首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   736篇
  免费   133篇
  国内免费   44篇
化学   365篇
晶体学   2篇
力学   192篇
综合类   17篇
数学   112篇
物理学   225篇
  2024年   3篇
  2023年   11篇
  2022年   28篇
  2021年   42篇
  2020年   48篇
  2019年   23篇
  2018年   17篇
  2017年   21篇
  2016年   26篇
  2015年   45篇
  2014年   54篇
  2013年   58篇
  2012年   34篇
  2011年   46篇
  2010年   42篇
  2009年   29篇
  2008年   28篇
  2007年   36篇
  2006年   40篇
  2005年   28篇
  2004年   27篇
  2003年   33篇
  2002年   17篇
  2001年   21篇
  2000年   28篇
  1999年   18篇
  1998年   36篇
  1997年   17篇
  1996年   13篇
  1995年   11篇
  1994年   6篇
  1993年   4篇
  1992年   3篇
  1991年   4篇
  1990年   5篇
  1989年   1篇
  1988年   1篇
  1986年   2篇
  1985年   3篇
  1984年   1篇
  1981年   2篇
  1977年   1篇
排序方式: 共有913条查询结果,搜索用时 250 毫秒
1.
The structural possibilities of decreasing the compliance of a composite saddle-shaped cable roof having a compliant support contour are investigated. The use of a supporting contour consisting of cables joined together with tie-bars is considered as a structural method enabling one to decrease the compliance of the roof. Each cable of the support has its own initial flexure. The method is most efficient from the viewpoint of material consumption per unit of covered area relative to the increasing rigidity and prestress level of the cable net.The efficiency of the method was evaluated by a numerical experiment, which was carried out for a composite saddle-shaped cable roof 50 × 50 m in the plan. The roof was formed by two orthogonal cable groups joined with a compliant supporting contour. A hybrid composite cable based on a carbon-fiber-reinforced plastic, a glass-fiber-reinforced plastic, and steel was considered as a material for the cable net in combination with steel. The material consumption and the maximum vertical displacement of the cable net in relation to the initial geometrical characteristics of the supporting contour were obtained. A possibility of decreasing the maximum vertical displacements of the roof by 8% was established.  相似文献   
2.
基础房价的相关指标及其走势一直是大众关心的热门话题.本文通过对上海基础房价相关指标的分析,建立了市场房价走势的两个数学模型.模型一:在相关性分析的基础上利用主成分分析消除指标间的共线性,再用回归拟合房价模型并进行预测;模型二:在相关性分析的基础上利用核估计方法预测出房价.继呵对2005年下半年的房价走势进行了预测,得出的结果与实际情况相吻合.  相似文献   
3.
HypersurfacewithConstantMainCurvatureSymmetricFunctions¥WuBaoqiang;SongHongzao(XuzhouTeachersCollege,221009)(HenanUniversity,...  相似文献   
4.
5.
The objective of this paper is a theoretical and numerical study of the dynamics of a taut inclined cable with a riding accolerating mass, which is suspended from two points of different elevation. The moving mass is a trolley that is accelerated by a solid fuel rocket down the inclined cable and is aerodynamically brought to a halt. The thrust of the rocket is tangential to the deformed configuration of the cable.Methods of analysis consist of the dynamics of small deformations superimposed on the static catenary state. The problem is nonlinear due to presence of friction and the convective acceleration interaction of the moving mass and the cable. Galerkin's procedure for removal of spatial dependence and numerical integration are used to obtain convergent solutions.Deceased  相似文献   
6.
Let G be a p-adic Lie group. Then G is a locally compact, totally disconnected group, to which Willis [14] associates its scale function G : G→ℕ. We show that s can be computed on the Lie algebra level. The image of s consists of powers of p. If G is a linear algebraic group over ℚ p , s(x)=s(h) is determined by the semisimple part h of xG. For every finite extension K of ℚ p , the scale functions of G and H:=G(K) are related by s H G =s G [ K :ℚ p ]. More generally, we clarify the relations between the scale function of a p-adic Lie group and the scale functions of its closed subgroups and Hausdorff quotients. Received: 20 February 1997; Revised version: 18 May 1998  相似文献   
7.
周雨  宋凤瑞 《分析化学》1996,24(9):1032-1035
本文研究了18种α-氨基酸的快原子轰击质谱,发现添加三氟乙酸溶液能显著提高灵敏度,改善谱图。特征碎片主要有中性丢失CO2H2,H2O,NH3的离子以及R^+离子。侧链的性质决定了碎片的产生和离子的强弱。  相似文献   
8.
众所周知 ,聚合物的光电性质依赖于聚合物链的构象和 (或 )组成 ,通过在聚合物上引入手性单元 ,采用圆二色谱 ( CD)和圆偏振荧光光谱 ( CPL)等方法可表征聚合物结构 [1] .近年来 ,由于圆偏振光可用作光数据存储和液晶显示器背景光 [2 ] ,人们开始注重共轭聚合物圆偏振光材料的研究 .共轭聚合物的光致和电致圆偏振光的现象由一种带手性侧链的聚噻吩[3 ] 和一种带手性侧链的聚 (对苯撑乙烯 ) [4 ]产生 ,但它们的圆偏振荧光度 (用不对称因子 glum=2 ( IL-IR) / ( IL+IR)表示 ,IL 和 IR 分别指左圆偏振光强度和右圆偏振光强度 )相对较低 …  相似文献   
9.
Liquid crystalline ionomers containing sulfonate groups on the terminal unit of the chain were synthesized by an interfacial condensation reaction of 4,4′-dihydroxy-α,α′-dimethyl benzalazine, the monofunctional dye fast yellow (FY), and a 50/50 mixture of sebacoyl and dodecanedioyl dichlorides. The weight-average molecular weights were estimated from inherent viscosity measurements to be between 6000–11,000 and the sodium sulfonate concentrations ranged from 0–18.4 meq/100 g polymer. Elemental analyses, however, indicated much higher molecular weights, which suggested that there was a distribution of chains with one, two, or no FY endgroups. The polymers were semicrystalline and melted at ca. 140°C to form nematic mesophases that were stable over a temperature range of ca. 80°C. They were thermally stable to about 350°C. The ionomeric nature of the polymers was confirmed by the presence of intermolecular associations in nonpolar solvents, as demonstrated by dilute solution viscosity measurements.  相似文献   
10.
Metal hydroxides represent a very interesting and highly useful class of compounds that have been known to chemists for a very long time. While alkali and alkaline earth metal hydroxides (s‐block) are commonplace chemicals in terms of their abundance and their use in a chemical laboratory as bases, the interest in Brønsted acidic molecular terminal hydroxides of p‐block elements, such as aluminum and silicon, has been of recent origin, with respect to the variety of applications these compounds can offer both in materials science and catalysis. Moreover, these systems are environmentally friendly, relative to the metal halides, owing to their ‐OH functionality (resembling that of water). Design and conceptualization of the corresponding terminal thiols, selenols, and tellurols (M? SH, M? SeH, and M? TeH) offer even more challenging problems to synthetic inorganic chemists. This concept summarizes some of the recent strategies developed to stabilize these otherwise very unstable species. The successful preparation of a number of silicon trihydroxides a few years back resulted in the generation of several model compounds for metal–silicates. The recent synthesis of unusual aluminum compounds such as RAl(OH)2, RAl(SH)2, and RAl(SeH)2 with terminal EH (E=O, Se, or Se) groups is likely to change the ways in which some of the well‐known catalytic conversions are being carried out. The need for very flexible and innovative synthetic strategies to achieve these unusual compounds is emphasized in this concept.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号