排序方式: 共有19条查询结果,搜索用时 234 毫秒
1.
Dr. M. Merced Montero‐Campillo Prof. Al Mokhtar Lamsabhi Prof. Otilia Mó Prof. Manuel Yáñez 《Chemphyschem》2013,14(5):915-922
The UV/Vis spectra of selected substituted subporphyrazines (SubPz) and subphthalocyanines (SubPc) with aluminum and gallium as central atoms are analyzed through time‐dependent DFT calculations in chloroform. The results are compared with previous results with boron as the central atom to analyze the photochemical properties of these two families of compounds on varying the metal along the same group. The absorptions of SubPz (Al, Ga) are redshifted or blueshifted with respect to SubPz (B) depending on the nature of the R substituents of the molecule, whereas the absorptions of SubPc (Al, Ga) structures are redshifted and with smaller energy gaps with respect to SubPc (B) for all kinds of R substituents. Looking at their absorption spectra, these systems with aluminum and gallium may also have, as in the case of boron, promising photochemical properties. 相似文献
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Peripherally and Axially Carboxylic Acid Substituted Subphthalocyanines for Dye‐Sensitized Solar Cells 下载免费PDF全文
Dr. Mine Ince Dr. Anaïs Medina Dr. Jun‐Ho Yum Dr. Aswani Yella Dr. Christian G. Claessens Dr. M. Victoria Martínez‐Díaz Prof. Michael Grätzel Dr. Mohammad K. Nazeeruddin Prof. Tomás Torres 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(7):2016-2021
A series of subphthalocyanines (SubPcs) bearing a carboxylic acid group either at the peripheral or axial position have been designed and synthesized to investigate the influence of the COOH group positions on the dye‐sensitized solar cell (DSSC) performance. The DSSC devices based on SubPcs with axially substituted carboxylic acid groups showed low photovoltaic performance, whereas peripherally substituted one exhibited higher power conversion efficiency owing to improved injection from LUMO of SubPcs to the TiO2 conduction band. 相似文献
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Dr. Víctor Mariñas Benedikt Platzer Jorge Labella Dr. Fabrizio Caroleo Prof. Sara Nardis Prof. Roberto Paolesse Prof. Dirk M. Guldi Prof. Tomás Torres 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201552
Porphyrinoids are considered perfect candidates for their incorporation into electron donor–acceptor (D–A) arrays due to their remarkable optoelectronic properties and low reorganization energies. For the first time, a series of subphthalocyanine (SubPc) and corrole (Cor) were covalently connected through a short-range linkage. SubPc axial substitution strategies were employed, which allowed the synthesis of the target molecules in decent yields. In this context, a qualitative synthetic approach was performed to reverse the expected direction of the different electronic events. Consequently, in-depth absorption, fluorescence, and electrochemical assays enabled the study of electronic and photophysical properties. Charge separation was observed in cases of electron-donating Cors, whereas a quantitative energy transfer from the Cor to the SubPc was detected in the case of electron accepting Cors. 相似文献
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Several subphthalocyanine derivatives that contain an alkoxo substituent as an axial ligand (RO-Subpc, R = 9-anthracenemethyl, benzyl, phenyl, 3,5-dimethylbenzyl, 3,5-dimethylphenyl, 4-methylbenzyl, and 4-methylphenyl) were synthesized. The formation of inclusion complexes of RO-Subpc with beta-CD in DMSO and at the toluene/water interface was investigated by UV/Vis absorption spectroscopy, induced circular dichroism (ICD), and nuclear magnetic resonance (NMR) measurements. Interfacial tension measurements suggested that beta-CD adsorbed as a monolayer at the toluene/water interface and probably orientated towards the toluene phase with its primary face. The 1:1 composition of beta-CD.RO-Subpc inclusion complexes was confirmed in DMSO and at the toluene/water interface for BzO-Subpc, PhO-Subpc, MeBzO-Subpc, and MePhO-Subpc. A 2:1 inclusion complex of AnO-Subpc formed in DMSO. The observed ICD spectra of beta-CDRO-Subpc inclusion complexes are discussed with respect to molecular modeling and the simulation based on Tinoco-Kirkwood theory. Interestingly, the ICD spectra of beta-CD.BzO-Subpc and beta-CD.MeBzO-Subpc inclusion complexes exhibited a negative sign in DMSO and a positive sign at the toluene/water interface. This reversal of the ICD sign strongly suggests a difference in the structure of the inclusion complexes: beta-CD at the interface formed the inclusion complex with its primary face, whereas the secondary face of beta-CD bound favorably to RO-Subpc in DMSO. 相似文献
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González-Rodríguez D Torres T Herranz MA Echegoyen L Carbonell E Guldi DM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(25):7670-7679
We have prepared two complementary series of SubPc-C(60) (SubPc=subphthalocyanine) electron/energy donor-acceptor systems, in which the two constituents are linked through ortho-, meta-, or para-substituted phenoxy spacers. In one of the series (1 a) the SubPc units bear iodine atoms, while in the other series (1 b) diphenylamino groups are linked to the SubPc macrocycles. The iodine atoms and diphenylamino groups both influence the resulting oxidation potentials of the electron-donating SubPc. They also modulate the outcome of excited state interactions, namely, energy and/or charge transfer. In addition, we have studied the impact that the substitution pattern in the phenoxy spacer exerts onto intramolecular processes in the ground and excited states. Although some of these processes are governed by the spatial separation between both components, the different electronic coupling through ortho-, meta-, or para- connections also plays decisive roles in some cases. 相似文献
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Charge Separation in Graphene‐Decorated Multimodular Tris(pyrene)–Subphthalocyanine–Fullerene Donor–Acceptor Hybrids 下载免费PDF全文
Chandra B. KC Gary N. Lim Prof. Dr. Francis D'Souza 《Angewandte Chemie (International ed. in English)》2015,54(17):5088-5092
A new approach to probe the effect of graphene on photochemical charge separation in donor–acceptor conjugates is devised. For this, multimodular donor–acceptor conjugates, composed of three molecules of pyrene, a subphthalocyanine, and a fullerene C60 ((Pyr)3SubPc‐C60), have been synthesized and characterized. These systems were hybridized on few‐layer graphene through π–π stacking interactions of the three pyrene moieties. The hybrids were characterized using Raman, HRTEM, and spectroscopic and electrochemical techniques. The energy levels of the donor–acceptor conjugates were fine‐tuned upon interaction with graphene and photoinduced charge separation in the absence and presence of graphene was studied by femtosecond transient absorption spectroscopy. Accelerated charge separation and recombination was detected in these graphene‐decorated conjugates suggesting that they could be used as materials for fast‐responding optoelectronic devices and in light energy harvesting applications. 相似文献
9.
Tuning Optical and Electron Donor Properties by Peripheral Thio–Aryl Substitution of Subphthalocyanine: A New Series of Donor–Acceptor Hybrids for Photoinduced Charge Separation 下载免费PDF全文
Dr. Chandra B. KC Gary N. Lim Prof. Dr. Francis D'Souza 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(37):13301-13311
Subphthalocyanine (SubPc), a unique ring‐reduced member of the common phthalocyanines family, although known for its higher absorptivity, reveals narrow absorption with peak maxima around 570 nm thus limiting its utility in light‐energy‐harvesting applications. In the present study, by peripheral thio–aryl substitution of SubPc macrocycle, the spectral properties have been modulated to extend the absorption and emission well into the visible/near‐IR region. Additionally, for α‐ring‐substituted derivatives, facile oxidation of SubPc was witnessed, thus making these derivatives better electron donors. Next, the preparation of donor–acceptor dyads containing the well‐known electron acceptor C60 connected to the central boron atom of SubPc was accomplished by making use of the 1,3‐dipolar cycloaddition reaction. Control experiments and free‐energy calculations using the redox and spectral data suggested that the observed fluorescence quenching of SubPc in these dyads is due to electron transfer. Accordingly, transient spectral studies performed both in polar and nonpolar solvents conclusively proved electron transfer to be the quenching mechanism in these dyads. The measured rate constants by fitting kinetic data revealed efficient charge separation and charge recombination processes, suggesting that these dyads could be useful materials for the construction of light‐to‐electricity or light‐to‐fuel production devices. 相似文献
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A Multifunctional Subphthalocyanine Nanosphere for Targeting,Labeling, and Killing of Antibiotic‐Resistant Bacteria 下载免费PDF全文
Indranil Roy Dr. Dinesh Shetty Dr. Raghunandan Hota Dr. Kangkyun Baek Jeesu Kim Prof. Dr. Chulhong Kim Sandro Kappert Prof. Dr. Kimoon Kim 《Angewandte Chemie (International ed. in English)》2015,54(50):15152-15155
Developing a material that can combat antibiotic‐resistant bacteria, a major global health threat, is an urgent requirement. To tackle this challenge, we synthesized a multifunctional subphthalocyanine (SubPc) polymer nanosphere that has the ability to target, label, and photoinactivate antibiotic‐resistant bacteria in a single treatment with more than 99 % efficiency, even with a dose as low as 4.2 J cm?2 and a loading concentration of 10 nM . The positively charged nanosphere shell composed of covalently linked SubPc units can increase the local concentration of photosensitizers at therapeutic sites. The nanosphere shows superior performance compared to corresponding monomers presumably because of their enhanced water dispersibility, higher efficiency of singlet‐oxygen generation, and phototoxicity. In addition, this material is useful in fluorescence labeling of living cells and shows promise in photoacoustic imaging of bacteria in vivo. 相似文献