全文获取类型
收费全文 | 3540篇 |
免费 | 562篇 |
国内免费 | 213篇 |
专业分类
化学 | 2487篇 |
晶体学 | 6篇 |
力学 | 103篇 |
综合类 | 32篇 |
数学 | 1159篇 |
物理学 | 528篇 |
出版年
2024年 | 4篇 |
2023年 | 36篇 |
2022年 | 85篇 |
2021年 | 110篇 |
2020年 | 211篇 |
2019年 | 149篇 |
2018年 | 138篇 |
2017年 | 125篇 |
2016年 | 168篇 |
2015年 | 165篇 |
2014年 | 178篇 |
2013年 | 375篇 |
2012年 | 149篇 |
2011年 | 170篇 |
2010年 | 149篇 |
2009年 | 155篇 |
2008年 | 185篇 |
2007年 | 203篇 |
2006年 | 193篇 |
2005年 | 164篇 |
2004年 | 147篇 |
2003年 | 145篇 |
2002年 | 106篇 |
2001年 | 81篇 |
2000年 | 89篇 |
1999年 | 88篇 |
1998年 | 64篇 |
1997年 | 77篇 |
1996年 | 63篇 |
1995年 | 48篇 |
1994年 | 49篇 |
1993年 | 33篇 |
1992年 | 34篇 |
1991年 | 22篇 |
1990年 | 18篇 |
1989年 | 16篇 |
1988年 | 12篇 |
1987年 | 8篇 |
1986年 | 10篇 |
1985年 | 10篇 |
1984年 | 11篇 |
1983年 | 6篇 |
1982年 | 12篇 |
1981年 | 4篇 |
1980年 | 6篇 |
1979年 | 11篇 |
1978年 | 6篇 |
1976年 | 7篇 |
1974年 | 4篇 |
1970年 | 3篇 |
排序方式: 共有4315条查询结果,搜索用时 15 毫秒
1.
New Phenomena in Organometallic‐Mediated Radical Polymerization (OMRP) and Perspectives for Control of Less Active Monomers
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Prof. Dr. Rinaldo Poli 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(19):6988-7001
The impact of reversible bond formation between a growing radical chain and a metal complex (organometallic‐mediated radical polymerization (OMRP) equilibrium) to generate an organometallic intermediate/dormant species is analyzed with emphasis on the interplay between this and other one‐electron processes involving the metal complex, which include halogen transfer in atom transfer radical polymerization (ATRP), hydrogen‐atom transfer in catalytic chain transfer (CCT), and catalytic radical termination (CRT). The challenges facing the controlled polymerization of “less active monomers” (LAMs) are outlined and, after reviewing the recent achievements of OMRP in this area, the perspectives of this technique are analyzed. 相似文献
2.
Roberto Morales-Cerrada Dr. Christophe Fliedel Dr. Jean-Claude Daran Dr. Florence Gayet Dr. Vincent Ladmiral Dr. Bruno Améduri Prof. Rinaldo Poli 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(1):296-308
Thermal decarbonylation of the acyl compounds [Mn(CO)5(CORF)] (RF=CF3, CHF2, CH2CF3, CF2CH3) yielded the corresponding alkyl derivatives [Mn(CO)5(RF)], some of which have not been previously reported. The compounds were fully characterized by analytical and spectroscopic methods and by several single-crystal X-ray diffraction studies. The solution-phase IR characterization in the CO stretching region, with the assistance of DFT calculations, has allowed the assignment of several weak bands to vibrations of the [Mn(12CO)4(eq-13CO)(RF)] and [Mn(12CO)4(ax-13CO)(RF)] isotopomers and a ranking of the RF donor power in the order CF3<CHF2<CH2CF3≈CF2CH3. The homolytic Mn−RF bond cleavage in [Mn(CO)5(RF)] at various temperatures under saturation conditions with trapping of the generated RF radicals by excess tris(trimethylsilyl)silane yielded activation parameters ΔH≠ and ΔS≠ that are believed to represent close estimates of the homolytic bond dissociation thermodynamic parameters. These values are in close agreement with those calculated in a recent DFT study (J. Organomet. Chem. 2018 , 864, 12–18). The ability of these complexes to undergo homolytic Mn−RF bond cleavage was further demonstrated by the observation that [Mn(CO)5(CF3)] (the compound with the strongest Mn−RF bond) initiated the radical polymerization of vinylidene fluoride (CH2=CF2) to produce poly(vinylidene fluoride) in good yields by either thermal (100 °C) or photochemical (UV or visible light) activation. 相似文献
3.
Annegret K. Wagler 《Mathematical Methods of Operations Research》2002,56(1):127-149
An edge e of a perfect graph G is critical if G−e is imperfect. We would like to decide whether G−e is still “almost perfect” or already “very imperfect”. Via relaxations of the stable set polytope of a graph, we define two
superclasses of perfect graphs: rank-perfect and weakly rank-perfect graphs. Membership in those two classes indicates how
far an imperfect graph is away from being perfect. We study the cases, when a critical edge is removed from the line graph
of a bipartite graph or from the complement of such a graph. 相似文献
4.
In this paper we introduce a generalization of stable sets: stable multi-sets. A stable multi-set is an assignment of integers
to the vertices of a graph, such that specified bounds on vertices and edges are not exceeded. In case all vertex and edge
bounds equal one, stable multi-sets are equivalent to stable sets.
For the stable multi-set problem, we derive reduction rules and study the associated polytope. We state necessary and sufficient
conditions for the extreme points of the linear relaxation to be integer. These conditions generalize the conditions for the
stable set polytope. Moreover, the classes of odd cycle and clique inequalities for stable sets are generalized to stable
multi-sets and conditions for them to be facet defining are determined.
The study of stable multi-sets is initiated by optimization problems in the field of telecommunication networks. Stable multi-sets
emerge as an important substructure in the design of optical networks.
Received: February 14, 2001/Revised version: September 7, 2001 相似文献
5.
Haifeng Yang Guangming XieTianguang Chu Long Wang 《Nonlinear Analysis: Theory, Methods & Applications》2006
In the paper, commuting and stable feedback design for switched linear systems is investigated. This problem is formulated as to build up suitable state feedback controller for each subsystem such that the closed-loop systems are not only asymptotically stable but also commuting each other. A new concept, common admissible eigenvector set (CAES), is introduced to establish necessary/sufficient conditions for commuting and stable feedback controllers. For second-order systems, a necessary and sufficient condition is established. Moreover, a parametrization of the CAES is also obtained. The motivation comes from stabilization of switched linear systems which consist of a family of LTI systems and a switching law specifying the switching between them, where if all the subsystems are stable and commuting each other, then the total system is stable under arbitrary switching. 相似文献
6.
Hai-Ping Cao 《Journal of fluorine chemistry》2006,127(8):1079-1086
In the presence of sodium dithionite and DMSO, the intramolecular radical cyclization of 4-chloro-1,1,2,2,3,3,4,4-octafluorobutylbenzenes is achieved to give the corresponding cyclic compounds in moderate to good yields. 相似文献
7.
We establish a relation between stable distributions in probability theory and the fractional integral. Moreover, it turns out that the parameter of the stable distribution coincides with the exponent of the fractional integral. It follows from an analysis of the obtained results that equations with the fractional time derivative describe the evolution of some physical system whose time degree of freedom becomes stochastic, i.e., presents a sum of random time intervals subject to a stable probability distribution. We discuss relations between the fractal Cantor set (Cantor strips) and the fractional integral. We show that the possibility to use this relation as an approximation of the fractional integral is rather limited. 相似文献
8.
In this note we show that all diffeomorphisms close enough to the time-one map of the frame flow on certain negatively curved manifolds are ergodic. As a simple corollary we deduce that the frame flows are ergodic for all compact manifolds with curvature pinched sufficiently close to –1, thus providing results in the case of manifolds of dimension 7 or 8 which were missing from the results of Brin and Karcher. 相似文献
9.
Liuman Ou Guilie Luo Yiping Li 《Journal of Mathematical Analysis and Applications》2003,283(2):534-548
In this paper, we consider an autonomous predator-prey Lotka-Volterra system in which individuals in the population may belong to one of two classes: the immatures and the matures, the age to maturity is represented by a time delay. By using eigenvalue analysis, principal term analyze method, reduction to absurdity, and iterative method, we obtain some simple conditions for global asymptotic stability of the unique positive equilibrium point. Moreover, a condition that the prey population in the system get extinction and the predator population in the system get permanence will be obtained. Meanwhile the theorems extend the corresponding conclusions in which there have no two stage structures. 相似文献
10.