铁基添加剂增强细水雾灭火性能的实验研究

采用实验模拟的方法,研究了添加氯化亚铁的细水雾在不同添加剂浓度、不同喷头压力下,熄灭不同性质的液体池火的性能。实验结果表明:添加有氯化亚铁的细水雾,其灭火性能发生了显著变化。存在一个最佳的灭火浓度,其对应的灭火时间最短,耗水量最少,灭火效率最高。细水雾喷头的工作压力和燃料的性质也对细水雾的灭火性能有影响:工作压力越大,细水雾的平均灭火时间越短。在相同的实验条件下,细水雾扑灭煤油池火的时间要短于扑灭酒精池火的时间。     

X-ray crystallographic structure and physical properties of the pentacoordinated [TPAFeCl] complex

A new pentacoordinated ferrous compound [TPAFeCl]⁺ (TPA = tris(2-pyridylmethyl)amine) was synthesized from the reaction between H₃TPA(ClO₄)₃ and Fe(PⁿPr₃)₂Cl₂ in MeCN. The unique trigonal bipyramidal [TPAFeCl]⁺ complex was characterized as a S = 2 high spin complex based on the crystallographic structure, magnetic susceptibility, ¹H NMR spectrum and semi-empirical ZINDO/S calculations. Crystal of [TPAFeCl]₂(FeCl₄)(MeCN)₂ was monoclinic with a = 12.019(2) Å, b = 27.550(5) Å, c = 14.138(2) Å, β = 94.168(3)°, V = 4668.9(13) Å³, space group C/c, and the unit cell contained a racemic mixture of Δ and Λ isomers with ferrous tetrachloride anion.     

无机高分子聚合铁盐类混凝剂制备方法评述(英文)

综述了无机高分子聚合铁盐类混凝剂的几种生产制备方法.对用硫酸亚铁经催化氧化法和直接氧化法制备聚合硫酸铁,用各种含铁工业废渣制备复合聚铁,以及采用生物和电化学方法制备聚铁类混凝剂等方法的优缺点等作了较全面评述.还对固体聚合铁的生产及液体聚合铁混凝剂的稳定性进行了讨论,对目前聚合铁生产中存在的问题及发展方向提出了建议.     

Synthesis of new colloidal formations during the strengthening of different activated hydrated metallurgical slags

This paper reports on a comparison of experimental researches on the hydration hardening of different types of dumped ferrous slag (DFS) (blast furnace, open hearth, electric steel and converter), non-activated and activated with small (2%) additions of Portland cement or lime. Activation was found to accelerate the strengthening processes in the early stages of hydration resulting from the growth of colloidal sol–gel new formations in a more alkaline environment. Over time, these formations became denser and transformed into stone-like amorphous materials with a uniaxial strength of up to 47.6 MPa at 1 year of age. All these types of slag can, therefore, be used in different applications, for example, like traditional binders, such as Portland cement, to different ceramic goods, new construction materials, etc. But till now the results of this research were used only for the preparing of binder materials for natural soils strengthening as road bases in Russia. Highways whose roadbeds were built with these DFS as binder materials have shown excellent performance indices in different parts of Russia, including Siberia and northern regions.     

硅灰石矿物发光原料中Fe2+的去除与CaSiO3∶Eu3+的光谱特性

提出了用草酸．邻菲哕啉去除硅灰石中Fe^2 的方法，研究了浸取剂的浓度、浸取时间和温度等条件对Fe^2 的去除率的影响，在最佳的浸取条件下，Fe^2 的去除率达到98．35％。在去除猝灭剂后的硅灰石矿物中，掺加适量的稀土激活剂Eu^3 ，通过高温固相法制成荧光发光材料，发光强度明显提高，接近于化学试剂合成的发光材料。     

氨基氮杂环荧光分子改性苯乙烯马来酸酐共聚物的研究

荧光高分子材料 ,由于其独特光学性质 ,成为功能高分子研究热点[1～ 3 ] .一般而言 ,荧光聚合物的合成有两种方法 ,一是首先合成荧光单体 ,然后与其他适宜单体聚合 ,得到荧光聚合物 ,然而荧光单体结构复杂 ,提纯困难 ,难以获得高分子量、成膜性能好的聚合物[4] ;另一种方法是通过官能团的反应 ,用荧光物质对聚合物进行化学改性来制备[5,6] .苯乙烯 马来酸酐共聚物 (ＳＭＡ)是一类成本低廉 ,性能良好的商品化聚合物材料 ,主链中含有具有反应性能的酸酐基团 ,这就使通过化学改性制备荧光聚合物成为可能 .本文通过 2 氨基苯并咪唑 ( 1 ) ,4 …     

Effect of Sulfate on an Iron Manganese Catalyst for Fischer-Tropsch Synthesis

The effect of sulfate on Fischer-Tropsch synthesis performance was investigated in a slurry- phase continuously stirred tank reactor(CSTR)over a Fe-Mn catalyst.The physiochemical properties of the catalyst impregnated with different levels of sulfate were characterized by N_2 physisorption,X-ray photoelectron spectroscopy(XPS),H_2(or CO)temperature-programmed reduction(TPR),Mφssbauer spectroscopy,and CO_2 temperature-programmed desorption(TPD).The characterization results indicated that the impregnated sulfate slightly decreased the BET surface area and pore volume of the catalyst, suppressed the catalyst reduction and carburization in CO and syngas,and decreased the catalyst surface basicity.At the same time,the addition of small amounts of sulfate improved the activities of Fischer- Tropseh synthesis(FTS)and water gas shift(WGS),shifted the product to light hydrocarbons(C_1-C_(11)) and suppressed the formation of heavy products(C_(12 )).Addition of SO_4~(2-)to the catalyst improved the FTS activity at a sulfur loading of 0.05-0.80 g per 100 g Fe,and S-05 catalyst gave the highest CO conversion(62.3%),and beyond this sulfur level the activity of the catalyst decreased.     

Inclusion of ferrous phenanthroline in molybdenum disulfide

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促进学生化学学科核心素养发展的“铁盐和亚铁盐”的单元教学

设计了“铁盐和亚铁盐”的单元教学,以“探究硫酸亚铁的性质”和“线路板腐蚀液的研究”为核心任务,把铁盐与亚铁盐的性质、Fe²⁺和Fe³⁺的相互转化等核心知识贯穿其中,建立从物质类别、元素价态视角研究物质性质及转化的思路方法,促进多维度化学学科核心素养的融合发展。经过多轮次教学改进,结合教学实践过程及其教学效果抽提出“注重应用无机物的认识模型,重点把握研究物质性质的角度和思路”“抓住典型活动,培养学生的关键能力”“设计开放性任务,通过有效的师生对话进行诊断,外显问题解决思路”等教学策略。     

基于OTDR和SMA原理的分布温度阈值执行器的设计

温度阈值执行器的设计是准分布光纤温度报警系统对温度报警空间定位的关键.本文分析了基于OTDR和SMA设计温度阈值执行器的原理,提出了执行器的物理模型.通过实验测试,从SMA弹簧样品中选出了满足执行器技术要求的记忆弹簧,完成了执行器的机械设计.系统运行表明:执行器能有效运作,能够实现准分布温度报警,并且系统具有接近1.5 m的空间分辨率和低于16 s的响应时间等优良的性能参数.