全文获取类型
收费全文 | 650篇 |
免费 | 112篇 |
国内免费 | 67篇 |
专业分类
化学 | 457篇 |
晶体学 | 5篇 |
力学 | 2篇 |
综合类 | 4篇 |
数学 | 23篇 |
物理学 | 338篇 |
出版年
2023年 | 6篇 |
2022年 | 19篇 |
2021年 | 21篇 |
2020年 | 42篇 |
2019年 | 27篇 |
2018年 | 10篇 |
2017年 | 14篇 |
2016年 | 28篇 |
2015年 | 24篇 |
2014年 | 29篇 |
2013年 | 46篇 |
2012年 | 29篇 |
2011年 | 27篇 |
2010年 | 23篇 |
2009年 | 28篇 |
2008年 | 32篇 |
2007年 | 38篇 |
2006年 | 36篇 |
2005年 | 32篇 |
2004年 | 25篇 |
2003年 | 27篇 |
2002年 | 20篇 |
2001年 | 28篇 |
2000年 | 22篇 |
1999年 | 23篇 |
1998年 | 22篇 |
1997年 | 22篇 |
1996年 | 26篇 |
1995年 | 17篇 |
1994年 | 20篇 |
1993年 | 18篇 |
1992年 | 10篇 |
1991年 | 10篇 |
1989年 | 5篇 |
1988年 | 10篇 |
1987年 | 7篇 |
1986年 | 3篇 |
1980年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有829条查询结果,搜索用时 578 毫秒
1.
P. M. Larionov A. N. Malov M. M. Mandrik N. A. Maslov A. M. Orishich 《Journal of Applied Spectroscopy》2003,70(1):38-42
We investigated the laser-induced fluorescence spectra (LIF) of porcine cardiac tissues with different degrees of viability. The data obtained are compared with the results of routine histological investigations and also with the experiments performed with the use of fluorescent probes. It has been found with a high degree of reliability that the loss of the viability of the myocardium tissue leads to the alteration of its LIF spectra. This can be used for low-invasive rapid control of transplant viability in the process of its preparation and during surgery. 相似文献
2.
本文采用了一种简单的功率监测法,观察了KrF准分子激光对掺锗光纤折射率影响的非线性过程。观察到子纤芯折射率扰动过程中非稳定现象、饱和现象和折射率扰动的非线性。 相似文献
3.
From flash photolysis data of benzil and 2,2′-dichlorobenzil, the role of conformeric triplets in the formation of hydrogen
adduct radicals has been discussed. The planar relaxed triplet absorbing at 470 nm is less efficient in forming a hydrogen
adduct radical as compared to its puckered conformeric partner. Among the hydrogen donors, triethyl amine and isopropanol,
the former is more efficient in converting puckered triplets and less efficient in the case of planar conformers. Absorptions
of radicals and radical anions of 2,2′-dichlorobenzil appear at 355 nm and 460 nm respectively. These are blue-shifted as
compared to those of the parent compound benzil appearing at 370 nm and 540 nm, respectively. This blue-shift has been discussed
in terms of steric hindrance due to ortho-substitution. 相似文献
4.
We have studied the temperature dependence of the radiative deactivation of the Pd-porphine triplet states in Shpol’skii matrices
in the temperature range 1.2–210 K. A substantial transformation of the phosphorescence spectra is observed as the temperature
increases and is due to the inclusion of thermally activated Pd-porphine states in the radiative deactivation processes. The
activation energy Ea of these Pd-porphine states is measured in matrices of n-octane and n-nonane. The splitting of the lowest quasidegenerate
triplet state ΔE(T2−T1) is determined for planar and distorted conformations of the Pd-porphine macrocycle in the n-octane matrix as 40 and 57 cm−1, respectively. The ability to use the temperature dependence of the phosphorescence properties of Pd-porphine to fabricate
molecular thermometers for the low-temperature range is analyzed.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 4, pp. 460–464, July–August, 2007. 相似文献
5.
The constants of binding dye molecules with the micelles of sodium dodecyl sulfate are determined using quenching of delayed fluorescence of acridine dyes by sodium iodide in aqueous–micellar solutions. Kinetic equations have been composed that describe the processes of deactivation of the excited states of dyes. By solving these equations at the concentration of the quencher sodium iodide corresponding to the minimum lifetime of triplet states and at the concentration of micelles corresponding to the least value of the delayed fluorescence quenching rate constants, we obtained the constants of binding dyes with micelles equal to 1.3·107, 2.9·107, and 3.1·107 M–1 for trypaflavine, acridine orange, and acridine yellow, respectively. We calculated the rate constants of quenching of the triplet states of the molecules of dyes by iodide ions (I
–) that decreased in transition from trypaflavine to acridine orange and acridine yellow. 相似文献
6.
7.
8.
Yoshihiro Itoh Masamitsu Inoue Tomoko Takahashi Akira Hachimori Satoshi Suzuki 《Journal of polymer science. Part A, Polymer chemistry》1995,33(7):1069-1074
Alternating and random copolymers of 9-phenanthrylmethyl methacrylate or 2-(9-carbazolyl)ethyl methacrylate with styrene were synthesized and their fluorescence properties were examined. There was no noticeable difference in the spectral features of the alternating and random copolymers in tetrahydrofuran (THF), demonstrating that this type of polymers have no quenching sites in the polymer chains. The fluorescence quenching studies indicated that the alternating copolymers permitted singlet-state energy migration as efficiently as the corresponding random copolymers but less efficiently than the random copolymers with higher chromophore contents. These results strongly suggest that to be chromophores close to each other is most important for facilitation of an intramolecular energy migration. © 1995 John Wiley & Sons, Inc. 相似文献
9.
The properties of the triplet excited state of [60] fullerene-containing cyclic sulphoxide have been investigated by time-resolved absorption spectroscopy. Transient absorption bands of [60] fullerene-containing cyclic sulphoxide showed two decay-components, which wrer attributed to triplet excited states of different spin multiplicity. The properties of photoexcited states of [60] fullerene-containing cyclic sulphoxide are also reported. 相似文献
10.
Aggregated aromatic molecule--cyclodextrin-precipitant complexes exhibit long-lived phosphorescence at room temperature in water after the chemical binding of oxygen. The temperature dependences of the phosphorescence lifetimes of naphthalene-h8, naphthalene-de, and phenanthrene in the aggregates were measured. For example, the phosphorescence lifetimes of naphthalene-d8 aggregated with -cyclodextrin and cyclohexane are equal to 25.1, 17.6, and 6.8 s at 77, 276, and 347 K, respectively, and that of phenanthrene aggregated with isooctane and -cyclodextrin are 3.24, 3.06, and 1.26 s at 268, 274, and 335 K, respectively. The temperature dependences of the phosphorescence lifetimes at room temperature are determined by the rate constants of the radiative and nonradiative transitions from the triplet state of an aromatic molecule.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2225–2228, September, 1996. 相似文献