Formation of porous polymer morphology by microsyneresis during divinylbenzene polymerization

This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781     

Enhancing the Water Stability of Al‐MIL‐101‐NH2 via Postsynthetic Modification

The resistance of metal–organic frameworks towards water is a very critical issue concerning their practical use. Recently, it was shown for microporous MOFs that the water stability could be increased by introducing hydrophobic pendant groups. Here, we demonstrate a remarkable stabilisation of the mesoporous MOF Al‐MIL‐101‐NH₂ by postsynthetic modification with phenyl isocyanate. In this process 86 % of the amino groups were converted into phenylurea units. As a consequence, the long‐term stability of Al‐MIL‐101‐URPh in liquid water could be extended beyond a week. In water saturated atmospheres Al‐MIL‐101‐URPh decomposed at least 12‐times slower than the unfunctionalised analogue. To study the underlying processes both materials were characterised by Ar, N₂ and H₂O sorption measurements, powder X‐ray diffraction, thermogravimetric and chemical analysis as well as solid‐state NMR and IR spectroscopy. Postsynthetic modification decreased the BET equivalent surface area from 3363 to 1555 m² g^?1 for Al‐MIL‐101‐URPh and reduced the mean diameters of the mesopores by 0.6 nm without degrading the structure significantly and reducing thermal stability. In spite of similar water uptake capacities, the relative humidity‐dependent uptake of Al‐MIL‐101‐URPh is slowed and occurs at higher relative humidity values. In combination with ¹H‐²⁷Al D ‐HMQC NMR spectroscopy experiments this favours a shielding mechanism of the Al clusters by the pendant phenyl groups and rules out pore blocking.     

因素空间理论与知识表示的数学框架（Ⅷ）─—变权综合原理

本文是文［１－７］的继续，研究变权综合问题，从确定变权的经验公式入手引出了变权原理，给出了变权的公理化定义，讨论了与之有关的均衡函数及其梯度向量。     

Cycle and circle tests of balance in gain graphs: Forbidden minors and their groups

We examine two criteria for balance of a gain graph, one based on binary cycles and one on circles. The graphs for which each criterion is valid depend on the set of allowed gain groups. The binary cycle test is invalid, except for forests, if any possible gain group has an element of odd order. Assuming all groups are allowed, or all abelian groups, or merely the cyclic group of order 3, we characterize, both constructively and by forbidden minors, the graphs for which the circle test is valid. It turns out that these three classes of groups have the same set of forbidden minors. The exact reason for the importance of the ternary cyclic group is not clear. © 2005 Wiley Periodicals, Inc. J Graph Theory     

The effects of doubly excited states on ionization balance

The effects of highly doubly excited states on ionization balance are investigated. In the calculation, A Collisional-Radiative model in Detailed-Configuration-Accounting (DCA) is applied to population calculations for NLTE plasmas. Configuration-averaged rate coefficients that needed in the rate equations are obtained based on the first order perturbation theory. The Hatree-Fock-Slater self-consistent-field method is used to calculate the electron wave functions. The mean ionization stage of high-Z plasma Lu is presented. The comparison shows that the mean ionization stage increases more than 3 stages when doubly excited states 5l6l' and 5l5l' are not included in the population calculations.     

Extrusion of pastes with a piston extruder for the determination of the local solid and fluid concentration, the local porosity and saturation and displacement profiles by means of NMR imaging

 Nuclear Magnetic Resonance (NMR) was used to investigate the extrusion behaviour of PTFE pastes in a ram extruder. By means of ¹H-NMR imaging (MRI) it is possible to determine the local proton density and therefore, the local fluid concentration. The ¹⁹F-MRI provides the local solid concentration. Thus the local saturation and the local porosity can be calculated with the information of the local fluid and solid concentration. Furthermore displacement profiles can be derived from NMR images by means of correlation techniques without any preparation or marking of the pastes. Received: 8 May 2000   Accepted: 1 May 2001     

对超重、失重演示实验的改进

对传统的超重、失重演示实验进行了改进,使弹簧秤的指针能静止在超重(或失重)的位置上,从而能准确地读出读数,提高演示效果.     

空间目标的可见光散射与红外辐射

利用Lowtran7大气传输模型计算0.4～0.8μm可见光波段的太阳辐射、大气自身的热辐射以及天地背景辐射.依据粗糙面光散射理论与双向反射分布函数计算空中目标表面对太阳辐射和云层对阳光反射的散射.利用传热学和背景辐射理论,根据能量守恒定律建立空间目标表面温度的热平衡方程.以气球为例,计算不同表面涂层材料的气球,在不同地理位置、不同高度和不同时间条件下,其温度及辐射功率的变化.分析空间目标红外辐射特性的一般规律和特征.     

三维流动传热空隙率计算程序FASTOR—3D开发研究

1引言大粘度（大r）和大系数（ss和sc）法是处理流动区域中障碍物的常用方法山。但当流动区域中障碍物数量较多时，宜采用空隙率来模拟障碍物，如模拟反应堆流动传热的商用程序COMMIX［’］。我们根据空隙率模拟的基本概念，针对采用交错网格的压力校正法，自行编制了多障碍物流动传热三维计算的全部源程序代码，应用于某核反应堆钠池流动传热的数值模拟，获得了比较合理的结果。2数学模型和数值方法2．1控制方程空隙率修整的质量、动量、能量及湍流动能与耗散率的守恒方程通式的三维柱坐标形式为其中中一1，。，。，。，T，k，。分别表…     

Consolidation around a borehole embedded in media with double porosity under release of geostatic stresses

The paper deals with the stress, displacement, pore and fissure pressures fields induced by the drilling and/or the pressurization of a vertical borehole in a formation of water-saturated porous media with double porosity. The solution includes the boundary condition of non-hydrostatic in situ state of stress. The solid skeleton is assumed to behave as a linearly poroelastic material with compressible constituents. The analytical solution is derived in Laplace’s space and transformed to the time domain using a numerical inversion technique. The histories of pore and fissure pressures are illustrated to show the influence of permeabilities of the pore and fissure systems.