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1.
Phase Relations and Sodium Ion Conductivity within the Quasi-binary System Na2SiF6/Na2AIF6 . The phase diagram of the Na2SiF6/Na3AlF6 system has been determined by means of x-ray powder diffraction, thermal analysis and conductivity measurements in the sub-solidus region. Na3AlF6 accomodates up to 73 mol.-% Na2SiF6 maintaining the crystal structure type. The sodium ion conductivity increases by about five orders of magnitude upon doping Na3AlF6 with Na2SiF6. 相似文献
2.
Microencapsulation of DNA Within alginate microspheres and crosslinked chitosan membranes for in vivo application 总被引:4,自引:0,他引:4
T. Alexakis D. K. Boadi D. Quong A. Groboillot I. O’Neill D. Poncelet R. J. Neufeld 《Applied biochemistry and biotechnology》1995,50(1):93-106
Calf thymus DNA was microencapsulated within crosslinked chitosan membranes, or immobilized within chitosan-coated alginate
microspheres. Microcapsules were prepared by interfacial polymerization of chitosan, and alginate microspheres formed by emulsification/
internal gelation. Diameters ranged from 20 to 500 Μm, depending on the formulation conditions. Encapsulated DNA was quantifiedin situ by direct spectrophotometry (260 nm) and ethidium bromide fluorimetry, and compared to DNA measurements on the fractions
following disruption and dissolution of the microspheres. Approximately 84% of the DNA was released upon core dissolution
and membrane disruption, with 12% membrane bound. The yield of encapsulation was 96%. Leakage of DNA from intact microspheres/capsules
was not observed. DNA microcapsules and microspheres were recovered intact from rat feces following gavage and gastrointestinal
transit. Higher recoveries (60%) and reduced shrinkage during transit were obtained with the alginate microspheres. DNA was
recovered and purified from the microcapsules and microspheres by chromatography and differential precipitation with ethanol.
This is the first report of microcapsules or microspheres containing biologically active material (DNA) being passed through
the gastrointestinal tract, with the potential for substantial recovery. 相似文献
3.
Hong-Chao Ma 《Applied Surface Science》2006,252(24):8593-8597
In this paper, we found that boron deposited on the surface of support when sodium borohydride used as reducing agent during the preparation of Pt/C catalyst. The deposition of boron markedly reduces particle size of Pt, raises electrochemical active surface (EAS) area of catalyst and electrochemical activity for hydrogen evolution or oxygen reduction reaction (ORR) compared with which prepared using other reducing agents (hydrogen and formaldehyde). 相似文献
4.
5.
海藻酸钠/大豆蛋白共混凝胶微球的结构 总被引:4,自引:1,他引:3
利用钙离子交联海藻酸钠/大豆分离蛋白共混溶液,制得海藻酸钠/大豆分离蛋共混凝胶微球.结果表明,海藻酸钠和大豆分离蛋白质量配比的不同以及各组分间相互作用的变化,微球呈现不同的微观结构.将微球干燥后置于水中溶胀,微球的尺寸无法回复到干燥前的尺寸,这是由于真空干燥处理使水分子挥发,促进微球内组分间形成了强的氢键作用所致.此外,用碱处理该共混微球,发现由于大豆分离蛋白溶解以及部分钙离子被置换析出,微球塌陷且内部形成了大孔. 相似文献
6.
X. Y. Yang H. C. Gao X. L. Tan H. Z. Yuan G. Z. Cheng S. Z. Mao S. Zhao L. Zhang J. Y. An J. Y. Yu Y. R. Du 《Colloid and polymer science》2004,282(3):280-286
1H chemical shift changes of sodium 4-decyl naphthalene sulfonate (SDNS) at 313 K show that its critical micellar concentration lies between 0.82 and 0.92 mmol/dm3, which is in the same range as that of the previous study at 298 K. The spin–lattice relaxation time, spin–spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy experiments give information about the structure of the SDNS micelle and the dynamics of the molecules in the micelle. The size of the SDNS micelle remains almost unchanged in the temperature range from 298 to 313 K as deduced by analyzing the self-diffusion coefficient. Special arrangement of the naphthyl rings of SDNS in the micelles affects the packing of these hydrophobic chains. The methylene groups of the alkyl chain nearest the naphthalene groups penetrate into the aromatic region, which results in a more tightly packed hydrophobic micellar core than that of sodium dodecyl sulfonate. 相似文献
7.
Using the full-potential linearized augmented plane wave (FP-LAPW) method, we have studied the effect of chemistry on the average intercalation voltage (AIV) caused by the Na ions intercalating into transition metal oxides. The effect of transition metal was systematically studied by varying M=Co, Ni and Mn in NaMO2 and fixing the α-NaFeO2 layered structure. The effect of the guest atoms into the host material is discussed in terms of the structural and electronic properties. Comparatively to Li intercalation, a significant electron transfer towards transition metal was found. This observation suggests that the transition metal contribute to the AIV determination and confirms the common assumption that intercalated electron reduces M4+ to M3+. 相似文献
8.
Ti(IV) as TiCl3(O3SCF3) and TiO(O2CCF3)2 are used as efficient catalysts for oxidative coupling of aliphatic, aromatic and heteroaromatic thiols to their disulfides in the presence of NaI under air atmosphere. 相似文献
9.
环丙沙星在胶束体系中的荧光特性研究及应用 总被引:9,自引:1,他引:8
研究了环丙沙星在胶束体系中的荧光性质,发现十二烷基硫基酸对环丙沙星有较强的增敏作用。据此建立了胶束增敏荧光光谱法测定痕量环丙沙星的新方法,经样品测定,其线性范围为0.033-0.60μg.mL^-1,检出限为0.033μg.mL^-1,回收率为94.0%-98.1%相对标准偏差为1.5%-2.8%。 相似文献
10.
A new flow electrical conductance instrument was constructed and tested on dilute NaCl solutions up to 458 K, and on more
concentrated solutions (maximum 0.436 mol⋅kg−1) at 373 K. The results of the new instrument agreed with those of previous authors within the estimated experimental errors.
The model of Bernard et al. (J. Phys. Chem. 96, 3833–3840 (1992), MSA) was found to represent the high-temperature results without introducing an ion-pairing equilibrium constant. The Fuoss–Hsia
conductance equation as given by Fernandez-Prini was found to represent the dilute concentrations with Λ° (NaCl) as the only adjustable parameter. It was found that Λ° (NaCl) could be expressed as a function of solvent viscosity and density by using three parameters found by regression of
literature results between 278.15 and 523 K. This equation along with the FHFP theory permits the equivalent conductivity
of dilute sodium chloride solutions to be calculated within the accuracy of the existing experimental measurements. 相似文献