全文获取类型
收费全文 | 330篇 |
免费 | 12篇 |
国内免费 | 26篇 |
专业分类
化学 | 41篇 |
力学 | 192篇 |
数学 | 54篇 |
物理学 | 81篇 |
出版年
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 10篇 |
2019年 | 5篇 |
2018年 | 8篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 10篇 |
2014年 | 21篇 |
2013年 | 25篇 |
2012年 | 26篇 |
2011年 | 39篇 |
2010年 | 20篇 |
2009年 | 21篇 |
2008年 | 22篇 |
2007年 | 17篇 |
2006年 | 12篇 |
2005年 | 15篇 |
2004年 | 11篇 |
2003年 | 7篇 |
2002年 | 8篇 |
2001年 | 14篇 |
2000年 | 7篇 |
1999年 | 10篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1980年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有368条查询结果,搜索用时 15 毫秒
1.
The oscillating conditions for a series piezoelectric quartz crystal (SPQC) are proposed and verified experimentally. The influence of the cell constant and oscillator phase on the oscillational ability of the SPQC was investigated. It is shown that the SPQC possesses excellent oscillational ability in low or high conductivity solutions, but in solution of intermediate conductivity, the oscillational ability decreases with increasing oscillator phase or decreasing cell constant, sometimes resulting in a cease-to-oscillate zone. The SPQC was applied to determine the urease activity in plant seeds with a detection limit of 0.004 U ml−1, based on the change in conductivity. 相似文献
2.
A new analytical method for the determination of uric acid (UA) by the perturbation of UA on the Belousov-Zhabotinsky oscillating reaction is proposed. The method is based on the linear relationship between the changes in the oscillating period and the concentration of UA. The calibration curve is linear over the range of 2.0 × 10−5 to 5.0 × 10−4 M, with a detecting limit of 3.28 × 10−6 M. The method features good precision (R.S.D.: 3.59%) and excellent throughput (10 samples h−1). The possible mechanism of the perturbation of UA on the oscillating reaction is discussed. 相似文献
3.
R. Bruce King 《Theoretical chemistry accounts》1980,56(4):269-296
The following procedure is described for investigating the qualitative dynamics of simple chemical systems: 1) A so-called influence diagram is generated representing the relationships between the reference reactants (phase-determining intermediates); 2) This influence diagram is used to generate a truth table indicating possible transitions between state vectors representing the signs of the time derivatives of of the reference reactant concentrations; 3) The truth table is used to determine a state transition diagram representing the flow topology around unstable equilibrium points; 4) The characteristic equation of the adjacency matrix of the influence diagram is solved in order to determine the presence of such unstable equilibrium points. The two types of qualitative dynamics possible for chemical systems containing two reference reactants and one feedback circuit are bifurcation between two attracting regions (bistability) and limit cycle oscillation. However, in two reference reactant systems oscillation requires an additional self-activating loop to generate the unstable equilibrium point required for its realization. Bistability and limit cycle oscillation are also two of the possible types of qualitative dynamics for chemical systems containing three reference reactants. However, chemical systems with three reference reactants and two or more feedback circuits can also contain interlocking limit cycles, which can lead to toroidal oscillations or chaos. The influence diagrams are given for the systems exhibiting these various types of dynamic behavior along with a summary of the important properties of all 729 possible influences for simple chemical systems containing three reference reactants. 相似文献
4.
Yalan Ning Megan J. Cooney Eugene Y.-X. Chen 《Journal of organometallic chemistry》2005,690(26):6263-6270
Characteristics of methyl methacrylate (MMA) polymerization using oscillating zirconocene catalysts, (2-Ph-Ind)2ZrX2 (X = Cl, 1; X = Me, 2), mixtures of rac- and meso-zirconocene diastereomers, (SBI)ZrMe2 [3, SBI = Me2Si(Ind)2] and (EBI)ZrMe2 [4, EBI = C2H4(Ind)2], as well as diastereospecific metallocene pairs, rac-4/Cp2ZrMe2 (5) and rac-4/CGCTiMe2 [6, CGC = Me2Si(Me4C5)(t-BuN)], are reported. MMA polymerization using the chloride catalyst precursor 1 activated with a large excess of the modified methyl aluminoxane is sluggish, uncontrolled, and produces atactic PMMA. On the other hand, the polymerization by a 2/1 ratio of 2/B(C6F5)3 or 2/Ph3CB(C6F5)4 is controlled and produces syndiotactic PMMA. Mixtures of diastereomeric ansa-zirconocenes 3 or 4 containing various rac/meso ratios, when activated with B(C6F5)3, yield bimodal PMMA; this behavior is attributed to the meso-diastereomer that, in its pure form, affords bimodal, syndio-rich atactic PMMA. For MMA polymerization using diastereospecific metallocene pairs, rac-4/5 and rac-4/6, the isospecific catalyst site dominates the polymerization events under the conditions employed in this study, and the aspecific and syndiospecific sites are largely nonproductive, thereby forming only highly isotactic PMMA. 相似文献
5.
This paper focuses on the further development of a previously published semi-empirical method for time domain simulation of vortex-induced vibrations (VIV). A new hydrodynamic damping formulation is given, and the necessary coefficients are found from experimental data. It is shown that the new model predicts the observed hydrodynamic damping in still water and for cross-flow oscillations in stationary incoming flow with high accuracy. Next, the excitation force model, which is one component of the total hydrodynamic force model, is optimized by simulating the VIV response of an elastic cylinder in a series of experiments with stationary flow. The optimization is performed by repeating the simulations until the best possible agreement with the experiments is found. The optimized model is then applied to simulate the cross-flow VIV of an elastic cylinder in oscillating flow, without introducing any changes to the hydrodynamic force modeling. By comparison with experiment, it is shown that the model predicts the frequency content, mode and amplitude of vibration with a high level of realism, and the amplitude modulations occurring at high Keulegan–Carpenter numbers are well captured. The model is also utilized to investigate the effect of increasing the maximum reduced velocity and the mass ratio of the elastic cylinder in oscillating flow. Simulations show that complex response patterns with multiple modes and frequencies appear when the maximum reduced velocity is increased. If, however, the mass ratio is increased by a factor of 5, a single mode dominates. This illustrates that, in oscillating flows, the mass ratio is important in determining the mode participation at high maximum reduced velocities. 相似文献
6.
氨基酸-BrO-3-Mn2+-H2SO4-丙酮体系的振荡反应 总被引:7,自引:3,他引:7
This paper, Using potentiometric method, first reports the oscillating behavior of five amino acids (L-methionine, L-cystine, L-tryptophan, L-serine, L-tyrosine) in a new oscillating system of amino acid-BrO_3~--Mn~(2+)-H_2SO_4-acetone. The effect of many factors on oscillation have been investigated. According to Arrhenius equation, the apparent activation energy of the oscillatary induction period and oscillation period of five oscillating systems are obtained within temperature range of 20~37 ℃. 相似文献
7.
8.
When solving unsteady computational fluid dynamics problems in aerodynamics with a gridless method, a cloud of points is usually required to be regenerated due to its accommodation to moving boundaries. In order to handle this problem conveniently, a fast dynamic cloud method based on Delaunay graph mapping strategy is proposed in this paper. A dynamic cloud method makes use of algebraic mapping principles and therefore points can be accurately redistributed in the flow field without any iteration. In this way, the structure of the gridless clouds is not necessarily changed so that the clouds regeneration can be avoided successfully. The spatial derivatives of the mathematical modeling of the flow are directly determined by using weighted least‐squares method in each cloud of points, and then numerical fluxes can be obtained. A dual time‐stepping method is further implemented to advance the two‐dimensional Euler equations in arbitrary Lagarangian–Eulerian formulation in time. Finally, unsteady transonic flows over two different oscillating airfoils are simulated with the above method and results obtained are in good agreement with the experimental data. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
9.
《Wave Motion》2015
The linearised water-wave radiation problem for the oscillating 2D submerged source in an inviscid shear flow with a free surface is investigated analytically. There is a nonzero surface velocity. The depth is infinite and the vorticity is uniform. The amplitudes radiated from the source are calculated analytically. Due to Doppler effects, there may be up to four different emitted waves, and there is resonance with zero group velocity and infinite amplitude. 相似文献
10.
This paper presents a local domain‐free discretization (DFD) method for the simulation of unsteady flows over moving bodies governed by the incompressible Navier–Stokes equations. The discretization strategy of DFD is that the discrete form of partial differential equations at an interior point may involve some points outside the solution domain. All the mesh points are classified as interior points, exterior dependent points and exterior independent points. The functional values at the exterior dependent points are updated at each time step by the approximate form of solution near the boundary. When the body is moving, only the status of points is changed and the mesh can stay fixed. The issue of ‘freshly cleared nodes/cells’ encountered in usual sharp interface methods does not pose any particular difficulty in the presented method. The Galerkin finite‐element approximation is used for spatial discretization, and the discrete equations are integrated in time via a dual‐time‐stepping scheme based on artificial compressibility. In order to validate the present method for moving‐boundary flow problems, two groups of flow phenomena have been simulated: (1) flows over a fixed circular cylinder, a harmonic in‐line oscillating cylinder in fluid at rest and a transversely oscillating cylinder in uniform flow; (2) flows over a pure pitching airfoil, a heaving–pitching airfoil and a deforming airfoil. The predictions show good agreement with the published numerical results or experimental data. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献