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1.
We report a comprehensive analyzes of the Fourier transform infrared (FTIR) absorption and Raman scattering data on the structural and vibrational properties of dilute ternary GaAs1−xNx,[GaP1−xNx] (x<0.03) alloys grown on GaAs [GaP] by metal organic chemical vapor deposition (MOCVD) and solid source molecular beam epitaxy (MBE). By using realistic total energy and lattice dynamical calculations, the origin of experimentally observed N-induced vibrational features are characterized. Useful information is obtained about the structural stability, vibrational frequencies, lattice relaxations and compositional disorder in GaNAs (GaNP) alloys. At lower composition (x<0.015) most of the N atoms occupy the As [P] sublattice {NAs[NP]}—they prefer moving out of their substitutional sites to more energetically favorable locations at higher x. Our results for the N-isotopic shifts of local mode frequencies compare favorably well with the existing FTIR data. 相似文献
2.
3.
主要研究在高空核爆的双指数类型电磁脉冲平面波入射时,地面附近的电磁脉冲环境。计算给出了在不同入射波状态,不同地表介质电气特性和距地面不同高度等条件下的电磁脉冲环境参数,归纳了一些规律性认识。结果显示:地面附近的电场会随距地面高度的不同而发生显著的变化,对于水平场分量,其反射场总是试图抵消入射场,而对于垂直场分量,其反射场叠加在入射场上,使得地面附近的垂直场强幅值一般大于入射波场强幅值;当入射波仰角增大时,合成电场波形的脉冲宽度会变宽;地表介质的电气特性参数不同也会对地面附近电场的波形和幅值造成一定的影响。 相似文献
4.
E. A. Sokolov S. D. Babenko N. P. Piven’ A. N. Ponomarev 《Russian Chemical Bulletin》1997,46(4):826-828
Experimental results related to the transition of spontaneous polymerization of acrylamide complexes with metal nitrates to
the “explosive” regime at room temperature are presented. It is suggested that the “explosion” has a thermal nature.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 859–861, April, 1997. 相似文献
5.
Denisov V. I. Denisova I. P. Svertilov S. I. 《Theoretical and Mathematical Physics》2004,138(1):142-149
We consider the effect that the gravitational field of a neutrino pulse radiated in the collapse of presupernova nuclei has on the observable optical radiation spectra of atoms at the supernova surface. We show that at the modern level of development of experimental methods, neutrino monitoring supplemented by optical monitoring of supernova candidates provides a unique possibility to check whether the Einstein equivalence principle is satisfied for neutrinos of each of the three types (electron, muon, and tau-lepton) and their antiparticles, to estimate the change of the gravitational potential at the surface of the star at the instant of the neutrino radiation pulse, and to obtain upper limits on the mass values of these neutrinos in a new way. 相似文献
6.
Summary Nonstationary regimes of the wave turbulence evolution are considered in the framework of isotropic kinetic equation. It is
predicted analytically and confirmed by numerical experiment that there is a class of wave systems in which any initial distribution
of the turbulence energy ink-space comes into a universal, Kolmogorovtype spectrum in a finite time. Before and after the formation of the Kolmogorov
spectrum, two different self-similar regimes of evolution occur: the first one is responsible for explosively forming the
universal spectrum and the second one determines energy dissipation. 相似文献
7.
V. N. Manuilov T. Idehara M. Kamada T. Hayashi La Agusu T. Kanemaki K. Yatsui Wiehua Jiang 《International Journal of Infrared and Millimeter Waves》2006,27(9):1183-1193
High power Large Orbit Gyrotron (LOG) [1] is now under development at FIR FU. First version of this device was recently manufactured
and then assembled with power supply ETIGO-IV [2]. Results of preliminary tests of electron-optic system are presented. The
conditions when stableflat form of current pulse realized are discussed. Analytical estimations of cathode-anode distance
to achieve small influence of cathode plasma during high voltage (HV) pulse are performed.
Two new electron gun versions with decreased influence of the cathode plasma on its impedance and pulse form are suggested
and optimized. New optimal magnetic field distributions are found. First gun has quiasi-flat cathode configuration near the
anode diaphragm and provides operating current about 60 A. Second one uses blade cathode with operating current about 30 A.
Beam quality for both guns is suitable for LOG operation. 相似文献
8.
The parallel between orbital first and second electric moments and statistical first and second central moments is noted. Three measures of orbital spatial distribution in terms of their moments are proposed, and applied to the LMO's in a series of ten-electron hydrides. Consistent differences between bond and lone pair distributions are found. Using the statistical interpretation, for each LMO an effective solid angle around the central atom is postulated. 相似文献
9.
R.-L. Yun Y.-M. Chang C.-H. Lin K.-H. Hu C.-M. Shu 《Journal of Thermal Analysis and Calorimetry》2006,85(1):107-113
In industrial processes, information
on the safety property of chemicals is essentially crucial for safe handling
during unit operations. Ensuring the safe use of combustible or flammable
substances in processes is unlikely without detailed investigations of their
flammability characteristics and related hazards. We studied 3-methyl pyridine
(3-picoline), e.g., flammability limits (LFL/UFL), maximum explosion pressure
(P
max), maximum
explosion pressure rise (dP/dt)max, minimum oxygen concentration
(MOC), vapor deflagration index (K
g),
and characterized the influence of inert steam (H2O)
on critical parameters for 3-picoline/water mixtures at 270°C, 1 atm,
various oxygen concentrations, and vapor mixing ratios (100/0, 30/70, 10/90
and 5/95 vol.%) with a 20-L-Apparatus in simulated conditions, respectively.
The results showed that the flammability characteristics
of 3-picoline(aq) all increased with the oxygen concentration.
However, as the composition of inert steam increased, the flammability parameters
and the degree of fire and explosion hazards were significantly reduced, instead.
This study elucidated the flammability properties of 3-picoline mixed with
inert steam. The conclusions could be applied to proactively prevent the relevant
processes from incurring fire and explosion accidents. 相似文献
10.
The transferability of the first and second order electric moments of localized orbitals have been shown. Some moment characteristics have also been investigated. The standard deviation of first order localized moments is less than 2.0%. The standard deviation of second order electric moment components are larger: although they do not exceed 4.0% for bond orbitals, for lone pair ones they vary about 1.5–10.1%. 相似文献