全文获取类型
收费全文 | 197篇 |
免费 | 12篇 |
国内免费 | 9篇 |
专业分类
化学 | 127篇 |
力学 | 28篇 |
数学 | 14篇 |
物理学 | 49篇 |
出版年
2019年 | 6篇 |
2018年 | 7篇 |
2017年 | 9篇 |
2016年 | 10篇 |
2015年 | 9篇 |
2014年 | 9篇 |
2013年 | 13篇 |
2012年 | 8篇 |
2011年 | 5篇 |
2010年 | 5篇 |
2009年 | 8篇 |
2008年 | 8篇 |
2007年 | 9篇 |
2006年 | 10篇 |
2005年 | 16篇 |
2004年 | 7篇 |
2003年 | 19篇 |
2002年 | 12篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1982年 | 6篇 |
1981年 | 5篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1948年 | 1篇 |
排序方式: 共有218条查询结果,搜索用时 46 毫秒
1.
2.
O. Životský K. Postava L. Kraus M. Foldyna J. Pištora 《Journal of magnetism and magnetic materials》2006
In this paper we investigate the surface magnetic properties of as-quenched (AQ) CoFeCrBSi ribbons prepared by planar flow casting method with using magneto-optic Kerr effect (MOKE). Measured hysteresis loops in longitudinal and transversal configurations enable us to obtain the information of ribbons surface magnetic properties. Moreover, we suggest new magneto-optic method, which is based on measurements of magneto-optical effects depending on DC current flowing through the ribbon. Experimental data of AQ ribbons are then compared with the model, which describes the influence of incidence angle on magneto-optical angles. 相似文献
3.
Optimale Quantisierung 总被引:1,自引:0,他引:1
Peter M. Gruber 《Mathematische Semesterberichte》2002,49(2):227-251
Zusammenfassung. Optimale Quantisierungen oder – damit ?quivalent – minimale Summen von Momenten spielen in mehreren Zweigen der Mathematik
und ihrer Anwendungen eine Rolle. Ausgehend von der Fejes Tóth'schen Ungleichung für Summen von Momenten in der euklidischen
Ebene und einem zugeh?rigen Stabilit?tssatz, werden gewisse Erweiterungen auf normierte R?ume und riemannsche Mannigfaltigkeiten
h?herer Dimension besprochen. Die Ergebnisse werden dann auf Probleme aus folgenden Bereichen angewendet: (i) Datenübertragung,
(ii) Wahrscheinlichkeitstheorie, (iii) numerische Integration, (iv) Approximation konvexer K?rper und (v) isoperimetrische
Probleme.
Eingegangen am 29. Mai 2002 / Angenommen am 8. Juli 2002 相似文献
4.
Marc Visseaux Mickael Terrier Andr Mortreux Pascal Roussel 《Comptes Rendus Chimie》2007,10(12):1195-1199
The reaction of one equivalent of Nd(BH4)3(THF)3 with an half equivalent of dialkylmagnesium in the presence of a stoichiometric amount of pentamethylcyclopentadiene cleanly affords a new kind of half-sandwich of neodymium that is stable toward comproportionation. This strategy can be advantageously applied to generate in situ catalysts allowing the controlled polymerisation of isoprene. 相似文献
5.
The apparent molar volumes V of KCl, BaCl2, K2SO4, LaCl3, Co(en)3Cl3 [Tris(ethylenediamine)cobalt(III) chloride], K3Co(CN)6, K3Fe(CN)6, K4Fe(CN)6, and Ba3[Co(CN)6]2 have been determined at 25°C in both light and heavy water. The V values in D2O are systematically lower and increase more rapidly with salt concentration than the V in H2O. The volume of transfer from H2O to D2O as well as the partial molar volume at infinite dilution in both solvents have also been calculated. These results together with literature values for other electrolytes were used to estimate both of these quantities for D2O solutions of individual ions. The predictions of ion hydration models and ion-ion interactions are compared with experimental observations. 相似文献
6.
7.
8.
Lophenol, cholest-4α-methyl-7-en-3β-ol (1), obtained from Dracaena cochinchinensis (Lour.) S. C. Chen, was structurally modified. It was acetylated to protect 3β-hydroxyl group, and then oxidised by selenium dioxide in acetic acid to give cholest-4a-methyl-8-en-3β, Ta-diol diacetate (3). This compound 3 is unstable in chloroform solution or when heated and easily converted to a diene compound, cholest-4a-methyl-7,14-dien-3β-ol acetate (4). The structures of 3 and 4 were elucidated by means of IR, ^1H NMR, ^13C NMR and MS, and the absolute configuration of 3 was established by X-ray crystallography. The property of 3 was also discussed in this paper. Both 3 and 4 are new compounds and were reported for the first time. 相似文献
9.
《Comptes Rendus Physique》2016,17(10):1072-1083
Thermoelectric devices are heat engines, which operate as generators or refrigerators using the conduction electrons as a working fluid. The thermoelectric heat-to-work conversion efficiency has always been typically quite low, but much effort continues to be devoted to the design of new materials boasting improved transport properties that would make them of the electron crystal–phonon glass type of systems. On the other hand, there are comparatively few studies where a proper thermodynamic treatment of the electronic working fluid is proposed. The present article aims at contributing to bridge this gap by addressing both the thermodynamic and transport properties of the thermoelectric working fluid covering a variety of models, including interacting systems. 相似文献
10.
Muhammad Umer Faroque Sammer Yousuf Salman Zafar M. Iqbal Choudhary Maqsood Ahmed 《Acta Crystallographica. Section C, Structural Chemistry》2016,72(5):398-404
Biotransformation is the structural modification of compounds using enzymes as the catalysts and it plays a key role in the synthesis of pharmaceutically important compounds. 10β,17β‐Dihydroxy‐17α‐methylestr‐4‐en‐3‐one dihydrate, C19H28O3·2H2O, was obtained from the fungal biotransformation of methyloestrenolone. The structure was refined using the classical independent atom model (IAM) and a transferred multipolar atom model using the ELMAM2 database. The results from the two refinements have been compared. The ELMAM2 refinement has been found to be superior in terms of the refinement statistics. It has been shown that certain electron‐density‐derived properties can be calculated on the basis of the transferred parameters for crystals which diffract to ordinary resolution. 相似文献