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1.
Wacker oxidation is an industry-adopted process to transform olefins into value-added epoxides and carbonyls. However, traditional Wacker oxidation involves the use of homogeneous palladium and copper catalysts for the olefin addition and reductive elimination. Here, we demonstrated an ultrahigh loading Cu single atom catalyst(14% Cu, mass fraction) for the palladium-free Wacker oxidation of 4-vinylanisole into the corresponding ketone with N-methylhydroxylamine hydrochloride as an additive under mild conditions. Mechanistic studies by 18O and deuterium isotope labelling revealed a hydrogen shift mechanism in this palladium-free process using N-methylhydroxylamine hydrochloride as the oxygen source. The reaction scope can be further extended to Kucherov oxidation. Our study paves the way to replace noble metal catalysts in the traditional homogeneous processes with single atom catalysts. 相似文献
2.
3.
Kurt Majewski 《Queueing Systems》2005,50(2-3):199-230
We consider multiclass feedforward queueing networks under first in first out and priority service disciplines driven by long-range dependent arrival and service time processes. We show that in critical loading the normalized workload, queue length and sojourn time processes can converge to a multi-dimensional reflected fractional Brownian motion. This weak heavy traffic approximation is deduced from a deterministic pathwise approximation of the network behavior close to constant critical load in terms of the solution of a Skorokhod problem. Since we model the doubly infinite time interval, our results directly cover the stationary case.AMS subject classification: primary 90B15, secondary 60K25, 68M20 相似文献
4.
Using a method of uniform approximations, necessary and sufficient conditions for a nonsmooth constrained vector-valued minimax problem are established in terms of Mordukhovich subdifferentials. 相似文献
5.
In this paper we describe the design and manufacture of an axial-torsion test specimen, and provide relationships needed when
conducting stress-strain characterization experiments with the specimen. The specimen is a short hollow cylinder of rubber
bonded between two steel mounting rings, in which simultaneous axial and shear strains are produced via independently controlled
axial and twist displacements. We present calculations for the strain-displacement and stress-load relationships, and strain
energy density. These relationships have been established and validated via a combination of analytical and experimental techniques,
and finite element analysis. We have investigated the extent and effects of strain and stress field non-uniformity in the
test specimen. The specimen design is sufficiently simple that a closed-form expression for the strain-displacement relationship
has been successfully developed. 相似文献
6.
We provide an approximate analysis of the transient sojourn time for a processor sharing queue with time varying arrival and
service rates, where the load can vary over time, including periods of overload. Using the same asymptotic technique as uniform
acceleration as demonstrated in [12] and [13], we obtain fluid and diffusion limits for the sojourn time of the Mt/Mt/1 processor-sharing queue. Our analysis is enabled by the introduction of a “virtual customer” which differs from the notion
of a “tagged customer” in that the former has no effect on the processing time of the other customers in the system. Our analysis
generalizes to non-exponential service and interarrival times, when the fluid and diffusion limits for the queueing process
are known. 相似文献
7.
应用电磁线路中涨落耗散理论,推导了不同温度均匀二半空间接触后产生辐射场密度的公式。将此公式近似展开后,即得Grover和Urtiew所获得的表示式,不过多了一松弛项,该项如用非富里叶热传导理论推导,也是存在的。该结果和实验结果一致,不过这里的松驰时间可以应用介质性质进行计算。 相似文献
8.
The fixed point property for multivalued nonexpansive mappings 总被引:1,自引:0,他引:1
T. Domínguez Benavides 《Journal of Mathematical Analysis and Applications》2007,328(2):1471-1483
We show some properties concerning geometrical constants of Banach spaces which imply the existence of fixed points for multivalued nonexpansive mappings and we study the relationship between these properties. 相似文献
9.
R. XuF.A. Davidson M.A.J. Chaplain 《Journal of Mathematical Analysis and Applications》2002,269(1):256-277
A two-species ratio-dependent predator-prey model with distributed time delay is investigated. It is shown that the system is persistent under some appropriate conditions, and sufficient conditions are obtained for both the local and global stability of the positive equilibrium of the system. 相似文献
10.
本文考虑损失函数的估计问题,分别对于球对称分布和均匀分布情形给出了其参数的J-S型估计量的损失之估计,它们满足[1]中提出的条件(Ⅰ)和(Ⅱ). 相似文献