全文获取类型
收费全文 | 290篇 |
免费 | 5篇 |
国内免费 | 23篇 |
专业分类
化学 | 250篇 |
晶体学 | 16篇 |
综合类 | 3篇 |
物理学 | 49篇 |
出版年
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2017年 | 5篇 |
2016年 | 7篇 |
2015年 | 2篇 |
2014年 | 10篇 |
2013年 | 27篇 |
2012年 | 25篇 |
2011年 | 11篇 |
2010年 | 13篇 |
2009年 | 19篇 |
2008年 | 23篇 |
2007年 | 18篇 |
2006年 | 18篇 |
2005年 | 14篇 |
2004年 | 11篇 |
2003年 | 15篇 |
2002年 | 6篇 |
2001年 | 6篇 |
2000年 | 9篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有318条查询结果,搜索用时 15 毫秒
1.
A continuous precipitation flame atomization atomic absorption spectrometric method for the indirect determination of sulphate is proposed. By using a reversed flow-injection configuration for precipitation as barium sulphate, this anion was determined in the range 10–150 g/ml, with a relative standard deviation of 2.6%. The sensitivity was increased by a factor of seven by using a nitrous oxide-acetylene flame to measure barium. 相似文献
2.
X. -H. Deng S. -F. Jiao Y. Yan C. Wang G. -F. Wang B. Fang 《Russian Journal of Electrochemistry》2006,42(8):873-877
Aminylferrocene is successfully immobilized on nanosized gold colloid particles associated with a 1,4-benzenedimethanethiol
monolayer on a gold electrode surface and characterized by cyclic voltammograms and electrochemical impedance spectroscopy.
In a pH 7.0 phosphate buffer solution, the formal potential (E
0’) of Fc is 0.432 V (SCE), and the apparent surface electron-transfer rate constant is 0.89 s−. The immobilized Fc gives an excellent electrocatalytic response to the terbutaline oxidation. The catalytic-current response
of differential pulse voltammograms increases linearly with the terbutaline concentration from 1.75 × 10−7 to 5.62 × 10−4 mol/l. The detection limit is 2.30 × 10−8 mol/l. The determination of terbutaline in a tablet dosage is satisfactory. The method is simple, quick, and sensitive.
Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 8, pp. 969–974.
The text was submitted by the authors in English. 相似文献
3.
硫酸根的分光光度法测定 总被引:6,自引:0,他引:6
本文就硫酸根的间接及直接光度测定的基本原理,试剂,方法和应用等作了较为系统的评述。列出重要文献67篇。 相似文献
4.
5.
Interactions of anionic surfactant sodium dodecyl sulphate (SDS) with vesicles formed by synthetic dialkyldimethylammonium
bromides i.e. didodecyldimethylammonium bromide (DDAB), ditetradecyldimethylammonium bromide (DTAB), dihexadecyldimethylammonium
bromide (DHAB) have been examined by using differential scanning microcalorimetry and electron transmission microscopy. The
temperatures and standard enthalpies characterising gel to liquid-crystal transitions increase significantly with increase
of SDS concentration for all investigated systems. It means that incorporation of SDS monomers in these vesicular bilayers
significantly stabilises their gel states. Moreover, in case of DDAB and DTAB vesicle systems added SDS limits kinetic features
of recorded isobaric heat capacity dependencies on temperature observed earlier for the pure vesicular solutions.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
6.
7.
8.
In developing a method for possible low level isotopic enrichment, which uses to advantage the equilibrium isotope effect
observed during U(1V)-U(VI) electron exchange reaction in sulphate solutions, details of a solvent extraction process involving
high concentration of a mixture of U(IV) and U(VI) and at low acid concentrations, are described. The extraction behaviour
of uranium under these conditions is discussed. During the extraction with amines, U(IV) tended to get oxidised in sulphate
solutions. 相似文献
9.
10.
T. L. Luke H. Mohan V. M. Manoj P. Manoj J. P. Mittal C. T. Aravindakumar 《Research on Chemical Intermediates》2003,29(4):379-391
Reactions of sulphate radical anion (SO·4
-) with 4,6-dihydroxy-2-methyl pyrimidine (DHMP), 2,4-dimethyl-6-hydroxy pyrimidine (DMHP), 6-methyl uracil (MU) and 5,6-dimethyl uracil (DMU) have been studied by pulse radiolysis at pH 3 and at pH 10. The transient intermediate spectra were compared with those from the reaction of hydroxyl radical (·OH). It is proposed that SO·4
- produces radical cations of these pyrimidines in the initial stage. These radical cations are short-lived except in the case of DMHP where a relatively longer lived radical cation is proposed to be formed. When there is a hydrogen atom attached to the N(1) or N(3) position, a deprotonation from these sites is highly favored. When there is no hydrogen attached to these sites, deprotonation from a substituted methyl group is favored. At acidic pH, deprotonation from nitrogen is observed for DHMP, MU and DMU. At basic pH, the radical cation reacts with OH- leading to the formation of OH adducts. 相似文献