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Elevated supersaturation of total dissolved gas (TDG) has deleterious effects in aquatic organisms. To minimize the supersaturation of TDG at hydropower dams, spillway flow deflectors redirect spilled water horizontally forming a surface jet that prevents bubbles from plunging to depth in the stilling basin. 相似文献
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Wang Yao Chuan-Jun Lu Li-Wen Zhan Yi Wu Dr. Jia Feng Prof. Dr. Ren-Rong Liu 《Angewandte Chemie (International ed. in English)》2023,62(21):e202218871
The catalytic asymmetric construction of N−N atropisomeric biaryls remains a formidable challenge. Studies of them lag far behind studies of the more classical carbon-carbon biaryl atropisomers, hampering meaningful development. Herein, the first palladium-catalyzed enantioselective C−H activation of pyrroles for the synthesis of N−N atropisomers is presented. Structurally diverse indole-pyrrole atropisomers possessing a chiral N−N axis were produced with good yields and high enantioselectivities by alkenylation, alkynylation, allylation, or arylation reactions. Furthermore, the kinetic resolution of trisubstituted N−N heterobiaryls with more sterically demanding substituents was also achieved. Importantly, this versatile C−H functionalization strategy enables iterative functionalization of pyrroles with exquisite selectivity, expediting the formation of valuable, complex, N−N atropisomers. 相似文献
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