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Abdollah Javidan A. R. Banan 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2253-2258
The synthesis of dialkyl-(2,2,2-trichloro-1-Hydroxyethyl) phosphonates using dialkyl hydrogen phosphite and chloral hydrate under solvent-free condition by microwave irradiation is reported. The products were chrachetrized using 1 H NMR, 13 C NMR, and 31 P NMR spectroscopy. 相似文献
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制备了乙酰胆碱酯酶/Nafion/普鲁士蓝修饰的玻碳电极,测试了该修饰电极检测有机农药西维因(carbaryl)和敌百虫(trichlorfon)的性能指标。 利用原子力显微镜和电化学技术研究了电极的构造及其对于有机农药检测性能指标的影响。 结果表明,乙酰胆碱酯酶均匀地分散到Nafion/普鲁士蓝修饰的玻碳电极上。 在最优的实验条件下,构筑的修饰电极检测西维因和敌百虫的线性范围分别为0.01~0.5 μmol/L及2.0~10.0 μmol/L和0.02~1.0 μmol/L及2.0~8.0 μmol/L,检出限分别为5.0和10.0 nmol/L。 并对模拟的实际样品进行了检测,发现该方法有较高的检测灵敏度、较好的重复性和抗干扰性。 相似文献
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结合氨基功能化离子液体修饰石墨烯(IL-GR)、纳米金(Au)等纳米材料的独特性质,以壳聚糖(CHIT)为交联剂,首先在玻碳电极表面固定IL-GR,然后吸附胶体金制得Au/IL-GR-CHIT复合膜,最后固定乙酰胆碱酯酶(AChE)制得新型有机磷检测酶传感器(AChE/Au/IL-GR-CHIT/GCE),并用于白菜样品中敌百虫农药的测定。采用透射电镜(TEM)对纳米材料进行了表征,循环伏安法(CV)和差示脉冲伏安法(DPV)研究了传感器的电化学性质。纳米复合物不仅为保持AChE的生物活性提供了适宜的微环境,并且对传感器性能的改善显示出强大的协同效应。在优化实验条件下,抑制率(A)与敌百虫浓度的负对数在2.0×10-10~1.0×10-6mol/L范围内呈良好的线性关系,检出限(S/N=3)为2.1×10-12mol/L。用于蔬菜中敌百虫含量的测定,回收率为97.5%~107.2%。 相似文献
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In this study, a molecularly imprinted polymer (MIP) that can selectively recognize both the trichlorfon and the structurally related compound of monocrotophos pesticides was prepared using mixtures of trichlorfon and monocrotophos as template molecules, methacrylic acid (MAA) as a functional monomer, and ethylene glycol dimethacrylate as a cross-linker. The polymerization conditions had an important influence on the adsorption ability of imprinted polymer. When the ratio of trichlorfon and monocrotophos was 1.5:1 (mol/mol), the MIP had high adsorption capacity. The prepared polymers were characterized by Fourier transform infrared spectroscopy and static and kinetic adsorption experiments. The results indicated that the P = O groups of trichlorfon and monocrotophos reacted with the -OH groups of MAA during the synthesis of MIP. The imprinted polymer exhibited good recognition ability and higher selectivity toward trichlorfon and monocrotophos than the structurally related pesticide compounds of acephate and methamidophos, and offered fast kinetics for solid phase by the MIP adsorption of trichlorfon and monocrotophos from liquid phase. 相似文献
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