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1.
Rb2I(OH): A Hydroxide Iodide in the System RbOH/RbI The pseudobinary system RbOH/RbI was investigated by X-ray methods. The crystal structure of Rb2I(OH) was solved by single crystal data: Rb2I(OH): Pnma, Z = 4, a = 7.748(1) Å, b = 5.654(2) Å,c = 13.254(2) Å Z(Fo) with (Fo)2 ? 3σ = (Fo)2 = 449, Z (parameter) = 25, R/Rw = 0.021/0.023 Rb2I(OH) crystallizes in a new type of structure, built up by a three dimensional network of [Rb2(OH)+] containing the iodide ions. 相似文献
2.
Synthesis and Crystal Structure of Calcium Imide, CaNH Single-crystals of calcium imide were obtained for the first time by the reaction of a mixture of calcium amide with sodium amide at 850°C in an autoclave for salt melts. After cooling the autoclave to room temperature the crystals are embedded in solid Na which was extracted by liquid ammonia. The structure of calcium imide was determined from single-crystal diffractometer data: space group Fm3 m, Z = 4, a = 5.143(1) Å, R/Rw = 0.032/0.028 mit N(F ? 3σ(F )) = 26, N(Var.) = 5. Ca and N atoms are arranged in the motif of the NaCl structure type. The hydrogen atoms of the imide groups are disordered within the Ca octahedra, and they occupy a six fold split position. 相似文献
3.
Compounds in the Systems Potassium(Rubidium)/Gold/Antimony: K3Au3Sb2, Rb3Au3Sb2, and K1,74Rb0,26RbAu3Sb2 Brittle, silver coloured single crystals of K3Au3Sb2, Rb3Au3Sb2 and K1,74Rb0,26RbAu3Sb2 were obtainded by reaction of the alkali metal azides (KN3, RbN3) with gold and antimon powder at 550°C. The structures of the isotypic compounds (R3 m, Z = 3) were determined by X-ray single-crystal diffractometer data: K3Au3Sb2, a = 6,198(2) Å, c = 21,520(5) Å, R/Rw (w = 1) = 0,046/0,058, Z(F) ? 3σ(F) = 175, Z(Var.) = 14; Rb3Au3Sb2, a = 6,443(3), c = 21,69(2), R/Rw (w = 1) = 0,059/0,082, Z(F) ? 3σ(F02) = 258, Z(Var.) = 14; K1,74Rb0,26RbAu3Sb2, a = 6,288(2) Å, c = 21,617(5) Å, R/Rw (w = 1) = 0,049/0,069, Z(F) ? 3σ(F) = 390, Z(Var) = 14. The compounds crystallize with the K3Cu3P2-structure type. The Au? Sb partial structures consist of [AuSb2/3] layers with linear Sb? Au? Sb dumb-bells and SbAu3 pyramids. The layers are separated by two crystallographically independent alkali metal atoms along [001]. 相似文献
4.
Na7I2(OH)5: A Hydroxide Iodide in the System NaOH/NaI The pseudobinary system NaOH/NaI is investigated by X-ray methods. The crystal structure of the compound Na7I2(OH)5 was solved by single crystal data: Na7I2(OH)5: P4/nmm, Z = 2, a = 7.748(2) Å, c = 10.260(3) Å, Z(Fo) = 443 with (Fo)2 ≥ 3σ(Fo)2, Z(parameter) = 28, R/Rw = 0.044/0.059 Na7I2(OH)5 crystallizes in a new type of structure which contains puckered layers of ∞2[Na7(OH)52+] connected via iodide ions. 相似文献
5.
Na4Br(NH2)3: An Amide Bromide in the System NaNH2/NaBr The pseudobinary system NaNH2/NaBr was investigated by X-ray methods. The crystal structure of Na4Br(NH2)3 was solved by single crystal data: Pnnm, Z = 4, a = 6.579(2) Å, b = 12.755(4) Å, c = 8.776(2) Å Z(Fo) with (Fo)2 ≥ 3σ = (Fo)2 = 503, Z(parameter) = 39, R/Rw = 0.082/0.106. It is a new type of structure, built up by a three-dimensional network of [Na4(NH2)3+] containing the bromide ions. 相似文献
6.
Tetraammine Lithium Cations Stabilizing Phenylsubstituted Zintl-Anions: The Compound [Li(NH3)4]2[Sn2Ph4] Ruby-red, brittle single crystals of [Li(NH3)4]2[Sn2Ph4] were synthesized by the reaction of diphenyltin dichloride and metallic lithium in liquid ammonia at ?35°C. The structure was determined from X-ray singlecrystal diffractometer data: Space group, P1 , Z = 1, a = 9.462(2) Å, b = 9.727(2) Å, c = 11.232(2) Å, α = 66.22(3)°, β = 85.78(3)°, γ = 61.83(3)°, R1 (F ? 4σF) = 5.13%, wR2 (F02 ? 4σF) = 10.5%, N(F ? 4σF) = 779, N(Var.) = 163. The compound contains to Sb2Ph4 isosteric centres [Sn2Ph4]2? as anions which are connected to rods by lithium cations in distorted tetrahedral coordination by ammonia. These rods are arranged parallel to one another in the b,c-plane, but stacked along [100]. 相似文献
7.
Uwe Zachwieja 《无机化学与普通化学杂志》1995,621(10):1677-1680
NaAuIn2, a Ternary Auride with Ethane Analogous In2Au6 Building Units and [In2/2] Chains Silver coloured, brittle single crystals of NaAuIn2 were synthesized by the reaction of NaN3, gold-sponge and indium at 500°C. The structure was determined from X-ray single-crystal diffractometry data: space group Cmcm, Z = 4, a = 4.482(1) Å, b = 10.366(2) Å, c = 7.869(2) Å, R/Rw(w = 1) = 0.017/0.020, Z(F) ≥ 3σ(F) = 547 and N(var.) = 16. NaAuIn2 crystallizes in the MgCuAl2-structure type. Gold and indium form a framework structure. [AuIn6/3] layers with trigonal prismatically coordinated gold are connected via In—In contacts along [010] which consist of ethane analogous In2Au6-building units. The In-partial structure consists of saw tooth like [In2/2] chains along [001]. The sodium atoms occupy channel-like cavities within the Au—In framework structure. 相似文献
8.
Na5Br(OH)4: Synthesis and Structure of a Compound in the System NaOH/NaBr The pseudobinary system NaOH/NaBr is investigated by X-ray methods. The structure of the compound Na5Br(OH)4 was solved by single crystal data: Na5Br(OH)4: Pnma, Z = 8, a = 11.846(2) Å, b = 18.782(4) Å, c = 6.431(1) Å, Z(Fo) = 1 202 with (Fo)2 ≥ 3σ(Fo)2, Z(parameter) = 100, R/Rw = 0.030/0.035 The compound crystallizes in a new type of structure. Pairs of octahedra around O by 5 Na and 1 H to [Na5(OH)]2 are orientated in such a way to one another that two ions OH? form a parallelogram hinting to unusual bent hydrogen bridge bonding. 相似文献
9.
Sun‐Min Jung Dongwook Kim Dongbin Shin Dr. Javeed Mahmood Prof. Dr. Noejung Park Prof. Dr. Myoung Soo Lah Prof. Dr. Hu Young Jeong Prof. Dr. Jong‐Beom Baek 《Angewandte Chemie (International ed. in English)》2016,55(26):7413-7417
Solid‐state reactions have been rapidly gaining popularity in organic chemistry owing to their simplicity, efficiency, and selectivity compared to liquid‐phase reactions. Herein, we describe the formation of superstructures through the solid‐state reaction of an organic single‐crystal. The superstructure of 5,5′,5′′‐(1,3,5‐triazine‐2,4,6‐triyl)triisophthalonitrile (TIPN) can be formed by cyclotrimerization of 1,3,5‐tricyanobenzene (TCB) single crystals. The TIPN superstructure was confirmed by single crystal X‐ray diffraction and visualized by transmission electron microscopy. The superstructure has hexagonally packed 1‐dimensional (1D) channels along the crystal axis. Furthermore, the superstructure arises from interdigitated nitrile interactions in the crystal lattice, and thus has electron‐beam tolerance and very high thermal stability. 相似文献
10.
Uwe Zachwieja 《无机化学与普通化学杂志》1996,622(7):1173-1176
NaAuGe, a Further Ternary Auride with Ethane Analogous Ge2Au6 Building Units Black, brittle single crystals of NaAuGe were obtained by the reaction of NaN3, gold sponge and germanium at 800°C. The structure was determined from X-ray single-crystal diffractometry data: space group Imm2, Z = 4, a = 4.422(1) Å, b = 7.238(2) Å, c = 7.531(2) Å, R1/wR2 = 0.0195/0.0482, N(F) ≥ 2σ(F) = 811 and N(var.) = 21. NaAuGe crystallizes in a new ternary variant of the KHg2 (CeCu2)structure type. Gold and germanium form puckered [AuGe3/3] layers with trigonal planar coordinated gold. The [AuGe3/3] nets are connected to a framework structure via Ge—Ge contacts along [010] which consist of ethane analogous Ge2Au6 building units. The sodium atoms are placed in channels of the Au—Ge framework structure which run along [100] and [010]. 相似文献