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1.
In Situ Observation of Skeletal Shape Transition during BaB2O4 Crystal Growth in High-Temperature Solution
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The transition from a fiat solid-liquid interface to a skeletal shape during BaB2O4 (BBO) single crystal growth in Li2B4O7 flux is observed in real time by an optical high-temperature in-situ observation system. The movement of crystal step is also investigated. The observation results demonstrate that the steps propagate along and parallel to the fiat interface when the crystal size is small. Nevertheless, they will ‘bend' close to the face centre if the crystal size becomes greater. Atomic force microscopy reveals that more deposition places near the face centre give rise to the bending of advancing steps and thus the formation of a vicinal interface structure. Measurements of step velocity show that the velocity keeps nearly constant at different moments for one specific step, whereas the step on a newly formed layer advanced faster than that on a previously formed one when the crystal size is larger than 210μm or so. Thus interracial morphological instability occurs and a skeletal interface is obtained. 相似文献
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XIE Bin ZHU Sha-Sha LI Yu-Long ZOU Li-Ke LIN Xiao HE Lin-Xin ZHANG Xiu-Lan XIE Feng 《结构化学》2013,(10):1485-1490
O-(p-tolyl)dithiophosphato nickel complex [Ni(S2P{O}OC6HaCH3-p)(dppv)] has been synthesized by the treatment of (dppv)NiCl2 (dppv = Ph2PCH=CHPPh2) with (p-CH3C6HaO)2P{S}SH'Et2NH in THF. The new complex was fully characterized by elemental analysis, IR, 1H NMR, 31p NMR spectroscopies and thermo-gravimetric analysis. The molecular structure of the complex was established by X-ray crystallography. The crystal crystallizes in monoclinic, space group P21/c with a = 9.2739(5), b = 17.8803(8), c = 20.1879(12) A, fl = 93.269(5), V = 3342.1(3) A3, Z = 4, C33H29NiO2P3S2, Mr = 673.30, Dc = 1.338 g/cm3, F(000) = 1392 and #(MoKa) = 0.877 rnm-l. The final R = 0.0578 and wR = 0.1045 for 4138 observed reflections with 1 〉 20(/) and R = 0.1050 and wR = 0.1204 for all data. The Ni centre atom adopts a NiP2S2 square-planar geometry with two phosphorus atoms from the dppv ligand and two sulfur atoms from the O-(p-tolyl)dithiophosphate ligand. The most interesting structural feature of the title complex resides in its 1D helical chain structure constructing via intermolecular C-H'"O secondary interactions along the b-axis. The adjacent helical chains running in opposite directions are connected into a 1D double-stranded helical chain and further linked into a 2D supramolecular network by weak C-H.--C interaction. 相似文献
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采用微弧氧化和热处理复合技术,在钛表面制备了具有双层结构的榍石/氧化钛复合涂层。榍石/氧化钛复合涂层的外层是由微弧氧化涂层经热处理后晶化生成;而内层是由钛基底的氧化生成,并且氧化钛表现出不同的Ti,O原子比。由于钛基底的氧化,孔径在50~500 nm的微孔呈层状结构分布在涂层内层。与微弧氧化涂层相比,该复合涂层具有很好的磷灰石诱导能力,这是由于榍石沿着特定晶面和晶向与羟基磷灰石表现出良好的晶体学匹配关系,从而为磷灰石的成核和取向沉积过程提供良好的位点。 相似文献
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FarzinMarandi 《结构化学》2014,(8):1184-1190
[Pb(TPT)(μ-I)2PbI2(μ-I)2Pb(TPT)] 1(TPT is the abbreviation of 3,5,6-tris(2-pyridyl)-1,2,4-triazine ligand) has been synthesized and characterized by elemental analysis, IR, 1HNMR spectroscopy and studied by thermal and electrochemical properties as well as X-ray crystallography. The single-crystal X-ray data show two different kinds of Pb2+ ions in 1 with coordination numbers of six, Pb1 = PbI6, and five, Pb2 = PbN3I2, with holodirected and hemidirected coordination spheres, respectively. The supramolecular features in 1 are negotiated through the weak but directional Pb···I, C–H···N and C–H···I interactions and aromatic π-π stacking interactions. 相似文献
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A novel two-dimensional coordination polymer [Ba2(phen)4(tp)2]n(phen=1,10-phenanthroline,tp=terephthalic acid) has been synthesized with tp as bridge ligands and structurally determined by X-ray crystallography.The crystal belongs to the monoclinic system,space group C2/c,with a=18.877(4),b=18.489(4),c=15.658(3),β=103.61(3)o,V=5311.5(19)3,C32H20O4N4Ba,Mr=661.86,Z=8,F(000)=2624,μ=1.542mm-1,Dc=1.655 g/cm3,the final R= 0.0228 and wR=0.0554 for 6063 observed reflections(I2σ(I)).The structural analysis shows that each tp ligand bridges barium atoms to form a two-dimensional infinite layer.There are aromatic π-π stacking interactions between neighboring layers,and aromatic π-π interactions further extend such layers into a three-dimensional supramolecular framework. 相似文献
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文章主要介绍几种蛋白质空间结构的实验测定方法,在现代生物学研究中,最常用的方法包括X射线晶体学、二维核磁共振(2D-NMR)和低温冷冻电镜,近几年发展起来的单分子技术在生物大分子动态结构的研究中应用越来越多,这些方法都有它们特定的时间和空间分辨率,所测定的结构及其动力学受环境热运动涨落的影响也非常不同,文章对这些问题作了较详细的分析,在蛋白质结构的理论方法方面,介绍了一个新的折叠理论及其与现有折叠模型的关系.讨论了模拟计算在研究蛋白质构象变化和动力学方面的应用,同时强调了分子动力学和蒙特卡罗方法.指出粗粒化模型是研究的热点之一,对生物学中经常遇到的多长度多时问尺度问题提供了一个可行的解决方案。 相似文献