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Unprecedented Dearomatized Spirocyclopropane in a Sequential Rhodium(III)‐Catalyzed C−H Activation and Rearrangement Reaction
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Dr. Xiaoming Wang Yingzi Li Tobias Knecht Dr. Constantin G. Daniliuc Prof. K. N. Houk Prof. Frank Glorius 《Angewandte Chemie (International ed. in English)》2018,57(19):5520-5524
An unprecedented dearomatized spirocyclopropane intermediate was discovered in a sequential Cp*RhIII‐catalyzed C?H activation and Wagner–Meerwein‐type rearrangement reaction. How the oxidative O?N bond is cleaved and the role of HOAc were uncovered in this study. Furthermore, a Cp*RhIII‐catalyzed dearomatization reaction of N‐(naphthalen‐1‐yloxy)acetamide with strained olefins was developed, affording a variety of spirocyclopropanes. 相似文献
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