电场作用下苏氨酸的电流特性研究

制备了以液态苏氨酸为沟道材料的四端有机场效应晶体管,观测了其随着栅极电压的不同呈现出源漏两极之间不同的电学特异现象;还观测了苏氨酸在外电场作用下,阻抗随着源漏之间电压频率变化的关系,提出一个极性液体模型解释了其导电机理。     

Ambident Reactivity of Imidazolium Cations as Evidence of the Dynamic Nature of N-Heterocyclic Carbene-Mediated Organocatalysis

This work reveals ambident nucleophilic reactivity of imidazolium cations towards carbonyl compounds at the C2 or C4 carbene centers depending on the steric properties of the substrates and reaction conditions. Such an adaptive behavior indicates the dynamic nature of organocatalysis proceeding via a covalent interaction of imidazolium carbenes with carbonyl substrates and can be explained by generation of the H-bonded ditopic carbanionic carbenes.     

Ruthenium Complexes of an Abnormally Bound,Anionic N‐Heterocyclic Carbene

The abnormally bound, anionic NHC–borane complex [Ru(IDipp‐BF₃)(p‐cymene)Cl]₂ ( 4 ; IDipp‐BF₃=1,3‐(2,6‐iPr₂C₆H₃)₂‐2‐BF₃(C₃HN₂)‐4‐yl) was synthesized by transmetalation from Li[(IDipp‐BF₃)₂Ag]. Addition of donors gave species of the form [Ru(IDipp‐BF₃)(p‐cymene)(L)Cl], whereas halide abstraction with Ag(Et₂O)[B(C₆F₅)₄] gave C?H activation of the methine position of the IDipp?BF₃ ligand.     

滚滑工况弹流反常温度场的研究

研究了弹流反常温度场的形成机理及影响因素，指出入口温升是压缩功发热和逆流剪切热所致，而出口局部低温是负压缩功吸热的结果，出口温度的再次微幅上升则是压缩功消失后剪切热作用的结果．研究结果表明，入口温升随载荷的增加而增大，随卷吸速度的增加显著升高而几乎与滑滚比无关；在高速小滑滚比工况下，接触区的最高温度有可能出现在入口位置；入口温升增加了材料在工作中经受高温的次数，对其接触疲劳寿命有不利影响；在保证润滑性能的前提下，适当减少供油量可以减小逆流，从而降低入口温升。     

光磁共振实验中壁弛豫过程与外磁场的关系

利用改进后的DH807型光磁共振实验装置,在静态磁场下精确测量了抽运信号的弛豫饱和值与外磁场的关系,从而得到壁弛豫速率与外磁场的关系,并建立模型对其原理进行了探讨.     

多频声光互作用的研究

本文推导出包括正常和反常声光互作用在内的多频声光耦合波方程的普适形式,并得出两个独立超声波信号时布拉格状态下方程的解.分析了多频声光互作用的各种线性和非线性效应,包括衍射效率、压缩、交叉调制和各级互调制强度等,并指出反常与正常多频声光衍射的差异.结论是反常多频声光互作用情况下,各级互调制模强度与主衍射模强度的比值小于正常多频声光互作用情况下的相应比值.实验结果与理论分析相符.     

Necessary optimality conditions for abnormal problems with geometric constraints

The abnormal minimization problem with a finite-dimensional image and geometric constraints is examined. In particular, inequality constraints are included. Second-order necessary conditions for this problem are established that strengthen previously known results.     

Cuccia定理的一个推广

For a finite group G,let S(G)be the set of minimal subgroups of odd order of G which are complemented in G.It is proved that if every minimal subgroup X of odd order of G which does not belong to S(G),C_G(X)is either subnormal or abnormal in G.Then G solvable.     

动态测量数据的合理性检验方法研究

采样数据合理性检验,是数据处理中重要的一环,它的主要功能是鉴别采样数据中可能含有的异常值,并进行相应的机理分析与修复工作.本文从飞行器外测系统工程应用的角度出发,给出了两种简单易行的判断方法.