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1.
Underground fluids are important natural sources of drinking water, geothermal energy, and oil-based fuels. To facilitate the surveying of such underground fluids, a novel microchannel extraction device was investigated for in-line continuous analysis and flow injection analysis of sulfide levels in water and in oil. Of the four designs investigated, the honeycomb-patterned microchannel extraction (HMCE) device was found to offer the most effective liquid–liquid extraction. In the HMCE device, a thin silicone membrane was sandwiched between two polydimethylsiloxane plates in which honeycomb-patterned microchannels had been fabricated. The identical patterns on the two plates were accurately aligned. The extracted sulfide was detected by quenching monitoring of fluorescein mercuric acetate (FMA). The sulfide extraction efficiencies from water and oil samples of the HMCE device and of three other designs (two annular and one rectangular channel) were examined theoretically and experimentally. The best performance was obtained with the HMCE device because of its thin sample layer (small diffusion distance) and large interface area. Quantitative extraction from both water and oil could be obtained using the HMCE device. The estimated limit of detection for continuous monitoring was 0.05 μM, and sulfide concentrations in the range of 0.15–10 μM could be determined when the acceptor was 5 μM FMA alkaline solution. The method was applied to natural water analysis using flow injection mode, and the data agreed with those obtained using headspace gas chromatography-flame photometric detection. The analysis of hydrogen sulfide levels in prepared oil samples was also performed. The proposed device is expected to be used for real time survey of oil wells and groundwater wells. 相似文献
2.
B. Kuhlmann B. Kaczmarczyk U. Schottler 《International journal of environmental analytical chemistry》2013,93(1-4):199-205
Abstract The behaviour of the three phenoxyacetic acid herbicides 2,4-D, 2,4,5-T and MCPA during underground passage and bankfiltration was tested in a model system consisting of laboratory filter columns filled with natural underground materials. Different redox environments were reproduced by operating the filters with natural aerobic and anaerobic groundwater. In the presence of oxygen, biodegradation of the three herbicides started after a lag phase. Under sulfate reducing conditions, no degradation could be observed. To assess the factors that may influence microbial degradation in the anaerobic environment, the concentration of herbicides, the time and the nutrient content were varied, but this did not increase degradation. The maximum retention of the herbicides in the filters was 30%, mainly due to adsorption to the filter material. 相似文献
3.
《Arabian Journal of Chemistry》2022,15(9):104082
Salt cavern gas storage is one of the vital strategic natural gas reserves and emergency peak shaving facilities all over the world. However, rock salt in China is primarily bedded salt, usually composed of many thin salt layers and interlayers (e.g., anhydrite, mudstone, and glauberite). During the water solution mining process of the cavern, the insoluble mudstones fall to the bottom and account for 1/3 up to 2/3 of the storage capacity. The bulk volume of the insoluble mudstones is almost twice its in-suit volume. It is of great urgency to investigate the swelling mechanisms of the bottom insoluble mudstones. Given this, we first analyzed the mineral composition of salt rock and insoluble mudstones by using XRD and SEM methods. Then, experimental studies were carried out considering both clay swelling and physical packing. At last, the zeta potential tests were conducted to reveal the swelling mechanisms of the bottom mudstones. Results show that the volumetric expansion of mudstones is made up of three parts: clay swelling, particle surface bound water volume, and pore space free water volume increase. Because the content of expansive clay in the bottom mudstones is less than 2%, and the high salinity brine in the cavern has excellent clay stability performance, clay swelling is not the main contributor to the volumetric expansion of the bottom mudstones. Measurement results show that the surface of the mudstones is negatively charged after hydration. Electrostatic repulsion can increase the spacing between small rock particles and creates approximately 47.6% of the pore space, which is the main factor in the volumetric expansion of mudstones. This study provides a theoretical basis for the mining solution and capacity enlargement during the construction of bedded salt cavern gas storage in China. 相似文献
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应用光纤布喇格光栅传感器监测地下管道腐蚀的新方法研究 总被引:2,自引:3,他引:2
地下管线工作环境恶劣,腐蚀是引起它破坏和失效的主要原因之一.本文提出了一种应用光纤光栅传感器监测管道腐蚀的新方法.输送石油和天然气等一些物质的管道内部存在的压力会使管道发生膨胀,进而导致管道外壁产生环向变形.假定管道为无限长,管道内部压力导致的管道外壁轴向应变可忽略不计,当管线发生腐蚀时,会导致管壁变薄,管道内部的压力又可以看作基本不变,这样就会增大管道外壁的环向应变.当管道内部压力保持恒定时,管道壁厚与应变之间存在一定的反比例关系,本文方法就是将封装好的光纤光栅传感器粘贴在管道外壁,通过监测外壁环向变形来判断管道腐蚀的情况和程度.通过理论值、模拟值和试验值三者的对比分析来说明了这种新方法是可行的,并且值得被广泛应用,为埋地管道的防灾减灾提供了一种对策. 相似文献
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本文将空间轴对称问题的Папковиц-Neuber通解用复变量广义解析函数表示,推导出用复变函数法求解空间轴对称问题的基本公式,并以此为工具求得了含球形空腔或刚性夹杂的中厚圆板在轴对称弯曲变形时的完全解. 相似文献
8.
国际地下实验室发展综述 总被引:5,自引:0,他引:5
地下实验室是开展粒子物理学、天体物理学及宇宙学等领域一些重大基础性前沿课题的重要研究场所和良好的低本底环境,建设和发展地下实验室对于一个国家的基础科学研究具有重要科学意义.目前,国际上许多国家都已经建立起地下实验室,而中国一直没有很好的地下实验室,特别是极深地下实验室.2009年,清华大学与二滩水电开发有限责任公司开展战略合作,利用锦屏山隧道建立中国首个世界最深的地下实验室--中国锦屏地下实验室(China Jinping Underground Laboratory,CJPL),并于2010年12月12日正式启用.中国锦屏地下实验室的建成,标志着中国已经具备开展物理学重大基础前沿科学研究的自主地下实验平台,对于推动我国相关领域的重大基础前沿课题的自主研究意义重大.文章对国际上一些重要地下实验室的情况进行了介绍,并对中国锦屏地下实验室的基本情况进行了介绍. 相似文献
9.
地下厂房位置及轴线方向的选择是一项重要的地质工作,本文在分析琅山抽水蓄能电站厂房区工程地质条件的基础上,就厂房位置及其轴线方向的优化选择,进行了分析和研究。 相似文献
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