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1.
Chikyu Lee Eun Ju Park Miseon Won Yeong-Soon Gal Jun Liu Liming Dai 《Molecular Crystals and Liquid Crystals》2015,621(1):8-16
Electroluminescent (EL) properties of Ir(III) complex, [(2,4-diphenylquinoli-ne)]2Iridium picolinic acid N-oxide [(DPQ)2Ir(pic-N-O)] were investigated using PEDOT:PSS and reduced graphene oxide (rGO) as a hole transport layer for solution processable phosphorescent organic light-emitting diodes (PhOLEDs). High performance solution-processable PhOLED with PEDOT:PSS and (DPQ)2Ir(pic-N-O) (8 wt%) doped CBP:TPD:PBD (8:56:12) host emission layer were fabricated to give a high luminance efficiency (LE) of 26.9 cd/A, equivelent to an external quantum efficiency (EQE) of 14.2%. The corresponding PhOLED with rGO as a hole transport layer exhibited the maximum brightness and LE of 13540 cd/m2 and 16.8 cd/A, respectively. The utilization of the solution processable rGO thin films as the hole transport layer offered the great potential to the fabrication of solution processable PhOLEDs. 相似文献
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Mui Siang Soh Sonsoles Amor Garcia Santamaria Evan Laurence Williams Marta Pérez‐Morales Henk J. Bolink Alan Sellinger 《Journal of Polymer Science.Polymer Physics》2011,49(7):531-539
A new class of solution processable dendrimers based on cyclic phosphazene (CP) cores have been prepared and used as host materials for blue and green organic light emitting diodes (OLEDs). The dendrimers are prepared in high yield from minimal step reactions, are soluble in common solvents for solution processing, are amorphous, and have excellent thermal properties necessary for application in OLEDs. OLED efficiencies of 10.3 cd/A (4.2 lm/W) and 35.3 cd/A (33.5 lm/W) were achieved using commercially available FIrpic and Ir(mppy)3 as blue and green phosphorescent emitters, respectively. These efficiencies were 2× higher than control devices prepared using poly(N‐vinylcarbazole), the most commonly used host material in solution processed phosphorescent OLEDs. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
3.
Komal Kurlekar Anshika Anjali Dr. Predhanekar Mohamed Imran Prof. Samuthira Nagarajan 《Chemphyschem》2023,24(2):e202200375
A series of new zinc porphyrins were synthesized, and their charge transport property was tuned by introducing various groups. Triarylamine was introduced to the porphyrin moiety at the meso-position as an electron donor, enhancing the charge carrier mobility. All the synthesized zinc porphyrins are thermally stable with a decomposition temperature over 178 °C. High frontier molecular orbitals levels of these compounds make them stable donor materials. SEM analysis of zinc porphyrins fabricated by spin-coating resulted in diversely self-assembled films. Field-effect transistors were fabricated using bottom-gate/top-contact architecture (BGTC) by solution-processable technique. The higher charge carrier mobility of 5.17 cm2/Vs with on/off of 106 was obtained for trifluoromethyl substituted compound due to better molecular packing. In addition, GIXRD analysis revealed zinc porphyrins films crystalline nature, which supports its better charge carrier mobility. The present investigation has validated that zinc porphyrin building blocks are an attractive candidate for p-channel OFET devices. 相似文献
4.
S. Tamai W. Yamashita A. Yamaguchi 《Journal of polymer science. Part A, Polymer chemistry》1998,36(6):971-978
A series of aromatic diamines containing pendent methoxy, phenoxy, and biphenoxy moieties were synthesized. By the reaction of diamines with 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA), several kinds of polyimides having bulky pendent ether groups were synthesized. Thermal properties and processability such as melt processability and solubility in organic solvents of obtained polyimides were investigated by focusing on the chemical structures of their repeating structure units. It was found that the thermal stability and melt processability of the polyimides did not strongly depend on the existence of bulky pendent phenoxy and biphenoxy moieties. Their solubility in organic solvents, however, was improved by introducing the bulky pendent ether groups such as methoxy, phenoxy, and biphenoxy moieties into their repeating structure units. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 971–978, 1998 相似文献
5.
Processable polyaniline doped and complexed with dodecylbenzenesulfonic acid was obtained by one-step micellar chemical polymerization of aniline in the presence of dodecylbenzenesulfonic acid. Homogeneous transparent suspension could be made by dispersing processable polyaniline in m-cresol without any precipitation. Polyaniline composite film blended with polymethylmethacrylate (PMMA) exhibits relatively high levels of conductivity at low volume fractions of the polyaniline, while keeping good mechanical properties, equivalent to those of the PMMA. © 1998 John Wiley & Sons, Ltd. 相似文献
6.
Xin‐Gui Li Hai‐Jun Zhou Mei‐Rong Huang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(23):6109-6124
Copolymers were synthesized through the chemically oxidative polymerization of N‐ethylaniline (EA) and aniline (AN) in five acid aqueous media. The polymerization yield, intrinsic viscosity, molecular weight, solubility, solvatochromism, electrical conductivity, and mechanical properties of the copolymer films were systematically studied through changes in the comonomer ratio, polymerization temperature, oxidant, oxidant/monomer ratio, and acid medium. Open‐circuit‐potential and temperature measurements of the polymerization solutions showed that the polymerization rate depended on the EA content, and the polymerization was an exothermic reaction. The resultant copolymers were characterized in detail with IR, ultraviolet–visible, and 1H NMR spectroscopy, gel permeation chromatography, wide‐angle X‐ray diffractometry, and scanning electron microscopy. The reactivity ratios of the monomer pair were calculated from the 1H NMR spectra of the copolymers formed at a low conversion. The polymers exhibited good solubility and interesting solvatochromism in most of the solvents and variable conductivity with the EA/AN ratio and doping state. The conductivity of the HCl‐doped copolymers increased monotonically from 5.61 × 10?7 to 2.55 × 10?1 S/cm with decreasing EA content from 100 to 0 mol % and showed a percolation transition between EA concentrations of 20 and 30 mol %. The EA/AN copolymers also had excellent film formability and flexibility together with high mechanical and oxygen‐enriching properties. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 6109–6124, 2004 相似文献
7.
Angela Šurca Vuk Sandra Benčič Boris Orel Franco Decker 《Journal of Sol-Gel Science and Technology》2002,23(1):53-66
Electrochemical properties of amorphous and crystalline V2O5 films, dip-coated from V-oxoisopropoxide sols and thermally treated at various temperatures (100, 150, 200 and 300°C), have been studied in extended potential range, i.e. from 1.4 to –1.6 V vs. Ag/AgCl in 1M LiClO4/propylen carbonate (PC) electrolyte. The formation of various lithiated (-, -, - and -Li
x
V2O5) phases was correlated with the values of insertion coefficient x obtained from cyclic voltammograms (CV) of crystalline V2O5 films (300°C). Reversible charging was observed when films were cycled up to –1.0 V vs. Ag/AgCl, while the extension of the potential to –1.3 V vs. Ag/AgCl change the CV of films irreversibly. Charging of crystalline V2O5 films was followed by the help of in-situ UV-visible spectroscopy, that revealed the intensity variations of the polaron absorption above 600 nm and the presence of the absorbing V3+ species between 550 and 650 nm. Ex-situ IR spectra of the crystalline films charged/discharged at –1.6V/1.4V vs. Ag/AgCl confirmed the amorphisation of the films' structure. 相似文献
8.
Guey‐Sheng Liou Sheng‐Huei Hsiao Tzy‐Hsiang Su 《Journal of polymer science. Part A, Polymer chemistry》2005,43(15):3245-3256
We describe the preparation, characterization, and luminescence of four novel electrochromic aromatic poly(amine hydrazide)s containing main‐chain triphenylamine units with or without a para‐substituted N,N‐diphenylamino group on the pendent phenyl ring. These polymers were prepared from either 4,4′‐dicarboxy‐4″‐N,N‐diphenylaminotriphenylamine or 4,4′‐dicarboxytriphenylamine and the respective aromatic dihydrazide monomers via a direct phosphorylation polycondensation reaction. All the poly(amine hydrazide)s were amorphous and readily soluble in many common organic solvents and could be solution‐cast into transparent and flexible films with good mechanical properties. These poly(amine hydrazide)s exhibited strong ultraviolet–visible absorption bands at 346–348 nm in N‐methyl‐2‐pyrrolidone (NMP) solutions. Their photoluminescence spectra in NMP solutions or as cast films showed maximum bands around 508–544 and 448–487 nm in the green and blue region for the two series of polymers. The hole‐transporting and electrochromic properties were examined by electrochemical and spectroelectrochemical methods. All obtained poly(amine hydrazide)s and poly(amine‐1,3,4‐oxadiazole)s exhibited two reversible oxidation redox couples at 0.8 and 1.24 V vs. Ag/AgCl in acetonitrile solution and revealed excellent stability of electrochromic characteristics, changing color from original pale yellow to green and then to blue at electrode potentials of 0.87 and 1.24 V, respectively. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3245–3256, 2005 相似文献
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Shimin Zhang Jingkun Xu Baoyang Lu Leiqiang Qin Long Zhang Shijie Zhen Daize Mo 《Journal of polymer science. Part A, Polymer chemistry》2014,52(14):1989-1999
2‐((2,3‐Dihydrothieno[3,4‐b]dioxin‐2‐yl)methoxy)methyl oxirane (EDOT‐MO) was successfully synthesized by the reaction of epichlorohydrin with hydroxymethylated‐3,4‐ethylenedioxylthiophene (EDOT‐MeOH), which was synthesized via a simple four‐step sequence. Poly(hydroxymethylated‐3,4‐ethylenedioxylthiophene) (PEDOT‐MeOH) and poly(2‐((2,3‐dihydrothieno[3,4‐b]dioxin‐2‐yl)methoxy)methyl oxirane) (PEDOT‐MO) were electrosynthesized through electropolymerization of EDOT‐MeOH and EDOT‐MO, respectively. Structural, electrochemical, optical, and thermal properties of as‐formed polymers were investigated by FTIR, cyclic voltammetry, UV–vis, and thermogravimetry. Spectroelectrochemistry studies demonstrated that PEDOT‐MeOH and PEDOT‐MO could be reversibly oxidized and reduced accompany with obvious color changes. Further kinetic studies demonstrated that the introduction of hydroxymethyl or ethylene oxide group significantly improved electrochromic properties of 3,4‐ethylenedioxythiophene (PEDOT) and resulted in high contrast ratios (57.3% at 585 nm) and coloration efficiencies (338.5 cm2 C?1), low switching voltages, and fast response time. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1989–1999 相似文献