Coadsorption of carbofuran and lead at the water/silica interface. Possible impact on environment

Despite its extremely weak adsorption at the water/silica interface, carbofuran can, however, induce the coadsorption of metallic salts, like, for example, lead nitrate, and thus enhance its adsorption. We quantitatively studied this phenomenon with a depletion method and under concentration conditions close to the environmental ones. Heavy metal salt was found to positively adsorb, whereas carbofuran relative adsorption is generally slightly negative. This study provides evidence that considering these facts is of paramount importance in environmental prospects. To cite this article: G. Elmanfe et al., C. R. Chimie 9 (2006).     

Effect of gleysation on remobilization of radionuclides in waterlogged soils

Joint leaching of iron and other macro- and microelements including radionuclides from radioactively contaminated floodplain soil of the Yenisei River is studied on miniecosystems. In developing anaerobic conditions, the redox potential E_h decreased to +140 mV, causing partial reduction of iron and solubilisation of iron hydrous oxide and organomineral films of the soil. Leaching of stable elements and radionuclides with water proceeds parallel to that of iron. To accelerate reductive mobilization of iron, 0.4% aqueous ascorbic acid was used instead of water as the leaching liquid phase. In this case, E_h approached –60 mV, and the leaching of stable and radioactive elements considerably increased, the effect being most pronounced for plutonium. To cite this article: E.K. Legin et al., C. R. Chimie 7 (2004).

Résumé

Effet du passage en milieu anaérobie sur la mobilisation des radionucléides dans les sols humides. La lixiviation simultanée du fer et d’autres éléments de sols contaminés de la vallée de la rivière Yénései a été étudiée. En imposant des conditions anaérobies, le potentiel redox chute à 140 mV, causant une réduction partielle du fer trivalent et la solubilisation de l’hydroxyde de fer et du film organominéral du sol. Les lixiviations du fer, des autres éléments et, par conséquent, des radionucléides contaminant le sol vont de pair. Pour accélérer la mobilisation réductive du fer, une solution d’acide ascorbique à 0,4% a été utilisée à la place de l’eau. Dans ces conditions, la valeur de E_h approche –60 mV et la lixiviation des éléments augmente considérablement, cet effet étant plus prononcé pour le plutonium. Pour citer cet article : E.K. Legin et al., C. R. Chimie 7 (2004).     

The role of precursors in the structure of SiO2-Al2O3 sols and gels by the sol-gel process

Binary sols and gels of SiO₂-Al₂O₃ were prepared using tetraethyl orthosilicate and each of four aluminum compounds; aluminum di (sec-butoxide) ethylacetoacetic ester chelate (AC), aluminum nitrate nonahydrate (AN), aluminum formoacetate (AF), and boehmite sol (BS) made from aluminum i-propoxide. The structure and the evolution of the Si-O-Al bonds in SiO₂-Al₂O₃ sols and gels were investigated by ²⁷Al nuclear magnetic resonance (NMR), Infrared absorption spectra, DTA, and X-ray diffraction. The formation of Si-O-Al bonds differs depending on the aluminum compounds used as raw materials. The ratio of Al(IV) to {Al(IV) + Al(VI)} is related to the microstructural homogeneity of the gels. When AC is used as a raw material, the Si-O-Al bonds are formed in the sol state and resultant gel shows good microstructural homogeneity. In case of AN, the Si-O-Al bonds are not formed either in the sol or the wet gel state. The bonds are formed by drying the gel before heat-treatment temperature reaches 300 400°C, resulting in good microstructural homogeneous gel. When AF is used, the Si-O-Al bonds are formed in the sol state but the ratio of Al(IV) to {Al(IV) + Al(VI)} is lower than when using AC. Microstructural homogeneity of the gel is ranked between AC or AN and BS. Using BS, the Si-O-Al bonds are not formed in the sol solution, and the change in the coordination number of the gel is similar to that of boehmite gel. The Microstructural homogeneity of the gel is the worst among the BS gels, which were prepared by using the four aluminum raw materials.     

Truth: non-additive measures for the determination of relative density of sands using CPT measurements

In this Note, a fuzzy-integral based approach is developed for aggregating some of the available correlations that are commonly used for determining relative density $D_r$, from cone penetration test (CPT) data, in which non-additive measures are used as fuzzy measures to relate the actual compressibility measured by the friction ratio of sands to the base correlations. The results of the case studied show that fuzzy measures and the fuzzy integral can be utilized for a new approach in geo-technical engineering. To cite this article: C. Tran, C. R. Mecanique 333 (2005).     

An estimate of maximum ground surface motion for non zero surface velocityEstimation du mouvement sismique maximal à la surface du sol pour une celerite d'ondes non nulle en surface

The increasing need for probability seismic hazard assessment (PSHA) of critical facilities sometimes leads to unrealistic earthquake scenarios with very high induced ground motions. From a physical standpoint these high motions cannot exist because of the limiting resistance capacity of the soil strata through which the seismic waves travel. A simple analytical model is proposed to bound the maximum ground surface acceleration that any soil deposit can transfer. This model is an extension to non zero ground surface velocity of a previously presented model. To cite this article: A. Pecker, C. R. Mecanique 332 (2004).     

An estimate of maximum ground surface motionEstimation du mouvement sismique maximal à la surface du sol

The increasing need for probability seismic hazard assessment (PSHA) of critical facilities sometimes leads to unrealistic earthquake scenarios with very high induced ground motions. From a physical standpoint these high motions cannot exist because of the limiting resistance capacity of the soil strata through which the seismic waves travel. A simple analytical model is proposed to estimate a bound to the maximum ground surface acceleration that any soil deposit can transfer. To cite this article: A. Pecker, C. R. Mecanique 331 (2003).     

X-ray microtomography for studying localized deformation in fine-grained geomaterials under triaxial compressionUtilisation de la microtomographie rayon X pour l'étude de la localisation des déformations dans les géomatériaux argileux sous sollicitation axisymétrique.

This Note presents a few selected results of an experimental testing program carried out at the ESRF in Grenoble, France. X-ray microtomography (with a spatial resolution of 14 μm) has been used to evaluate the onset and evolution of shear banding in a fine-grained stiff soil under deviatoric loading. It allowed detailed observations of strain localization in a specimen during the test, including the presence of more than one shear zone and a varying degree of dilatancy and/or crack opening. To cite this article: G. Viggiani et al., C. R. Mecanique 332 (2004).     

三氧化钨溶胶稳定机理及薄膜结构变化特征探讨

本文以钨酸钠阳离子树脂酸化法制备三氧化钨溶胶,采用提拉法成膜,并讲座了溶胶稳定和成膜的机理,通过TG－DTA和IR分析探讨了固体薄在热算是过程中的结构变化,实验结果表明,双氧水和乙醇与钨酸络合,使溶胶稳定,挥发性强的小分子配体（如乙醇）对成膜有利,TG－DTA和IR分析结果表明,随着热处理温度的提高,薄膜中多聚钨酸离子（或者产氧化钨分子簇）进一步缩合,WO6八面对称性逐渐增强。