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Bredikhin A. A. Strunskaya E. I. Novikova V. G. Azancheev N. M. Sharafutdinova D. R. Bredikhina Z. A. 《Russian Chemical Bulletin》2004,53(1):213-218
The enantioselective partial hydrolysis of a number of racemic aryl glycidyl ethers in the presence of chiral Co(salen)-catalyst was studied. The enantiomeric composition of the isolated (R)-aryl glycidyl ethers was analyzed by 31P NMR using optically active substituted 2-chloro-1,3,2-dioxaphospholanes. A synthesis of -adrenoblocking agents (S)-toliprolol and (S)-moprolol based on the simultaneously obtained (S)-3-aryloxypropane-1,2-diols was proposed. 相似文献
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