低温硫钼复合渗镀工艺及其渗镀层的综合性能考察

本文首先阐述了低温硫钼复合渗镀方法的基本原理与工艺流程,接着又对硫钼复合渗镀层的物相组成和物理性能进行了测试与分析,并且着重就其减摩性能及抗粘着磨损性能与低温电解渗硫层的作了对比试验研究和讨论,最后还通过诸多例证综合说明了硫钼复合渗镀层的实用效果明显地比电解渗硫层的好。文章指出,由于这种渗镀层的物相组成主要是FeS和MoS_2等而具有良好的自润滑性能,故其特别在干摩擦条件下的摩擦学性能更佳。不仅如此,硫钼复合渗镀工艺还具有处理温度低、时间短、操作简便、无公害和成本低廉等优点,而且被处理零件无变形,尺寸变化可以控制在6μm左右,因而适用于精密零件和刀具的处理,应用前景相当广阔。     

Microstructure and tribological properties of WS2/MoS2 multilayer films

In this paper, a novel method, namely, magnetron sputtering and low temperature ion sulfurizing combined technique was used to fabricate the solid lubrication WS₂/MoS₂ multilayer films. Scanning Electron Microscopy (SEM) was used to observe the surface and worn scar morphologies. X-ray diffraction (XRD) was utilized to analyze the phase structure. The nano-hardness and elastic modulus of WS₂/MoS₂ multilayer films were surveyed by the nano-indentation tester. The friction and wear test were conducted on a ball-on-disk wear tester under dry sliding condition. The results obtained showed that the WS₂/MoS₂ multilayer films exhibited a lower friction coefficient and better wear-resistance when compared with single WS₂ film and original 1045 steel.     

Research on tribological behaviors of composite Zn/ZnS coating under dry condition

A composite Zn/ZnS coating was prepared by a novel compound technology-combining high velocity arc spraying and low temperature ion sulfurizing in this paper. The surface and cross-section morphologies were observed by scanning electron microscopy (SEM). The X-ray diffraction (XRD) pattern for the Zn/ZnS coating implies that it mainly consists of Zn and ZnS. The nanohardness and elastic modulus were measured by a nano-indentation tester. The tribological behaviors were investigated on a ball-on-disk wear tester under dry condition. The results showed that the friction coefficient and worn depth of the composite Zn/ZnS coating were low and stable, indicating that it had excellent friction-reduction and anti-wear properties under dry condition.     

Mo硫化物/Ti复合薄膜的制备及其环境摩擦磨损性能研究

采用高温硫化处理磁控溅射Mo/Ti金属前驱体薄膜制备Mo硫化物/Ti复合薄膜,采用X射线衍射仪、能谱仪和扫描电子显微镜对复合薄膜的组织结构、化学成分和表面形貌进行分析,采用涂层附着力自动划痕仪和可控气氛球-盘式摩擦磨损试验仪分别测试薄膜与基体的结合力以及摩擦系数,并用扫描电子显微镜观察薄膜的磨损表面形貌,分析其磨损机制.结果表明:硫化温度在450 ℃以上时能够生成较多Mo硫化物,最佳硫化工艺为450 ℃×15 h;提高硫化温度或延长硫化时间均使薄膜的结合力下降;磁控溅射Mo/Ti前驱体复合薄膜经450 ℃×15 h硫化处理后,薄膜中生成复杂的Mo硫化物,形成Mo硫化物/Ti复合薄膜;与纯Mo薄膜硫化后相比,Mo硫化物/Ti复合薄膜具有更高的界面结合力和更优异的摩擦磨损性能.     

连续离子层吸附反应沉积后硫化法制备柔性铜锌锡硫薄膜太阳电池

在柔性钼箔衬底上采用连续离子层吸附反应法(successive ionic layer absorption and reaction)制备ZnS/Cu2SnSx叠层结构的预制层薄膜,预制层薄膜在蒸发硫气氛、550 C温度条件下进行退火得到Cu2ZnSnS4吸收层.分别采用EDS,XRD,Raman,SEM表征吸收层薄膜的成分、物相和表面形貌.结果表明,退火后薄膜结晶质量良好,表面形貌致密.用在普通钠钙玻璃上采用相同工艺制备的CZTS薄膜表征薄膜的光学和电学性能,表明退火后薄膜带隙宽度为1.49 eV,在可见光区光吸收系数大于104cm 1,载流子浓度与电阻率均满足薄膜太阳电池器件对吸收层的要求.用上述柔性衬底上的吸收层制备Mo foil/CZTS/CdS/i-ZnO/ZnO:Al/Ag结构的薄膜太阳电池得到2.42%的效率,是目前报道柔性CZTS太阳电池最高效率.