Anomalous diffraction model of linear optical dichroism in shear-thickening polymer solutions

The anomalous diffraction approximation (ADA) has bees recently applied to interpret measurements of the linear optical dichroism induced by shear in shear-thickening polymer solutions. A conceptual problem in this application is discussed, and a minor modification to the interpretation is proposed which is concordant with earlier magneto-optic results, but retains the correct use of the ADA.     

Threshold-type shear-thickening in polymeric solutions

Threshold-type shear-thickening has been reported in the literature for relatively complex mixtures and one of the most famous is a solution of poly(vinylalcohol) in water in which a substantial amount of sodium borate is added. As far as we know, relatively few polymer solutions have been shown to be shear-thickening, even less of the threshold type. Two cases of threshold-type shear-thickening are examined. One of them is reversible [HPAM Pusher 700 or partially hydrolyzed poly(acrylamide) aqueous solution], the other one (in vitro-synthesized native dextran aqueous solution) leads to the formation of an irreversible structure provided sufficient strain is applied. In both cases, the occurrence of shear-thickening above a critical value of shear rate is related with a change in macromolecular conformation. This conformational change (reversible) can be followed by the formation of intermolecular bonds (irreversible).Presented at the 57^th Annual Meeting of the Society of Rheology, Ann Arbor, Michigan, Oct. 1985     

Nonlinear rheological behavior of a concentrated spherical silica suspension

Linear and nonlinear viscoelastic properties were examined for a 50 wt% suspension of spherical silica particles (with radius of 40 nm) in a viscous medium, 2.27/1 (wt/wt) ethylene glycol/glycerol mixture. The effective volume fraction of the particles evaluated from zero-shear viscosities of the suspension and medium was 0.53. At a quiescent state the particles had a liquid-like, isotropic spatial distribution in the medium. Dynamic moduli G^* obtained for small oscillatory strain (in the linear viscoelastic regime) exhibited a relaxation process that reflected the equilibrium Brownian motion of those particles. In the stress relaxation experiments, the linear relaxation modulus G(t) was obtained for small step strain (0.2) while the nonlinear relaxation modulus G(t, ) characterizing strong stress damping behavior was obtained for large (>0.2). G(t, ) obeyed the time-strain separability at long time scales, and the damping function h() (–G(t, )/G(t)) was determined. Steady flow measurements revealed shear-thinning of the steady state viscosity () for small shear rates (< ^–1; = linear viscoelastic relaxation time) and shear-thickening for larger (>^–1). Corresponding changes were observed also for the viscosity growth and decay functions on start up and cessation of flow, + (t, ) and _– (t, ). In the shear-thinning regime, the and dependence of ₊(t,) and _–(t,) as well as the dependence of () were well described by a BKZ-type constitutive equation using the G(t) and h() data. On the other hand, this equation completely failed in describing the behavior in the shear-thickening regime. These applicabilities of the BKZ equation were utilized to discuss the shearthinning and shear-thickening mechanisms in relation to shear effects on the structure (spatial distribution) and motion of the suspended particles.Dedicated to the memory of Prof. Dale S. Parson     

Rheological Behavior Investigation of Concentrated Coal-Water Suspension

The Haake rheometer is used to determine the rheological property of coal-water suspension (CWS) made up from Datong coal, and the obtained rheological curves are fitted using power-law, Binghamplastic, Herschel-Bulkley, Casson, and Sisko models, respectively. The fitted parameters indicate that the Herschel-Bulkley model has the maximum correlation coefficient of all the rheological models, so the Herschel-Bulkley model is selected to study the rheological property of the prepared CWS. By means of the Herschel-Bulkley model, the effects of coal concentration, dispersant dosage and electrolyte addition on rheological property of CWS are studied. The results show that CWS with higher coal concentration tend to be pseudoplastic behavior, and CWS prepared using excessive dispersant show shear-thickening flow characteristic. The addition of high-valence cationic electrolyte increase the yield value and the pseudoplastic behavior of CWS, while the addition of anionic adjusting agent decrease the yield value of CWS, and the CWS tend to be shear-thickening flow characteristic.     

Flow of a generalized second grade non-Newtonian fluid with variable viscosity

A modified constitutive equation for a second grade fluid is proposed so that the model would be suitable for studies where shear-thinning (or shear-thickening) may occur. In addition, the dependence of viscosity on the temperature follows the Reynolds equation. In this paper, we propose a constitutive relation, (18), which has the basic structure of a second grade fluid, where the viscosity is now a function of temperature, shear rate, and concentration. As a special case, we solve the fully developed flow of a non-Newtonian fluid given by (11), where the effects of concentration are neglected.Received: 28 August 2003, Accepted: 3 March 2004, Published online: 25 June 2004 Correspondence to: M. Massoudi Dedicated to Professor Brian Straughan     

Characterization of micellar structure dynamics for a drag-reducing surfactant solution under shear: normal stress studies and flow geometry effects

Some surfactant solutions have been observed to exhibit a strong drag reduction behavior in turbulent flow. This effect is generally believed to result from the formation of large cylindrical micelles or micellar structures. To characterize and understand better these fluids, we have studied the transient rheological properties of an efficient drag-reducing aqueous solution: tris (2-hydroxyethyl) tallowalkyl ammonium acetate (TTAA) with added sodium salicylate (NaSal) as counter ion. For a 5/5 mM equimolar TTAA/NaSal solution, there is no measurable first normal stress difference (N ₁) immediately after the inception of shear, but N ₁ begins to increase after a well-defined induction time — presumably as shear-induced structures (SIS) are formed — and it finally reaches a fluctuating plateau region where its average value is two orders of magnitude larger than that of the shear stress. The SIS buildup times obtained by first normal stress measurements were approximately inversely proportional to the shear rate, which is consistent with a kinetic process during which individual micelles are incorporated through shear into large micellar structures. The SIS buildup after a strong preshear and the relaxation processes after flow cessation were also studied and quantified with first normal stress difference measurements. The SIS buildup times and final state were also found to be highly dependent on flow geometry. With an increase in gap between parallel plates, for example, the SIS buildup times decreased, whereas the plateau viscosity increased.     

剪切增稠液体液舱侵彻实验

为研究剪切增稠液体(shear-thickening fluid, STF)液舱对弹体的防护性能,制备特定规格剪切增稠液体,并开展弹体侵彻剪切增稠液舱实验研究。实验中采用高速相机记录液舱侵彻过程中空泡的演化情况,并测试得到了弹体的剩余弹速以及前后靶板变形数据。实验结果显示,剪切增稠液体可有效抑制液舱侵彻过程中空泡的增长,从而降低液舱结构的损伤程度。结合空泡扩展理论模型,并考虑液体密度以及黏度变化对空泡增长的影响,验证了剪切增稠液体在高速冲击下产生的局部密度增大以及固化现象是抑制空泡扩展的主要原因。此外,剪切增稠液体对弹体速度的衰减作用明显,且相同初始弹速下,剪切增稠液体液舱前后靶板变形明显小于水体液舱。将剪切增稠液体填充于舰船液舱防护结构,可显著提高液舱结构的防护性能。     

Network development during shear-thickening in semidilute solutions of gently solubilized starches

The shear-thickening behavior of semidilute waxy maize (WM) starch solutions (90/10 DMSO/water) exhibit much of the behavior of classical nonlinear viscoelasticity. Small-amplitude oscillatory shear experiments were used to investigate the network structure formed during the shear-thickening regime. The solution viscoelastic properties of WM starch prior to the shear-thickening region could be described by the GLV model. The macromolecules behave as random coils with a longest relaxation time of 0.58 ± 0.03 s. For WM starch the observed shear-thickening region creates a stable, highly entangled network which resembles the behavior found in solutions in the concentrated regime. The longest relaxation time for the entangled solution is estimated to be 1.4 s. Semidilute solutions of normal maize (NM) starch in 90/10 DMSO/water do not exhibit a shear-thickening regime. The oscillatory shear data obtained before and after a thixotropic loop experiment were identical. The semidilute solution conformational dynamics of NM starch indicate some degree of rigidity in one of the components that constitute NM starch which might be associated with the helical structure obtained by amylose in DMSO. © 1998 John Wiley & Sons, Inc.

1 This article is a US Government work, and, as such, is in the public domain in the United States of America.

J Polym Sci B: Polym Phys 36: 2085–2093, 1998     

Studies of the solution properties of sulfonated-(styrene-(ethyrene-CO-butylene)-styrene) block copolymer

The dilute solution properties of lightly sulfonated hydrogenated styrene-butadiene-styrene block copolymer (S-SEBS) dissolved in tetrahydrofunan (THF) were studied by viscometry. The ring conformation in dilute regime can be deduced from the intrinsic viscosity data. It is believed that this special conformation results from the location of ionic group at both two-end blocks. The intermolecular aggregation can be observed when the solutions undergo the freezing–thawing process in the same concentration region. The extent of aggregation is affected by the freezing–thawing cycle times, water content in THF, and the counterion radii, etc. The properties of the aggregation equilibrium are also discussed. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 2677–2681, 1998