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1.
The existence of global smooth solutions to the multi-dimensional hydrodynamic model for plasmas of electrons and positively charged ions is shown under the assumption that the initial densities are close to a constant. The model consists of the conservation laws for the particle densities and the current densities, coupled to the Poisson equation for the electrostatic potential. Furthermore, it is proved that the particle densities converge exponentially fast to the (constant) steady state. The proof uses a higher-order energy method inspired from extended thermodynamics.  相似文献   
2.
New developments in inductively coupled plasma mass spectrometry (ICP-MS) and laser desorption-time-of-flight mass spectrometry (LD-TOF-MS) for inorganic analysis are described. These include fundamental studies of the ion extraction, process in ICP-MS, development of a highly efficient nebulizer, isotope tracer studies, measurement of elemental speciation by liquid chromatography with ICP-MS detection and characterization of the structures of solids by ion association. The possibilities of determining inorganic species in solutions by electrospray MS are also described.  相似文献   
3.
In this work, surface-enhanced Raman scattering (SERS)-active gold substrates were first developed by combining the technologies of oxidation–reduction cycles (ORCs) and plasmas treatments in roughening metal substrates. First, a gold substrate was treated by argon plasmas. Then the treated gold substrate was further roughened by triangular-wave ORCs in an aqueous solution containing 0.1 M HCl. Encouragingly, the SERS of Rhodamine 6G (R6G) adsorbed on this roughened gold substrate modified by argon plasmas pretreatment exhibits a higher intensity by 10-fold of magnitude and a better resolution, as compared with the SERS of R6G adsorbed on an unmodified roughened gold substrate. Meanwhile, the probing concentration of R6G adsorbed on the modified substrate can be reduced by one order. It was also found that the pretreatment of argon plasmas demonstrates a positive effect on the (2 2 0) face of Au partly changing into the (1 1 1) face with the lowest surface energy after the ORCs roughening, which is contributive to the improved SERS observed.  相似文献   
4.
Inductively coupled plasma mass spectrometry (ICP-MS) was used in an isotope dilution mode to assay small-volume (0.25 ml) sediment pore waters for their uranium contents, using 236U as the spike. The only pretreatment required was a simple dilution by a factor of 20, which gave sufficient volume for three replicate analyses per sample. Rapid and accurate results were obtained for a variety of samples and standards, ranging in concentration from 0.05 to 10 ng U ml?1. A suite of 30 samples can be analysed in less than 6 h by this method. The relative standard deviation was better than 1.9%, with a detection limit, based on 3σ background, of 2 pg U ml?1 in solution (40 pg ml?1 in samples). Sea water is a difficult matrix for ICP-MS and thus the method is generally suitable for uranium determinations in many other sample solutions.  相似文献   
5.
This paper is concerned with nonisentropic hydrodynamic models for two-carrier plasmas, which take the form of Euler equations for conservation laws of mass density, current density and energy density for two-carrier plasmas, coupled to Poisson’s equation for self-consistent electronic field. Due to the nonlinear coupling and cancellation between electrons and ions, the expected dissipation rates of densities for two carriers are no longer available in comparison with the one-carrier case, which leads to the lack of exponential stability near constant equilibrium in the whole space. In order to capture the weaker dissipation and obtain global solutions in spatially critical Besov spaces, calculus techniques which have been recently developed in Chemin–Lerner spaces, will be further applied.  相似文献   
6.
The triggering and guiding of high voltage discharge by plasma filaments generated by 400 nm and 800 nm femtosecond laser were studied experimentally. The detailed diagnostics for characteristics of filaments, such as amount of free electrons, diameter and electron density, were performed using sonographic method, fluorescence imaging and resistivity measurement. A significant reduction of the breakdown voltage threshold due to the pre-ionization of the air gap by laser pulse filaments was observed. It is shown that the 400 nm laser pulses demonstrated stronger triggering ability than 800 nm laser pulse under same pulse energy. This behavior of 400 nm femtosecond pulse is connected to the rich population of highly excited particles in filaments.  相似文献   
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8.
The recent progress in plasma medicine as well as biomedical aspects of plasma physics over the last years have enhanced the need for experimental plasma devices which are capable of producing non‐thermal atmospheric pressure plasmas. These plasma sources are used for studying the effect of non‐thermal plasmas on biological samples of different nature. In this paper we present such an easy to build low cost apparatus that can be used for scientific as well as for educational purposes. Directions for the construction of the device are given and the basic plasma parameters are investigated. The characterisation of the experiment was done by electrical diagnostics for the measurements of the plasma potential in combination with optical emission spectroscopy. The latter is used for the determination of the excitation temperature of the plasma and the electron density. Furthermore the influence of the produced plasma on yeast cells is demonstrated. The produced plasma is characterised in different ways and it was found that the feeding gas has also a considerable impact on the radio frequency wave form of the source. It is also demonstrated that the constructed plasma source is capable of producing non‐thermal plasma that hinder cell growth of yeast colonies on a agar substrate. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
9.
Direct analysis of rocks by laser ablation inductively coupled plasma mass spectrometry is described. Both powdered standard rocks and the original rocks were analysed and the results agreed with each other in spite of the difference in the surface states. Microprobe analysis of biotite in granite JG1 was also done directly with a focused laser beam and the results obtained were very close to the solution values given by the conventional aqueous method using biotite separated from an original rock. For quantitative analysis, the measured signal intensity was normalized either by the ablated weight or the barium signal intensity. Forty-two major and minor elements (two of them being used as internal standards) in twelve standard rocks fromt the igneous rock series of the Geological Survey of Japan were determined successfully.  相似文献   
10.
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