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1.
We report a facile and rapid method for fabrication of composite particles consisting of a polystyrene (PS) core and a uniform silver shell. The process involves the PS colloid surface swelling, the anchoring of silver ions and nanoparticles onto the surfaces, and the subsequent growth of metal seeds in a short period. The present approach has the advantages of simplicity and high efficiency. The TEM images show the morphology of the obtained PS core-silver shell particles, and their chemical composition and crystallinity are analysed by x-ray diffraction. To our knowledge, this is the first study based on swelling PS surface for synthesis of silver-coated PS particles and may be implemented for preparing other metal-coated PS particles. 相似文献
2.
采用本体聚合技术合成全氘代聚苯乙烯(DPS),所得聚合物分子量约250000,分散度约3,氘代率为98.7%。采用热诱导相分离技术制备全氘代聚苯乙烯泡沫。在室温溶解DPS于溶剂中,然后转入轴向冷却模具,进行单向冷却,直到溶剂完全冷冻,最后取出冷冻样置于冷冻干燥仪中进行冷冻干燥,待溶剂完全脱出后即得泡沫。通过对二恶烷/环己烷混合溶剂相图,以及PS一混合溶剂体系的相图的测定, 相似文献
3.
The polyacrylic acid functionalized polystyrene nanospheres were synthesized and self-assembled into irregular, densely packed monolayers in non-aqueous media. The polymer nanoparticles were chemically adhered to substrates. The morphologies of the resulting films were investigated. The impact of the volume fraction of alcohol in the mixed solvents on the particle adsorption and fabrication of nanosphere assembled films was examined. 相似文献
4.
Self-assembly behaviour of amphiphilic diblock copolymer in selective solvents studied by synchrotron small-angle x-ray scattering 下载免费PDF全文
The aggregation behaviour of styrene-vinyl benzoic acid (PSm-b-PVBAn) amphiphilic diblock copolymers in selective solvents with different m and n was investigated by synchrotron small-angle x-ray scattering (SAXS). We have carried out a detailed analysis of scattering intensity, dimension, shape and microstructure of the diblock copolymers of narrow distribution in water, methanol, ethanol and isopropanol selective solvents, respectively. We have found that the aggregation behaviour of the copolymer depends on the nature of the solvent and the micelle forms fiat disc objects with the ratio of radius ω=0.4. The average radius gyration Rg of the copolymer decreases as solvents change from isopropanol to ethanol and to methanol, and increases with increasing pH in aqueous solution, but decreases with the addition of COCl2 in ethanol solvent. The scattering intensity of diblock copolymer micelle follows I(h) ∝ h^-α in different selective solutions, suggesting that the PSm-b-PVBAn coils have self-similar structure behaviour or a fractal structure in the selective solvents. All of these revealed that the aggregation behaviour of the diblock copolymer changes dramatically with experimental condition in the selective solvent. The increase of mass fractal dimension (Dm) from 2.12 to 2.47 indicates that the copolymer chain changes from a swollen coil to a rather compact disc in the course of changing solvents, decreasing surface fractal dimension (Ds) from 2.98 to 2.58 indicates that the copolymer micelle change from a rather rough surface to a smooth form in the course of increasing pH in aqueous solutions, and increasing Dm and Ds from 2.29 to 2.35 and 2.70 to 2.90, respectively, indicates the shrinkage of copolymer micelle to a rather compact and rough disc form by adding COCl2 in ethanol solvents. 相似文献
5.
用HAAKE、DSC、IR等方法研究了侧基含有过氧键的反聚苯乙烯与LDPE之间的反应,并将其应用到LDPE/PS共混体系。考察了不同添加方式,交联助剂等对共混物力学性能、流变性能及微观结构的影响。 相似文献
6.
The abnormal transmittance in the dielectric band edge of a polystyrene opal is observed and analysed. The transmittance is periodically modulated and the period of modulation varies with the wavelength, which destroys the perfect structure of the photonic band gap. The transmittance modulation originates from the propagation of the low order whispering-gallery mode excited in polystyrene spheres. These results indicate that the whisperinggallery mode has a great influence on practical applications of polystyrene opal. 相似文献
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Polystryene-supported benzly selenide has been prepared.This novel reagent was treated with LDA to produce a selenium stabilized carbanion,which reacted with alkyl halide,followed by selenoxide syn-elimination,to give substituted olefins stereospecificly. 相似文献
10.
聚苯乙烯磺酰氯和聚苯乙烯亚磺酸盐的合成及其应用 总被引:1,自引:0,他引:1
本文以36篇文献,包括作者近年的工作,综述了聚苯乙烯磺酰氯和聚苯乙烯亚磺酸盐的合成方法和这些功能基化聚合物在有机合成及其他方面的应用。 相似文献