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1.
本文制备了PANI纳米点阵列, 利用导电原子力显微镜(C-AFM)表征了其形貌和导电性能, 在室温下观察到PANI纳米点的库仑台阶(Coulomb staircase)现象, 并利用库仑阻塞效应的理论进行了初步的分析. 相似文献
2.
阶梯扫描伏安法与线性扫描伏安法相关性的理论研究——简单可逆体系 总被引:1,自引:0,他引:1
本文采用Reimann-Stielties(黎曼-斯堤杰斯)级数展开法,指导了简单可逆电极体系的线性扫描伏安法和阶梯扫描伏安法的电流方程式,得到了能有机地统一的这两种最大为基本的伏安法的电流函数表达式,表达式简明直观,在无因次电流函数的基础详细讨论了制约阶梯扫描伏安法和线性扫描伏安法之间相关性程度的各因素,获得了一些新的结论。 相似文献
3.
Milivoj Lovrić 《Electroanalysis》2021,33(11):2372-2380
A model of cyclic staircase voltammetry of enzymatic reactions on the rotating disk electrode is developed and the inhibition by the product is investigated. The responses are mostly time – dependent current – potential curves with maxima in the forward but not in the backward branch. If the maxima appear in both branches, the inhibition is potential – dependent either directly or indirectly. The source of the second maximum is explained. 相似文献
4.
Several aspects of localized defects in the Frenkel-Kontorova, classicalXY chain and analogous models with a finite range of interactions are discussed from a general point of view. Precise definitions are given for defect phase shifts (charges) and for creation, pinning, and interaction energies. Corresponding definitions are also provided for interfaces (localized regions separating two phases). For the nearest-neighbor Frenkel-Kontorova model, the various defect energies are related to areas enclosed by contours joining heteroclinic points of the area-preserving map generated by the conditions of mechanical equilibrium. 相似文献
5.
Ananias M. Mariz Constantino Tsallis E. L. Albuquerque 《Journal of statistical physics》1985,40(3-4):577-592
We study the phase diagram for the Ising Model on a Cayley tree with competing nearest-neighbor interactionsJ
1 and next-nearest-neighbor interactionsJ
2 andJ
3 in the presence of an external magnetic field. To perform this study, an iterative scheme similar to that appearing in real space renormalization group frameworks is established; it recovers, as particular cases, previous works by Vannimenus and by Inawashiroet al. At vanishing temperature, the phase diagram is fully determined, for all values and signs ofJ
2/J
1 andJ
3/J
2; in particular, we verify that values ofJ
3/J
2 high enough favor the paramagnetic phase. At finite temperatures, several interesting features (evolution of reentrances, separation of the modulated region into two disconnected pieces, etc.) are exhibited for typical values ofJ
2/J
1 andJ
3/J
2.Partially supported by the Brazilian Agencies CNPq and FINEP. 相似文献
6.
采用楔形光纤(WSF)实现了与半导体多量子阱(MQW)平面光波光路(PLC)芯片的高效耦合。在多量子阱-平面光波光路前置模斑转换器(SSC)和不加模斑转换器的情况下,用阶梯串联法(SCM)数值模拟并优化设计了楔形光纤-平面光波光路间最佳耦合参量:楔形光纤楔角45°、端面圆柱透镜曲率半径2.5μm、模斑转换器-多量子阱-平面光波光路出射椭圆光斑长半轴3.5μm、纵横比5、楔形光纤-平面光波光路间垂直方向和水平方向无偏移、纵向间距5.5μm。用反向推演法(IDM)实验分析了楔形光纤样品的出射光场,与阶梯串联法(SCM)计算结果相比长轴误差为3.125%,短轴误差为0.8%。建立楔形光纤-平面光波光路-单模光纤(SMF)的耦合实验系统,在1.55μm波长处以单模光纤作为出纤的相同条件下,发现楔形光纤激励入射平面光波光路比单模光纤和锥形透镜光纤(TLF)作为入纤的耦合效率分别提高了24.827 dB和16.22 dB,为多量子阱-平面光波光路芯片尾纤封装技术提供了实验原型。 相似文献
7.
8.
We solve analytically for the perimeter-area generating functions for two models of vesicles. While from the solution of the first model, staircase polygons, one can easily extract the asymptotic scaling behavior, the exact solution of the second, column-convex polygons, is difficult to analyze. This leads us to apply a recently developed method for deriving the scaling behavior indirectly, utilizing a set of nonlinear differential equations. One result of this work is a nontrivial confirmation of the scaling/universality hypothesis. 相似文献
9.
10.