Preparation and applications of novel fluoroalkyl end‐capped vinyltrimethoxysilane oligomer/hydroxyapatite nanocomposites

Novel fluoroalkyl end‐capped vinyltrimethoxysilane oligomer/hydroxyapatite (HAp) nanocomposites were prepared by the reaction of calcium nitrate tetrahydrate and phosphoric acid in the presence of the corresponding oligomer. These fluorinated oligomer/HAp composites thus obtained are nanometer size‐controlled fine particles (83–173 nm), and were found to exhibit good dispersibility in methanol, ethanol, and isopropyl alcohol. These fluorinated HAp nanocomposites were applied to the surface modification of glass and poly(methyl methacrylate) (PMMA) to exhibit good hydro‐ and oleophobic characteristics imparted by fluorine on their surface. In addition, the surface structural changes of the modified polyethylene terephtalate and PMMA films treated with these fluorinated nanocomposites before and after soaking in a simulated body fluid (SBF) were analyzed by using SEM, XRD, and EDX to observe the formation of spherical HAp deposits on the surface. Copyright © 2009 John Wiley & Sons, Ltd.     

Maxwell粘弹性球体的湿应力

谷物烘干时，谷粒内部的热－湿应力太大，可能使谷粒出现裂纹．基于这一实际问题，本文研究了当初始湿度和平衡湿度给定时，Ｍａｘｗｅｌ粘弹性圆球内的湿应力分布，及其随时间的变化情况．     

次澳酸氧化葡萄糖反应动力学研究

使用分光光度法在近 中性介质 中对 H O Br氧化葡萄糖的反 应动力学进行了研究.结果表明,该 反 应对葡萄糖和 H O Br 都是一级,反 应有 负盐 效应,并 随 Br一浓 度的增 加,反 应速度 减慢.本文还提出 了可能的反 应机理.     

Application of inverse finite element method in tube hydroforming modeling

In tube hydroforming, the inverse finite element method (IFEM) has been used for estimating the initial length of tube, axial feeding and fluid pressure. The already developed IFEM algorithm used in this work is based on the total deformation theory of plasticity. Although the nature of tube hydroforming is three-dimensional deformation, in this paper a modeling technique has been used to perform the computations in two-dimensional space. Therefore, compared with conventional forward finite element methods, the present computations are quite fast with no trial and error process. In addition, the solution provides all the components of strain. Using the forming limit diagram (FLD), the components of strain can lead us to measure the potentials for failures or wrinkles during the deformation. The results of analysis for free bulging and square bulging have been compared with some published experimental data and the results obtained by conventional commercial software.     

Organic–Inorganic Hybrid Zinc Phosphate with 28‐Ring Channels

An organic–inorganic hybrid zinc phosphate with 28‐ring channels was synthesized by use of an organic ligand instead of organic amine template under a hydro(solvo)thermal condition. This crystalline zinc phosphate contains large channels constructed from 28 zinc and phosphate tetrahedral units. The walls of the channels consist of two types of zincophosphate chains, in which the Zn atoms are coordinated by 2,4,5‐tri(4‐pyridyl)‐imidazole ligands as pendent groups. This compound exhibits yellow emission and interesting properties of removing cobalt, cadmium, and mercury cations from aqueous solution. A new two‐dimensional organic–inorganic hybrid zincophosphate was also obtained by changing the solvent mixture ratios in the synthesis.     

同轴型爆磁压缩发生器1维磁扩散模型

 基于１维爆轰驱动模型、爆炸管与金属固壁的１维磁扩散模型及回路等效电路模型,编制了关于轴线起爆大电流同轴型爆磁压缩发生器的数值模拟程序CEMG2.0。应用该程序对洛斯·阿拉莫斯实验室设计试验的43 cm长Ranchero发生器进行了对比模拟,结果证明CEMG2.0程序所采用的模型是合理的,可以应用于今后同类发生器的优化设计。     

Thermal and infrared studies of calcium malate crystals grown in diffusion limited medium

Single crystals of the title compound Ca (C₄H₅O₅)₂.10H₂O are grown in silica gel using controlled chemical reaction method. Multifaceted single crystals of size up to 8 × 4 × 2 mm³ are obtained. Powder X‐ray Diffraction (XRD) pattern of the grown crystal and the Fourier Transform Infra‐Red (FTIR) spectrum in the range 400–4000 cm^–1 are recorded. The vibrational bands corresponding to different functional groups are assigned. Thermal decomposition stages observed in the Thermo‐gravimetric (TG) and Differential Thermal Analysis (DTA) studies are discussed. A six‐stage thermal decomposition scheme is proposed for the compound. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Hydro(solvo)thermal Construction of a Copper Coordination Polymer Involving in Situ Ligand Synthesis: Preparation and Structure of [Cu_3(bdcO)_2(H_2O)_2]_n

1 INTRODUCTION Increasing attention has been paid to the coppercoordination polymer frameworks not only due totheir intriguing structure diversity but also theirpotential applications in the areas of molecular ad-sorption, catalysis, electromagnetism and photo-chemistry[1～4]. Incorporation of both organic and in-organic components in these compounds has createda new direction in searching for functional materialswith desired structures and properties. Over the lastdecades, the majority o…     

统一流体力学模型与BNL-RHIC低能量区重离子碰撞中的赝快度分布

重离子碰撞产生的高温高密度物质假设按照统一流体力学模型的规律做时空演化,并最终经由一固有时为Tau_FO的类时超曲面冻析为带电粒子。统一流体力学模型是一种将Landau与Hwa-Bjorken两著名流体力学模型结合在一起的模型,是一种少有的可精确求解的理论之一。本文的研究表明:BNL-RHIC低能量区重离子碰撞中带电粒子的赝快度分布可由统一流体力学模型很好地描述。 这与高能区的情况不同,在那里,除了流体外,还需考虑带头粒子的贡献。The hot and dense matter created in heavy ion collisions is supposed to have spatiotemporal evolution according to unified hydro model, and finally freeze out into the charged particles via a space-like hypersurface with a proper time Tau_FO . The unified hydro model is a model which integrates Landau and Hwa-Bjorken two famous hydro models together. It is one of few hydro models which can solved exactly. Shown from the investigations in this paper, the pseudorapidity distribution of charged particles in heavy ion collisions at low BNL-RHIC energy region can be well described by unified hydro model. This is different from that at high nergy region, where, apart from fluid, the contribution from leading particles should be taken into account.