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Synergetic catalytic effect of rGO,Pd, Fe3O4 and PPy as a magnetically separable and recyclable nanocomposite for coupling reactions in green media
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In this paper, rGO/Pd–Fe3O4@PPy as an efficient stable nanocomposite was synthesized. To understand the synergetic effects of rGO, Pd, Fe3O4 and PolyPyrrole, the performance of rGO/Pd–Fe3O4@PPy as a heterogeneous recyclable nanocatalyst in the green synthesis of C‐C and C‐O coupling products, as well as different conditions are studied. Synthesized rGO/Pd–Fe3O4@PPy was characterized by FT‐IR, XRD, FE‐SEM, EDS, TGA and AFM analysis. Best results are obtained under sonication in H2O for C‐C coupling and by ball‐milling for C‐O coupling. The benefits of this method include: green solvents and conditions, absence of external base, low reaction times with high yield and easy work‐up method. 相似文献
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超声条件下, 在乙醇分散的3-氨丙基三乙氧基硅烷(APTES)功能化的磁性Fe3O4纳米粒子和四氯合金酸的混合溶液中滴加柠檬酸钠, 成功地制备了磁性Fe3O4/Au复合纳米粒子. 采用X射线粉末衍射仪(XRD)、紫外吸收可见光谱(UV-Vis)、带有电子能谱仪(EDS)的扫描电子显微镜(SEM)、透射电子显微镜(TEM)、光电子能谱(XPS)、超导量子干涉仪(SQUID)等方法, 对复合粒子的形态、结构、组成以及磁学性质进行了表征. 结果表明: 在此条件下制得的复合粒子粒径在30 nm左右, 室温下磁化强度可达63 emu/g. 相似文献
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Nina Perkas Michael Shuster Galina Amirian Yuri Koltypin Aharon Gedanken 《Journal of polymer science. Part A, Polymer chemistry》2008,46(5):1719-1729
Silver nanoparticles were immobilized on the surface of polypropylene (PP) porous beads by an ultrasound‐assisted reduction method. The structure and properties of the silver–PP composite were characterized with XRD, TEM, HRSEM, EDX, XPS, and Raman spectroscopy. Water‐soluble polymers such as PEG, PVA, and PVP were used as stabilizing agents for preventing the agglomeration of the silver nanoparticles. With PVP, a homogeneous distribution of silver nanocrystals, 50 nm in size, on the PP surface was achieved. The mechanism proposed for the silver anchoring to the inert polymer accounts for a localized melting of the PP. The beads of the silver PP composite demonstrated good stability and high antibacterial activity. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1719–1729, 2008 相似文献
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This paper describes an efficient method of inducing sonochemical reactions with focussed ultrasound. A sector-vortex transducer (a phased array transducer with multiple sectors and a geometric focus) is used to produce focal ultrasound fields with spiral-shaped wavefronts. Clockwise and counter-clockwise spiral focal fields, with basically the same ultrasound power distribution but having different wavefront angles, are produced by using the same array transducer. The oxidation of the iodide ions induced from the periodic switching between such a pair of spiral focal fields is investigated at an ultrasound frequency of 750 kHz. The oxidation rate at the optimum switching period (3 ms) is about ten times higher than that at switching periods of 1 s. The optimum switching period and the sonochemical reaction rate are unchanged when the viscosity was adjusted to that of human blood. 相似文献
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不使用有机模板剂,采用超声化学法一步水解制得吸附硫酸根的介孔偏钛酸,500℃焙烧得到介孔SO2-4/TiO2固体超强酸.用XRD、TFEM、FTIR、低温氮吸附-脱附等手段对催化剂结构进行了表征.结果表明,硫酸根在焙烧过程中与前驱体介孔偏钛酸孔壁上自由羟基的键合起到了孔结构导向及支撑作用,500℃焙烧后样品具有161 m2·g-1的比表面积及4.1 nm的平均孔径,酸强度H0介于-14.52与-16.02之间,硫含量为2.8%,晶型全部为锐钛矿相,介孔SO2-4/TiO2具有较大比表面、强酸特性和稳定性.催化合成富马酸二甲酯的最佳条件为:n(甲醇):n(富马酸)=6:1,催化剂用量为1.0%(反应物总质量),带水剂苯用量为10 mL,反应时间为3 h,催化剂重复使用7次,酯化率大于90%. 相似文献
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Wanquan Jiang Wei Zhu Chao Peng Fan Yang Shouhu Xuan Xinglong Gong 《Crystal Research and Technology》2012,47(9):997-1003
Large‐scale chrysanthemum‐like strontium molybdate (SrMoO4) with hierarchical structure has been successfully synthesized via a facile and fast ultrasound irradiation approach at room temperature. By varying the experimental conditions, SrMoO4 with different morphologies, such as spindles, peanuts, spheres, and rods, can be obtained. The products are characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and selected‐area electron diffraction (SAED). The influent parameters including concentration, pH value, and surfactants have been investigated. A possible growth mechanism is proposed and the shape evolution of the products is characterized. The as‐prepared chrysanthemum‐like SrMoO4 particles are used as the precursor for electrorheological fluid and their electrorheological property is investigated. 相似文献
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A new supramolecular zinc(II) complex containing 4‐biphenylcarbaldehyde isonicotinoylhydrazone ligand: Nanostructure synthesis,catalytic activities and Hirshfeld surface analysis
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Yunes Abbasi Tyula Abedien Zabardasti Hamid Goudarziafshar Monika Kucerakova Michal Dusek 《应用有机金属化学》2018,32(3)
A new potentially tridentate hydrazone ligand, 4‐biphenylcarbaldehyde isonicotinoylhydrazone (4‐bpinh), was prepared by the condensation of biphenyl‐4‐carboxaldehyde with isonicotinic acid hydrazide. Then, its nano‐sized and single crystal of zinc complex were synthesized using sonochemical and heat gradient methods, respectively. The structure of complex, [Zn(4‐bpinh)2 Br2] (1), was determined by single‐crystal X‐ray diffraction, FT‐IR, and elemental analysis, and the nano‐structure of complex was characterized by FT‐IR, XRD, and SEM. The single crystal X‐ray structure of complex showed that the metal center has a distorted tetrahedral geometry and the hydrazone ligand acts as monodentate trough the pyridyl N atom. Moreover, the analysis of crystal structures indicates the existence of intermolecular interactions such as N/C–H?Br/O, N/C–H?π, and π?π stacking in the stabilization of complex structure which finally led to the formation of the three‐dimensional supramolecular structure. Also, the impact of this interactions was more studied using Hirshfeld surface analysis and corresponding 2D fingerprint plots. Furthermore, the catalytic activity of 1 was studied in the selective oxidation of various sulfides to corresponding sulfoxides using hydrogen peroxide as the oxidative agent. 相似文献
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An efficient sonochemical protocol for the nitration of aromatic compounds was described in the presence of a catalytic amount of sulfuric acid-functionalized silica-based core/shell magnetic nanocomposite at room temperature in an eco-friendly and recyclable media, deep eutectic solvent (DES), based on choline chloride and urea. The particle size, morphology and elemental analysis of the core/shell nanocatalyst were carried out by TEM, SEM, EDX and XRD analyses. The nanocatalyst and DES were easily recovered from the reaction mixture quantitatively and reused several times. 相似文献
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Polyaniline (PANI) is one of the most investigated intrinsically conducting polymers. Copolymerization of aniline with aniline derivatives was considered one of the most effective and promising ways of improving the properties of PANI. In this work, firstly ethyl 3‐aminobenzoate and butyl 3‐aminobenzoate were synthesized from 3‐aminobenzoic acid by direct esterification. Then the copolymerization of 3‐amino benzoic acid, ethyl 3‐aminobenzoate, and butyl 3‐aminobenzoate with aniline was carried out by sonochemical polymerization in aqueous hydrochloric acid using ammonium persulfate (APS) as an initiator. The effects of variation in the molar ratio of the two monomers on chain structure, conductivity, and the redox properties of the copolymer are discussed. The prepared polymers are characterized by 1H NMR spectroscopy, X‐ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT‐IR). Thermal behavior of the prepared copolymers was studied by differential scanning calorimetry. The copolymers were doped with HCl and their conductivity was measured. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献