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1.
Wacker oxidation is an industry-adopted process to transform olefins into value-added epoxides and carbonyls. However, traditional Wacker oxidation involves the use of homogeneous palladium and copper catalysts for the olefin addition and reductive elimination. Here, we demonstrated an ultrahigh loading Cu single atom catalyst(14% Cu, mass fraction) for the palladium-free Wacker oxidation of 4-vinylanisole into the corresponding ketone with N-methylhydroxylamine hydrochloride as an additive under mild conditions. Mechanistic studies by 18O and deuterium isotope labelling revealed a hydrogen shift mechanism in this palladium-free process using N-methylhydroxylamine hydrochloride as the oxygen source. The reaction scope can be further extended to Kucherov oxidation. Our study paves the way to replace noble metal catalysts in the traditional homogeneous processes with single atom catalysts. 相似文献
2.
Kurt Majewski 《Queueing Systems》2005,50(2-3):199-230
We consider multiclass feedforward queueing networks under first in first out and priority service disciplines driven by long-range dependent arrival and service time processes. We show that in critical loading the normalized workload, queue length and sojourn time processes can converge to a multi-dimensional reflected fractional Brownian motion. This weak heavy traffic approximation is deduced from a deterministic pathwise approximation of the network behavior close to constant critical load in terms of the solution of a Skorokhod problem. Since we model the doubly infinite time interval, our results directly cover the stationary case.AMS subject classification: primary 90B15, secondary 60K25, 68M20 相似文献
3.
In this paper we describe the design and manufacture of an axial-torsion test specimen, and provide relationships needed when
conducting stress-strain characterization experiments with the specimen. The specimen is a short hollow cylinder of rubber
bonded between two steel mounting rings, in which simultaneous axial and shear strains are produced via independently controlled
axial and twist displacements. We present calculations for the strain-displacement and stress-load relationships, and strain
energy density. These relationships have been established and validated via a combination of analytical and experimental techniques,
and finite element analysis. We have investigated the extent and effects of strain and stress field non-uniformity in the
test specimen. The specimen design is sufficiently simple that a closed-form expression for the strain-displacement relationship
has been successfully developed. 相似文献
4.
应用电磁线路中涨落耗散理论,推导了不同温度均匀二半空间接触后产生辐射场密度的公式。将此公式近似展开后,即得Grover和Urtiew所获得的表示式,不过多了一松弛项,该项如用非富里叶热传导理论推导,也是存在的。该结果和实验结果一致,不过这里的松驰时间可以应用介质性质进行计算。 相似文献
5.
S.T. Mileiko V.M. Kiiko K.A. Khvostunkov 《Theoretical and Applied Fracture Mechanics》2006,45(1):41-45
A micromechanical model of island-type fibre/matrix interface is described and experimental data are represented and analysed. Changes in the interface strength during a cycle loadings and, correspondingly, changes in the creep resistance of a composite due the island-like scheme of the fibre/matrix interface are described. 相似文献
6.
本文以金属指示剂甲基百里(香)酚蓝作为鳌合剂制得具有相应鳌合基团的负载树脂.研究了该树脂的某些分析特性及其在富集天然水中微量铜、钻、镍、锌中的应用. 相似文献
7.
程治国 《宁波大学学报(理工版)》2004,17(1):28-31
提出了在无外力作功的情况下,具有Bauschinger效应的弹塑性材料处于屈服状态产生自发的塑性流动时应满足的条件.这个条件不仅与材料的力学性能有关,而且还处决于材料的具体的载荷边界条件和变形.举例说明了承受拉一扭组合的薄壁圆筒中,采用组合强化模型时,产生塑性流动的具体条件. 相似文献
8.
冲击载荷下剪切断裂研究 总被引:1,自引:0,他引:1
利用Hopkinson压杆技术对单边平行双裂纹试样倒向加载,在较大的加载率范围,对Ti6Al4V钛合金和40CrNiMoA两种材料的动态剪切断裂行为进行了研究.实验结果表明:存在两类韧性剪切断裂模式,即常规的韧性剪切型断裂和绝热剪切断裂.常规剪切型断裂模式的断裂韧性KⅡd随加载率的提高而增大,而绝热剪切型的断裂韧性KⅡd则随加载率的提高而减小,并且,当加载率增大至某一临界值时,常规的韧性剪切断裂模式将转变为绝热剪切断裂破坏模式. 相似文献
9.
C.Q. Ru 《International Journal of Non》2003,38(4):521-530
This paper gives an asymptotic analysis of the deformation field near the tip of an arbitrary mixed-mode crack in a compressible hyperelastic harmonic material which loses ellipticity at sufficiently large deformations. It is found that the near-tip deformation field is characterized by a localized non-elliptic deformation band issuing from the crack-tip and bounded by two curves of discontinuous deformation gradient. Explicit expression for the near-tip deformation field is obtained both inside and outside the localized deformation band. In particular, a simple relation is derived that determines the orientation of the deformation band in terms of two complex governing parameters of the near-tip fields inside and outside the deformation band, respectively. 相似文献
10.
This paper addresses the problem of determining stowage plans for containers in a ship, that is the so-called master bay plan problem (MBPP). 相似文献