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Dr. Saud Asif Ahmed Qiao-Bo Liao Qi Shen Dr. Mirza Muhammad Faran Ashraf Baig Juan Zhou Cai-Feng Shi Dr. Pir Muhammad Dr. Sumaira Hanif Prof. Kai Xi Prof. Xing-Hua Xia Prof. Kang Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(57):12996-13001
Layered/two-dimensional covalent organic frameworks (2D COF) are crystalline porous materials composed of light elements linked by strong covalent bonds. Interlayer force is one of the main factors directing the formation of a stacked layer structure, which plays a vital role in the stability, crystallinity, and porosity of layered COFs. The as-developed new way to modulate the interlayer force of imine-linked 2D TAPB-PDA-COF (TAPB = 1,3,5-tris(4-aminophenyl)benzene, PDA = terephthaldehyde) by only adjusting the pH of the solution. At alkaline and neutral pH, the pore size of the COF decreases from 34 Å due to the turbostratic effect. Under highly acidic conditions (pH 1), TAPB-PDA-COF shows a faster and stronger turbostratic effect, thus causing the 2D structure to exfoliate. This yields bulk quantities of an exfoliated few/single-layer 2D COF, which was well dispersed and displayed a clear Tyndall effect (TE). Furthermore, nanopipette-based electrochemical testing also confirms the slipping of layers with increase towards acidic pH. A model of pH-dependent layer slipping of TAPB-PDA-COF was proposed. This controllable pH-dependent change in the layer structure may open a new door for potential applications in controlled gas adsorption/desorption and drug loading/releasing. 相似文献
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Hiroshi Kimura Koichiro Aikawa Yuichi Masubuchi Jun-ichi Takimoto K. Koyama Keiji Minagawa 《Rheologica Acta》1998,37(1):54-60
The mechanism of the electrorheological (ER) effect in two types of liquid crystalline polymer (LCP)/dimethylsiloxane (DMS)
blends was investigated by rheological measurements and by structure observation under electric field and shear flow. The
results show that the phase structures of these immiscible blends can be categorized into slipping (low viscosity) and non-slipping
(high viscosity) states. In the non-slipping state, higher viscosity LCP domains connect the electrodes. In the slipping state,
on the other hand, LCP domains do not connect the electrodes and the shear is mainly confined in the lower viscosity DMS domains.
The ER effect (electrically induced viscosity increase) originates from the electrically induced slipping to non-slipping
transition. In one of the blends, the ER effect occurs only at high shear rate, since this blend is in non-slipping state
even under no field if the shear rate is low.
Received: 29 April 1997 Accepted: 3 November 1997 相似文献
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An explicit full-field expression of the Green's functions for anisotropic piezoelectric bimaterials with a slipping interface
is derived. When the electro-elastic singularity reduces to a pure dislocation in displacement and electric potential, interaction
energy between the dislocation and the bimaterials is obtained explicitly while the generalized force on the dislocation is
given in a real form which is also valid for degenerate materials. The investigation demonstrates that the boundary conditions
at the slipping interface between two piezoelectric materials will exert a prominent influence on the mobility of the dislocation.
Project supported by the National Natural Science Foundation of China (No. 59635140). 相似文献
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A theory is proposed for the electrophoresis of a large colloidal particle with a surface charge layer. The slipping plane is assumed to be located within the surface layer but may not be located at the boundary between the surface layer and the particle core. In previous studies, the depth of the slipping plane is assumed to coincide with the surface layer thickness. The present theory makes it possible to examine the separate dependence of the electrophoretic mobility on the position of the slipping plane and on the surface layer thickness. It is shown that, at constant amount of particle-fixed charges in the surface layer, the mobility increases as the depth of the slipping plane (d
s
) increases, while it decreases as the surface layer thickness (d
c
) increases, causing a mobility maximum in some cases ifd
s
=d
c
. Several approximate analytic expressions for the mobility are presented. 相似文献
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The damping property of magnetorheological (MR) elastomers is characterized by a modified dynamic mechanical-magnetic coupled analyzer. The influences of the external magnetic flux density, damping of the matrix, content of iron particles, dynamic strain, and driving frequency on the damping properties of MR elastomers were investigated experimentally. The experimental results indicate that the damping properties of MR elastomers greatly depend on the interfacial slipping between the inner particles and the matrix. Different from general composite materials, the interfacial slipping in MR elastomers is affected bythe external applied magnetic field. 相似文献