using vacuum-assisted resin transfer molding, and the composites fabricated were characterized for the effect of the layering pattern on their static and dynamic mechanical properties. Tensile strength and flexural strength were shown to be dependent on the ply angle arrangement. Dynamic mechanical analysis of the composites showed a glass transition temperature of 70°C, and the storage modulus and mechanical damping properties showed that the developed composites can withstand considerable loads and have excellent fiber-to-matrix adhesion.     

Induction technique in manufacturing preforms

The prepreg technology is a state-of-the-art method to produce high-performance CFRP parts. Due to the high material prices, the restricted process rate, and limitations to the component complexity, in future, more and more parts will be assembled by using liquid composite moulding. Especially in the case of series larger than 100 parts per year, the LCM technology offers the best cost-effectiveness. This technology is based on resin injection into dry multilayer fibre textiles (preforms). The Institute of Joining and Welding (TU, Braunschweig), together with the Institute of Composite Structures and Adaptive Systems (DLR), has elaborated a new technology to speed up the preform process, which is the most labour-intensive step within the LCM process chain. A novel concept to consolidate binder-coated fabrics is under development. By applying the high energy transfer rate of induction technology, it is possible to heat up a preform with rates up to 50 K/s to melt the binder and consolidate the preform. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 44, No. 5, pp. 747–756, September–October, 2008.