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为实现较少试验次数下固化土无侧限抗压强度(qu)的准确预测, 提出了基于支持向量机(SVM)的固化土qu的预测模型. 以固化剂各组分掺入比、龄期、初始含水量、固化剂掺量等因素为输入量, 固化土的qu作为输出量, 以径向基为核函数, 采用网格搜索法和交叉验证法进行参数优化, 建立了基于SVM的固化土qu的预测模型. 算例分析表明: 该模型适用于任意条件下固化土qu的精确预测, 且在较小试验成本下实现与响应面法相当的预测精度. 相似文献
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在华南沿海地区的低矮丘陵及台地上,广泛发育一套黄色粉土堆积。对该区7个典型剖面进行系统的激光粒度分析,并与典型黄土以及研究区常见的海、河相沉积进行对比。结果表明,华南沿海各黄色粉土剖面均以10~50 μm的粗粉砂为众数粒组,<5 μm的粘粒为次众粒组,分别对应风成黄土的“基本粒组”和“挟持粒组”,岩性均属于粘土质粉砂。样品的粒度参数、粒度散点图、频率分布曲线、粒度指数特征均显示为典型的风成成因。粒度判别分析结果为负值,同样证实了黄色粉土的风成特性。华南沿海黄色粉土的各项粒度特征指标及其所反映的沉积类型、沉积环境均与我国典型黄土具有较好的可比性,而与研究区的海、河相沉积截然不同。 相似文献
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IntroductionTheshallowwaterequationsareanimportantmathematicalmodelforavarietyofprobleminhydraulicengineering .Inrecentyears,therehasbeeninterestinthenumericalsolutionfortheshallowwaterequations.Thenumericalsimulationsfortheshallowwaterequationsystemcanbeappliedtomanypurposes .First,itcanserveasameansformodelingtidalfluctuationsforthosenterestedincapturingtidalenergyforcommercialpurposes.Secondly ,thesesimulationscanbeusedtocomputetidalrangesandsurgessuchashurricanesandtsunamiscausedbyextreme… 相似文献
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Meghdad Pirsaheb Hiva Hosseini Hasan Mohamadi Sorkali Negar Noori 《International journal of environmental analytical chemistry》2019,99(2):112-123
In the present study, a new method for extraction and preconcentration of amoxicillin and ceftriaxone was used in hospitalised sewage samples, called vortex-assisted liquid-phase microextraction based on the solidification of deep eutectic solvent. Samples were analysed by high-performance liquid chromatography–ultraviolet detection after preparation and extraction. In this method, the new deep eutectic solvent is used as the extraction solvent, which is obtained from the combination of 1-decyl-3-methylimidazolium chloride and n-butanoic acid. The important advantages of this novel extraction solvent include material stability, low density and good freezing point near room temperature. Under the optimum conditions, enrichment factors are in the range of 164–172. Repeatability and reproducibility of the method based on seven replicate measurements of 50.0 µg L?1 of the target analytes in analysed samples were in the range of 2.1–3.5% and 3.8–5.2%, respectively. The limit of detections and linearity are in the range of 0.005–0.10 and 3–600 µg L?1, respectively. The method was successfully applied for the determination of amoxicillin and ceftriaxone in the real sewage samples. The relative recoveries of sewage samples spiked with amoxicillin and ceftriaxone are 91–107%. 相似文献
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Rapidly solidified nanocomposite Nd9Fe77−xB14Tix alloys, consisting of magnetic Nd2Fe14B phase and soft magnetic phases, were investigated. The effect of titanium addition on the structure and magnetic properties was studied. It was found that 2–4 at% Ti addition leads to substantial increase of the coercivity and maximum energy product, maintaining the remanence unchanged. The highest properties: Jr=0.81 T, JHc=907 kA/m, (BH)max=99 kJ/m3, were achieved for the Nd9Fe73B14Ti4 alloy. This effect we attribute to the formation of fine and homogeneous grain structure and a change of the phase morphology in the Ti-containing alloys. The initial magnetization curve indicates a change of the coercivity mechanisms giving rise to pinning of domain walls, which is caused by reduction of the crystallite size. 相似文献
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YUAN Zhi-Qing a Lü Guang-Lie a② WEI Fan-Song b LEI Yong-Quan b a 《结构化学》2004,23(5):520-524
Crystal structures of nonstoichiometric La(Ni, Sn)5 x (x = 0.1~0.4) alloysprepared by different methods were investigated by using powder X-ray diffraction and Rietveldrefinement analysis. Space group of this type of alloys belongs to P6/mmm, in which Sn onlyoccupies the 3g sites. It has been demonstrated that some of the la sites of the nonstoichiometricalloy are replaced by the Ni-Ni dumb-bells which have a strong correlation with the anisotropicthermal parameter B33. The preparation methods have an effect on the number of dumb-bells thatcan substitute the l a sites. It was found that the annealed alloys have more Ni-Ni dumb-bells inthe structure than the rapid solidified and as-cast alloys have while still keep good crystallinity. 相似文献
8.
Evolution of defects and deformation mechanisms in different tensile directions of solidified lamellar Ti-Al alloy
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Two-phase γ-TiAl/α2-Ti3Al lamellar intermetallics have attracted considerable attention because of their excellent strength and plasticity. However, the exact deformation mechanisms remain to be investigated. In this paper, a solidified lamellar Ti-Al alloy with lamellar orientation at 0°, 17°, and 73° with respect to the loading direction was stretched by utilizing molecular dynamics (MD) simulations. The results show that the mechanical properties of the sample are considerably influenced by solidified defects and tensile directions. The structure deformation and fracture were primarily attributed to an intrinsic stacking fault (ISF) accompanied by the nucleated Shockley dislocation, and the adjacent extrinsic stacking fault (ESF) and ISF formed by solidification tend to form large HCP structures during the tensile process loading at 73°. Moreover, cleavage cracking easily occurs on the γ/α2 interface under tensile deformation. The fracture loading mechanism at 17° is grain boundary slide whereas, at 73° and 0°, the dislocation piles up to form a dislocation junction. 相似文献
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Laura Bulgariu Dumitru Bulgariu Ioan Sârghie Theodor Măluṭan 《Central European Journal of Chemistry》2007,5(1):291-302
Cd(II) plus iodide species were extracted into PEG-rich phases in the aqueous PEG(1550)-(NH4)2SO4 system at pH 2.05–7.12. IR spectra show that increasing (NH4)2SO4 solution acidity does not protonate PEG ether oxygen atoms, but decreases water content in the PEG-rich phases. Metallic
species’ extraction into the PEG predominantly alters how water molecules bind to polymer chains; the changes in their absorption
bands depend on pH. Microscopy shows that “fixation” of the extracted metal in the PEG-rich phase occurs by specific interactions
which depend on the species. These also determine changes in the polymer chains’ conformation. 相似文献