Ultraviolet Luminescence in Mg0.12Zn0.88O Alloy Films

We investigate the origin of ultraviolet （UV） emission from Mg0.12 Zn0.88 O alloy thin films with a wurtzite structure fabricated on c-plane Al2O3 substrates by plasma assisted molecular beam epitaxy. At room temperature, the absorption edge and UV emission band of the Mg0.12Zn0.88O film shift to high-energy side compared with ZnO films. Temperature dependence of the photoluminescence spectra shows that the UV emission is composed of free exciton and neutral donor bound exciton emissions. Two-step dissociation processes of the UV emission are observed with the increasing temperature. The thermal quenching mechanism is attributed to the dissociation of the free exciton from the neutral donor bound exciton in the low temperature region and the dissociation of free electron and hole from the free exciton in the high temperature region.     

防紫外线伞ATR-OMNI采样器的FTIR分析

本实验使用OMNI采样器，直接对伞面内外进行单反射ATR的分析，快速、简便、不破坏样品，得到分辨率很好的红外图谱，再配合红外谱库的谱图检索，可以分别得到匹配率95％以上的尼龙－6和聚酯型聚氨酯的分析结果。     

低能N+离子注入对加工番茄的辐照效应

本研究以87-5制罐番茄种子为处理材料,用N 离子作为诱变源,以35keV的能量,分别以20次、40次、50次、60次脉冲,注入剂量2×1016N /cm2、4×1016N /cm2、6×1016N /cm2、10×1016N /cm2进行激发诱变,变异显著.表现为出苗率降低,座果提前.在果实的品质性状变化不大情况下,座果数明显增加,部分处理材料的产量明显提高.     

生物物理学的医用发展

 生物物理,特别是生物物理材料的医用研究,近年来在国际医用科学界形成了一个特别值得注意的热潮。人们越来越认识到,从医用科学的角度来看,生物与物理的结合是一个正待发掘的宝藏。这是一个新的交叉领域,充满挑战性又富有机会。人们已经用生物物理材料制作除大脑以外的几乎所有组织和器官用于医疗。目前,在富有挑战性的仿生、智能材料及组织工程材料的研究方向上,都在丰富生物医用材料的内容,而在这一领域的研究应用中,也不乏有许多自然科学的哲学问题。生物物理医用材料技术的兴起和发展的内外部因素生物物理何以在20世纪60～70年代崛起并得到迅猛的发展呢?     

Eu^2＋：BaFCl光激励发光过程中紫外线的激发与漂白效应

通过改变紫外线的辐射照能量范围，研究了Ｅｕ＾２＋：ＢａＦＣｌ的光激励发光性质。发现紫外线能量大于Ｅｕ＾２＋的最低激发态能量及紫外线的能量小于Ｅｕ＾２＋最低激发态的能量两种情况下，光激励发光具有明显的差异，分析了产生差异的原因，给出了紫外线的辐照能量发生转时所对应的能级位置。     

3,4,5-三甲氧基苯甲酰甲壳素的制备与表征

在甲磺酸体系中，将具有较好紫外吸收性能的3，4，5—三甲氧基苯甲酸分子键接到甲壳素的分子链上，制得了3，4，5—三甲氧基苯甲酰甲壳素。采用红外光谱、^1H-NMR、广角X—射线衍射、紫外光谱等表征方法对改性产物进行了结构表征。通过对改性产物的紫外光谱表征发现产物具有一定的吸收紫外线能力。产物在有机溶剂中有一定的溶解性能。     

Determination of Tetracyclines in Honey Using Liquid Chromatography with Ultraviolet Absorbance Detection and Residue Confirmation by Mass Spectrometry

A determination method has been optimized and validated for the simultaneous analysis of tetracycline （TC）, oxytetracycline （OTC）, chlortetracycline （CTC） and doxycycline （DC） in honey. Tetracyclines （TCs） were removed from honey samples by chelation with metal ions bound to small Chelating Sepharose Fast Flow columns and eluted with Na2EDTA-Mcllvaine pH 4.0 buffers. Extracts were further cleaned up by Oasis HLB solid-phase extraction （SPE）, while other solid-phase extraction cartridges were compared. Chromatographic separation was achieved using a polar end-capped C 18 column with an isocratic mobile phase consisting of oxalic acid, acetonitrile and methanol. LC with ultraviolet absorbance at 355 nm resulted in the quantitation of all four tetracycline residues from honey samples fortified at 15, 50, and 100 ng/g, with liner ranges for tetracyclines of 0.05 to 2 μg/mL. Mean recoveries for tetracyclines were greater than 50% with R.S.D. values less than 10% （n= 18）. Detection limits of 5, 5, 10, 10 ng/g for oxytetracycline, tetracycline, chlortetracycline and doxycycline, respectively and quantitation limits of 15 ng/g for all the four tetracyclines were determined. Direct confirmation of the four residues in honey （2-50 ng/g） was realized by liquid chromatography-tandem mass spectrometry （LC/MS/MS）. The linear ranges of tetracyclines determined by LC/MS/MS were between 5 to 300 ng/mL, with the linear correlation coefficient r〉 0.995. The limits of detection of 1 to 2 ng/g were obtained for the analysis of the TCs in honey.     

DNA Separation by Capillary Electrophoresis with Ultraviolet Detection using Mixed Synthetic Polymers

The mixtures of two polymers, poly (N,N-dimethylacrylamide) (PDMA) and polyvinylpyrrolidone (PVP) were synthesized and used as the separation medium for double-stranded and single-stranded DNA fragments by capillary electrophoresis with UV detector. On optimal conditions, 2%w/v PDMA 2%w/v PVP can be used to separate the doublet 123/124bp in pBR322/Hae Ⅲ Markers.     

紫外线激活氚原子—制备氚标记单磷酸阿糖腺苷的研究

本文采用紫外线激活氚原子的方法,进行氚-氢同位素交换反应,制得氚标记单磷酸阿糖腺苷(9—~3H—mparaA)。产品的纯度是层析纯;放射性比活度16GBq.m mol~(-1);放射化学纯度92.0%。本法的优点是:交换反应温和、反应时间较短、不易破坏生物活性、引起的副产物少、产品分离和纯化较方便。     

化妆品车间空气消毒方法效果比较

评价几种消毒方法对化妆品车间空气的消毒效果。分别使用紫外线照射消毒法、甲醛蒸熏消毒法、戊二醛消毒液气溶胶雾化消毒法、臭氧气体发生器消毒法4种方法进行消毒,然后用平皿沉降法进行采样评价分析,试验结果表明,戊二醛消毒法和臭氧消毒法可以代替紫外线消毒法和甲醛消毒法进行化妆品车间空气常规消毒。