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1.
Azepane rings have been constructed diastereoselectively upon a carbohydrate derivative utilising reductive amination and RCM. The stereochemistry of the ring junctions was confirmed by X-ray crystallography and NMR. Diastereoselective dihydroxylation has also been employed to afford a tetrahydroxylated azepane carbohydrate derivative with potential biological activity. 相似文献
2.
Consider the problem of rolling a dynamically asymmetric balanced ball (the Chaplygin ball) over a sphere. Suppose that the
contact point has zero velocity and the projection of the angular velocity to the normal vector of the sphere equals zero.
This model of rolling differs from the classical one. It can be realized, in some approximation, if the ball is rubber coated
and the sphere is absolutely rough. Recently, J. Koiller and K. Ehlers pointed out the measure and the Hamiltonian structure
for this problem. Using this structure we construct an isomorphism between this problem and the problem of the motion of a
point on a sphere in some potential field. The integrable cases are found.
相似文献
3.
用A的不变子空间作参数,给出了算子方程AX=XAX的全部解。当A是单射或稠值域时,或者当A是正规算子时,给出了算子方程AX=XA=XAX的全部解。我们还给出正规算子X是算子方程AX=XZ=XAX的解的充分必要条件。 相似文献
4.
A facile, rapid and regioselective method for the 1-O-deacylation of peracylated glycopyranoses is described which occurs under mild conditions by absorption onto alumina using microwave irradiation. 相似文献
5.
2-Amino-2,4-anhydro-psicofuranose derivative was synthesized starting from d-fructose. 相似文献
6.
It is generally in a firm’s interest for its supply chain partners to invest in innovations. To the extent that these innovations either reduce the partners’ variable costs or stimulate demand for the end product, they will tend to lead to higher levels of output for all of the firms in the chain. However, in response to the innovations of its partners, a firm may have an incentive to opportunistically increase its own prices. The possibility of such opportunistic behavior creates a hold-up problem that leads supply chain partners to underinvest in innovation. Clearly, this hold-up problem could be eliminated by a pre-commitment to price. However, by making an advance commitment to price, a firm sacrifices an important means of responding to demand uncertainty. In this paper we examine the trade-off that is faced when a firm’s channel partner has opportunities to invest in either cost reduction or quality improvement, i.e. demand enhancement. Should it commit to a price in order to encourage innovation, or should it remain flexible in order to respond to demand uncertainty. We discuss several simple wholesale pricing mechanisms with respect to this trade-off. 相似文献
7.
Crosslinked hyaluronan gels are used in various applications where their stability is a prerequisite. The sensitivity of such gels to hyaluronidase can be determined as an index of stability by several approaches: chromatography, electrophoresis, and viscometry. We describe here a test based on the colorimetric determination of the N-acetyl-d-glucosamine released by hyaluronidase in standardized conditions. The sensitivities to bovine testicular hyaluronidase of 11 different gels used to fill skin wrinkles (Restylane; Perlane; Juvéderm 18, 24, 24HV, 30, and 30HV; Surgiderm 18, 24XP, 30, and 30XP) were compared.The method was reproducible, easy to perform, not time-consuming and allowed us to demonstrate that the sensitivity to testicular hyaluronidase was dependent on the degree of crosslinking of the gels and also on their monophasic/biphasic nature. Under our conditions, Surgiderm 30, 24XP and 30XP were the most resistant gels.We propose to retain the hyaluronidase test to predict the in situ stability of a crosslinked gel used to fill skin wrinkles. 相似文献
8.
Yu. V. Tomilov I. V. Kostyuchenko G. P. Okonnishnikova I. P. Klimenko E. V. Shulishov 《Russian Chemical Bulletin》2006,55(11):2008-2012
A new way of generating cyclopropyl radicals in the base-catalyzed decomposition of N-cyclopropyl-N-nitrosourea in the presence of organic reducing agents (1-phenylpyrazolidin-3-one and 4-methoxyphenol) was developed. The
cyclopropyl radical generated under these conditions can not only abstract a proton from the substrate to give cyclopropane
but also form C-C or C-Br bonds in reactions with aromatic substrates or polybromomethanes.
Dedicated to Academician O. M. Nefedov on the occasion of his 75th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1934–1938, November, 2006. 相似文献
9.
The boxes contained kiwifruits were irradiated with cobalt-60 γ-rays at different dosages (0.6 , 1.8 and 3.6 KGy) and stored in a room ventilated at night, the natural ambient air being used as cool source.The results showed that the treatment which fruits irradiated with 0.6 KGy was the best after 85 days. It gave the normal-fruit rate of 95.10%, fruit flesh hardness of 4.10 Kg · cm-2, fresh and plump fruits, good quality and less Vc loss. 相似文献
10.
Boris Pejin Kristina Tešanović Dragica Jakovljević Sonja Kaišarević Filip Šibul Milena Rašeta 《Natural product research》2019,33(5):750-754
The polysaccharide (PSH) extracts from the edible mushroom species Coprinus comatus and Coprinellus truncorum were screened in liquid for their acetylcholinesterase inhibitory (AChE) activity. Both extracts were found to display inhibition of the aforementioned enzyme reaching similar IC50 values of 0.62 ± 0.07 and 0.61 ± 0.03 mg/mL, respectively. According to the means of FTIR spectroscopy, these PSH extracts mostly contained β-glucans. However, the presence of some proteins and polyphenolics as minor ingredients were also detected. Compared with existing literature data for anti-AChE activity of the sugar samples, the findings within this study may be treated as a profound bioactivity. Consequently, this study puts some light on the possible use of the screened macrofungi in the palliative treatment of Alzheimer’s disease. 相似文献