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1.
Fabrication, Characterization and Electrocatalysis of an Ordered Carbon Nanotube Electrode 总被引:3,自引:0,他引:3
A method for fabrication of ordered carbon nanotube (CNT) film,which was template-synthesized within the highly ordered pores of a commercially available alumina template membrane,modified glassy carbon(CNT/GC) electrode was established.The CNT/GC electrode showed excellent electrocatalytic activity toward dopamine electrochemical reaction without introducing any electrochemically active group into CNT film or activating any electrochemically active group into CNT film or activating the electrode electrochemically.DA undergoes ideal reversible electrochemical reaction on CNT/GC electrode at low scan rate(≤20mV/s) with an excellent reproducibility and stability.The CNT/GC electrode might be used in biosensors because the highly ordered CNT may present a steric effect on more efficient redox reactions of biomolecules. 相似文献
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The constitutive equation under the low-cycle fatigue (LCF) was discussed, and a two-dimensional (2-D) model for simulating fatigue crack extension was put forward in order to propose a new cyclic J-integral. The definition, primary characteristics, physical interpretations and numerical evaluation of the new parameter were investigated in detail. Moreover, the new cyclic J-integral for LCF behaviors was validated by the compact tension (CT) specimens. Results show that the calculated values of the new parameter can correlate well with LCF crack growth rate, during constant-amplitude loading. In addition, the phenomenon of fatigue retardation was explained through the viewpoint of energy based on the concept of the new parameter. 相似文献
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STRUCTURAL DAMAGE MODEL OF UNSATURATED EXPANSIVE SOIL AND ITS APPLICATION IN MULTI-FIELD COUPLE ANALYSIS ON EXPANSIVE SOIL SLOPE 总被引:1,自引:0,他引:1
Focused on the sensitivity to climate change and the special mechanical characteristics of undisturbed expansive soil, an elastc-plastic damage constitutive model was proposed based on the mechanics of unsaturated soil and the mechanics of damage. Undisturbed expansive soil was considered as a compound of non-damaged part and damaged part. The behavior of the non-damaged part was described using non-linear constitutive model of unsaturated soil. The property of the damaged part was described using a damage evolution equation and two yield surfaces, i.e., loading yield (LY) and shear yield (SY). Furthermore, a consolidation model for unsaturated undisturbed expansive soil was established and a FEM program named UESEPDC was designed. Numerical analysis on solid-liquid-gas tri-phases and multi-field couple problem was conducted for four stages and fields of stress, displacement, pore water pressure, pore air pressure, water content, suction, and the damage region as well as plastic region in an expansive soil slope were obtained. 相似文献
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Euclid的《几何原本》同化学术语中的化学计量比都来自希腊语Στοιχεια■ο,反映的是古希腊原子论的精神. 相似文献
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年龄相关的种群系统的最优扩散控制 总被引:1,自引:0,他引:1
运用扰动方法研究了由积分-偏微分方程所描述的年龄相关的种群系统的最优扩散控制问题.首先,在证明了原系统及其扰动系统正则广义解存在唯一等预备结果的基础上,用先验估计和紧性定理,证明了系统最优扩散控制的存在性.其次,利用Gteax微分和变分不等式等理论,得到了控制为最优的必要条件和由偏微分方程与变分不等式所构成的最优性组,由最优性组确定最优控制. 相似文献
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在Poisson方程的求解域Ω存在一致的三角剖分,并且相邻两初始单元构成平行四边形的假设下,证明了若Poisson方程的解u属于H6(Ω),那么二次有限元的误差有h4的渐近展开.基于误差的渐近展开,可以利用h4-Richardson外推进一步提高数值解的精度阶,并且能够得到一个后验误差估计.最后,一个数值算例验证了理论分析. 相似文献
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Ordered ZnS semiconductor nanoparticles were in situ synthesized in metal halide perovskite organic/inorganic layered hybrids (CnH2n 1NH3)2ZnCl4 (n=10 and 12) by reaction of their spin-casting films with H2S gas. Transmission electron microscopy, UV-vis spectroscopy and small-angle X-ray diffraction were used to characterize the morphology and the structure of formed nanoparticles. Obtained results indicate an effective way to incorporate functional inorganic nanoparticles into structured organic matrices. 相似文献