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排序方式: 共有163条查询结果,搜索用时 15 毫秒
1.
A thermal analysis study on the reduction of iron oxide rich slags under different conditions is presented in this paper. The effects of important process variables such as time, temperature, lime-silica ratio, FeO level in slag etc. are discussed. It is shown that the mechanism of reduction by externally added graphite is different from that by a carbon saturated bath although the activation energy values are similar. 相似文献
2.
Carmen Luna Concepción Lloreda Juan F. Almagro Bello Jaime Botella Maria J. Orts Ana Gozalbo 《Mikrochimica acta》2004,145(1-4):121-127
Non-metallic inclusions in steel are formed due to interactions between liquid steel and its environment in the melting shop (refractories and slags). Particles not trapped in the slag remain in the cast steel, impairing steel properties in service. Inclusion composition varies and certified standards covering the whole compositional range are unavailable.The present study describes the preparation of a set of homogeneous, glassy and crystalline standards with a wide compositional range for use in analysing non-metallic steel inclusions. For this, materials were designed based on knowledge of the compositional range of interest in the Al2O3–SiO2–CaO–MgO–CaF2 system, which is the matrix of the most frequent steel inclusions. The composition and microstructural homogeneity of the reference materials was verified. 相似文献
3.
In the process of industrial corporation activities a lot of waste, which pollutes the atmosphere, is generated, for example ash and slag. In Tomsk region, by estimates, ash stores occupy about 600 hectares, which contain about 25 million tons by weight. In Russian thermal power-stations ash disposal areas there are about 1.3 billion tons of ash, and only 10% of it is used. That is why this problem is topical enough. In this paper the scheme of producing ash ceramic bricks and complex ash and slag waste processing is shown. Besides, profitability of the project is presented. 相似文献
4.
Sujie Yang Xiuyu Liu Gang Tang Hongming Long Bibo Wang Hao Zhang Yilong Ji Yadong Yang 《先进技术聚合物》2022,33(1):452-463
A series of FR-RPUF composites were prepared by a one-step water foaming process with ammonium polyphosphate (APP) and steel slag (SS) as flame retardants. Thermogravimetric analysis (TG), limiting oxygen index (LOI), UL-94 vertical combustion test, microscale combustion calorimetry (MCC), TG-Fourier transform infrared spectrometry (TG-FTIR), scanning electron microscopy (SEM), Raman spectra and FTIR were used to investigate the thermal stability, flame retardancy, combustion performance, gas phase products, and char residue morphology of FR-RPUF composites. TG test results showed that the initial decomposition temperature (T-5wt%) and char residue rate at 700°C of RPUF/APP/SS composites were significantly enhanced by the addition of APP and SS, and the thermal stability of the composites was improved. Flame retardant test results confirmed the significantly increased LOI values of RPUF/APP/SS composites with V-0 rating. TG-FTIR also confirmed the obviously decreased release of toxic gases and flammable gases in the combustion of RPUF/APP/SS composites. SEM and Raman spectra of char residues for the composites suggested that APP/SS system improved the compactness and graphitization degree of char layer for RPUF/APP/SS composite. The above researches provide a new strategy for the utilization of SS in fire safety engineering. 相似文献
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6.
钢渣是冶金工业中产生的主要固体废弃物,其产量约为每年粗钢产量的15%~20%。由于技术的局限,导致我国钢渣利用率较低,仅为年钢渣产量的10%,同时加之管理制度的不健全,导致钢渣大量露天堆放,对土地资源、地下水源,以及空气质量形成严重影响。固体废弃物再利用是资源可持续发展的重要途径之一,钢渣的主要化学成分为CaO, SiO2, Al2O3, MgO, Fe2O3, MnO, f-CaO等。面对上述问题,利用冶金固体废弃物与活性炭开发一种价格低廉且性能优越的活性炭混合钢渣复合材料,既是冶金固体废弃物的高附加值利用与资源可持续发展的重要途径之一,也是大幅降低改性活性炭生产成本与提高经济效益的重要途径之一。该研究创新性以活性炭与钢渣为研究对象,利用钢渣中含有的金属氧化物对活性炭进行改性处理制备用于烧结烟气脱硫脱硝的活性炭混合钢渣复合材料,通过搭建实验反应装置对活性炭混合钢渣复合材料的脱硫脱硝性能进行测试。利用X射线荧光光谱仪(XRF)对钢渣的化学成分进行测试与分析,比表面积及孔径测定仪(BET)对活性炭混合钢渣复合材料的孔结构进行测试与分析,傅里叶变换红外光谱仪(FTIR)对钢渣的结构组成进行测试与分析,扫描电子显微镜(SEM)对活性炭混合钢渣复合材料的微观结构进行测试与分析,以揭示活性炭与钢渣制备活性炭混合钢渣复合材料的机理,以及活性炭混合钢渣复合材料对烧结烟气脱硫脱硝的机理。结果表明:当钢渣为电炉热泼渣、钢渣与活性炭质量比为2∶4、钢渣与活性炭细度为400目时,活性炭混合钢渣复合材料具有良好的脱硫脱硝性能与合理的经济性,即脱硫效率为100%、脱硝效率为58%。活性炭混合钢渣复合材料具有的多孔结构对SO2和NO进行有作用,钢渣中Fe2O3与MnO2促使活性炭官能团进行催化还原反应提高脱硫脱硝性能,其中吸附作用是主导与前提,催化还原反应是辅助与协同。以期为高附加值的钢渣利用提供新途径,实现钢铁企业以废治废、以废增效的目的。 相似文献
7.
以磷铁废渣(Fe1.5P)和温室效应气体CO2为原料,以磷酸为补充磷源合成磷酸铁锂(LiFePO4)的前驱体Fe2P2O7,并研究了其合成过程对LiFePO4正极材料储能性能的影响。采用SEM观察了LiFePO4的表面形貌,采用XRD分析了LiFePO4和Fe2P2O7的晶体结构。进一步对该方法进行优化,发现Fe1.5P与磷酸混合物(nFe1.5P:nH3PO4=1:1)在800℃热处理6 h合成的Fe2P2O7对应的LiFePO4/C电化学性能最好,在0.1C,0.2C,0.5C和1C倍率下的容量分别可达130,126,117和108 mAh·g-1。该方法具有成本低廉,减少碳排放和环境友好等特点,为LiFePO4正极材料的生产提出了一种新的工艺。 相似文献
8.
选择CaO和纯碱作为激发剂掺入GGBS(粒化高炉矿渣微粉)制备GGBS+CaO+纯碱固化合肥湖积软土,通过无侧限抗压强度试验研究固化黏土的强度变化规律。以GGBS、CaO和纯碱的掺量作为影响因子,以7d和28d固化土的无侧限抗压强度作为响应值,基于Box-Behnken法确定3种外添剂的最佳配合比。研究表明:GGBS掺量的变化对强度响应影响最大,且其敏感程度随龄期的增大而增大;而对于CaO和纯碱,情况则相反。养护7d后,各因素对强度的线性效应和曲面效应均显著,CaO与纯碱的交互作用显著;养护28d后,GGBS与纯碱的交互作用显著。最终得出:GGBS、CaO和纯碱三掺量固化黏土最佳配比分别为13.08%、4.89%和1.25%;在最佳配合比下,7d和28d的预测强度分别达到550.904kPa和665.953kPa。最后对实测值与预测值进行了对比分析。研究成果可为在合肥滨湖地区应用矿渣类软土固化剂提供理论依据。 相似文献
9.
Waste minimization strategy was applied in the current work for synthesis of the catalysts from industrial solid waste, namely desulfurization slag. The starting slag material comprising CaCO3, Ca(OH)2, SiO2, Al2O3, Fe2O3, and TiO2 was processed by various treating agents systematically varying the synthesis parameters. A novel efficient technique – ultrasound irradiation, was applied as an additional synthesis step for intensification of the slag dissolution and crystallization of the new phases. Physico-chemical properties of the starting materials and synthesized catalysts were evaluated by several analytical techniques. Treatment of the industrial slag possessing initially poor crystal morphology and a low surface area (6 m2/g) resulted in formation of highly-crystalline catalysts with well-developed structural properties. Surface area was increased up to 49 m2/g. High basicity of the neat slag as well as materials synthesized on its basis makes possible application of these materials in the reactions requiring basic active sites. Catalytic performance of the synthesized catalysts was elucidated in the synthesis of carbonate esters by carboxymethylation of cinnamyl alcohol with dimethyl carbonate carried out at 150 °C in a batch mode. Ultrasonication of the slag had a positive effect on the catalytic activity. Synthesized catalysts while exhibiting similar selectivity to the desired product (ca. 84%), demonstrated a trend of activity increase for materials prepared using ultrasonication pretreatment. The choice of the treating agent also played an important role in the catalytic performance. The highest selectivity to the desired cinnamyl methyl carbonate (88%) together with the highest activity (TOF35 = 3.89*10−7 (mol/g*s)) was achieved over the material synthesized using 0.6 M NaOH solution as the treating agent with the ultrasound pre-treatment at 80 W for 4 h. 相似文献
10.