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1.
Electron spin resonance spectra of Mn2+ in diluted solid solutions of MnO2 in Y2O3 have been studied at room temperature for Mn concentrations between 0.20 and 2.00 mol%. Isolated Mn2+ ions in sites with two different symmetries were observed, as well as Mn2+ ions coupled by the exchange interaction. The relative concentration of isolated to coupled Mn2+ ions decreases with increasing manganese concentration. The results are consistent with the assumption that the manganese ions occupy preferentially the C2 symmetry sites. A theoretical calculation based on this model yields an effective range of the exchange interaction between Mn2+ ions of 0.53 nm, of the same order as that of Mn2+ ions in CaO. 相似文献
2.
H.S RagabA Shehap M.S Abo EllilW.H Osman F.H Abd El-Kader 《Journal of Physics and Chemistry of Solids》2002,63(10):1839-1847
Ternary-phase ceramic system of Li2O Al2O3 4SiO2 doped with CuO, FeO and TiO2 has been prepared and subjected to dc electrical conductivity and thermally stimulated depolarization current (TSDC) measurements as a function of temperature (30-250 °C) and field strength. The electrical conductivity results are explained by assuming both ionic and electronic conduction mechanisms coexist with different contributions over the whole temperature range of experiments. TSDC spectra have been found to be characterized by a broad intense relaxation peak, which can be attributed to an ionic charge polarization. The broad relaxation transitions are apparently a result of the nonuniform nature of this process. Activation energies are calculated for both dc electrical conductivity and TSDC according to Arrhenius equation and initial rise method, respectively. 相似文献
3.
V.B. Nalbandyan 《Journal of Physics and Chemistry of Solids》2004,65(6):1201
The irreproducibility of electrical properties of Na0.88Li0.12NbO3 solid solution on thermal cycling reported by M.A.L. Nobre and S. Lanfredi is explained by gradual decomposition of the supersaturated solid solution below ca. 800 °C. 相似文献
4.
The cation distribution in spinel-related titanium-substituted lithium ferrite, Li0.5+0.5xFe2.5−1.5xTixO4 has been explored using interatomic potential and ab initio calculations. The results suggest that the cation distribution with Ti4+ substituting for Fe3+ on octahedral B sites and excess Li+ substituting for Fe3+ on tetrahedral A sites is stabilised by the formation of clusters of two octahedrally coordinated Ti4+ ions and one tetrahedrally coordinated Li+ ion linked through a common oxygen. 相似文献
5.
Cr-doped mullites were prepared from single-phase precursors containing up to 9.60 wt% Cr2O3 using a sol-gel technique followed by thermal treatment. Particle induced X-ray emission spectroscopy and X-ray powder diffraction were used to characterize the samples. Mullites were orthorhombic, space group Pbam. Cr doping caused the increase of unit-cell parameters. Strongest expansion was noticed along c-axis followed by a and b (Δc/c=0.089, Δa/a=0.061, Δb/b=0.045% per mole Cr2O3). A second phase, namely θ-(Al,Cr)2O3, was revealed by XRD in the sample containing 9.60 wt% Cr2O3. The structure of mullites was refined by the Rietveld method, location of Cr3+ was performed by the EPR spectroscopy. At low chromium doping level (Cr2O3 content less than ∼5 wt%) Cr3+ ions were substituted for Al3+ in the AlO6 octahedra of the mullite structure (M1 site). For higher doping level, Cr3+ ions were additionally substituted for Al3+ in the AlO6 octahedra of the second phase [θ-(Al,Cr)2O3 at 1400 °C, or α-(Al,Cr)2O3 at 1600 °C] which segregated in the system. Substitution of Cr3+ for Al3+ on M1 site in the mullite structure resulted in increase of average distances in (M1)O6 octahedron and decrease of average distances in T*O4 tetrahedron, while average distances in TO4 tetrahedron stayed almost constant. 相似文献
6.
Low-temperature property investigation of the lead indium-niobate-lead nickel-niobate solid solution
Edward F AlbertaAmar S Bhalla 《Journal of Physics and Chemistry of Solids》2002,63(9):1759-1769
The complex perovskite solid solution (1−x) Pb(In1/2Nb1/2)O3-(x) Pb(Ni1/3Nb2/3)O3 has been successfully prepared by the Columbite precursor method. The temperature dependencies of the dielectric constant and pyroelectric coefficient were measured between −261 and 200 °C. Relaxor ferroelectric behavior has been noticed in all compositions across the solid solution. The room-temperature electrostrictive coefficient, Q33, was 1.83×10−2 C2/m4 for x=0.10. No room-temperature piezoelectric activity was detected; however, upon cooling to −261 °C the maximum coupling coefficients kp=29%, kt=11%, and k33=31% were observed for the composition x=1.00. 相似文献
7.
The single domain size of BaFe12O19 powder with crystallite sizes less than 200 nm was produced using a citric acid precursor method. Fe3+ and Ba2+, in a molar ratio of 12, were chelated by COOH− in an aqueous solution. After ethylene glycol additions, esterification, dehydration, and calcination led to the formation of ester-derived BaFe12O19 powder. High pH and/or high citric acid contents in the starting solution are required to complete chelate metallic ions in the solution and to form pure barium ferrite powder at 1073 K. Pure single magnetic domain BaFe12O19 particles of M(30 kOe)≈54 emu/g, Mr≈28 emu/g, and Hc≈3.7 kOe were produced using [citric acid]/[metallic ions]=1.5 and pH7. 相似文献
8.
Powder X-ray diffraction (XRD) and Raman spectroscopic study of order-disorder-phase transition with increase in the content of Gd in Nd2−yGdyZr2O7 solid solution is being reported. It has been observed from Rietveld analysis that with increase in concentration of Gd in Nd2−yGdyZr2O7, the value of the x parameter of the 48f oxygen changes from 0.332(1) to 0.343(1) with a sudden change in the slope for y=1.8, which indicates that the structure is transforming from ordered pyrochlore to disordered pyrochlore. In addition to that a sudden and drastic change in the Raman spectra including changes in the position and width of several Raman modes beyond y?1.8 has also been observed which has been correlated with increasing disorder. Based on these studies, it is suggested that there is a discontinuous order-disorder transition from ‘perfect pyrochlore’ to ‘defect pyrochlore’ phase in Nd2−yGdyZr2O7 solid solution. 相似文献
9.
10.
Aigars Vītiņš Ģirts Vītiņš Jānis Krastiņš Ints Šteins Ilmārs Zālīte Andrejs Lūsis 《Journal of Solid State Electrochemistry》1998,2(5):299-307
Ceramic specimens have been obtained from the powder of ZrO2-7.5 mol% Y2O3 having a specific surface area of 30 m2/g synthesized in air plasma. The novelty of this research lies in the fact that the plasma process makes it possible to prepare
so-called nanopowders with a particle size less than 100 nm, possessing specific physical, chemical and technological properties.
The sintered density of the specimens was 94–96% of the theoretical value, 6.001 g/cm3. The X-ray diffraction pattern of the specimens corresponded to a face-centered cubic lattice. Impedance in the frequency
range of 100 Hz–15 MHz and d.c. polarization curves in a potential range of −10 to 10 mV were measured in the temperature
range 200–850 °C in heating and cooling cycles. The intragrain, the grain boundary and the total bulk conductivities, the
electrode polarization resistance and their activation energies were determined. The thermal stability of the studied system
was proved in three measurement series up to 600–850 °C in heating and cooling cycles. The results obtained have shown that
the conductivity of ZrO2-7.5 mol% Y2O3 ceramics is not solely a function of temperature, but also depends on the previous thermal state of the ceramics.
Received: 16 October 1997 / Accepted: 19 January 1998 相似文献