Photochemical Ionic-Conductivity Switching Systems of Photochromic Crown Ethers for Information Technology

Design of two types of ion-conducting systems using photochromic crown ethers as the photocontrol agents is described; one type is based on the phase transition of azobenzene derivatives induced by their photoisomerization and the other based on the molecular control of metal ion complexation by crowned spirobenzopyrans. The photoresponsive ion-conducting systems are applicable to electrostatic imaging and photorefractive materials.     

Photochromic chiral liquid crystalline systems containing spiro-oxazine with a chiral substituent I. Synthesis and characterization of compounds

Photochromic acrylates containing both biphenylene and spiro-oxazine moieties with a chiral substituent and the related polymers were prepared and yielded photochromic chiral liquid crystalline systems. The photochromic acrylates containing both an undecamethylene group and a (2S, 3S)-2-chloro-3-methylpentanoyloxy group (A11SOP) or a (-)-menthoxyacetoxy group (A11SOM) gave a supercooled mesophase; the latter reflected right-handed visible light (blue colour) at room temperature. On the other hand, the photochromic acrylate containing both the (R)-(-)-2-methylpropylene and (2S, 3S)-2-chloro-3-methylpentanoyloxy groups (A3SOP) showed no mesophase. The related homopolymers, PA11SOP and PA11SOM, did not exhibit mesophases because of steric hindrance between the side groups of the polymers. However, only PA11SOM exhibited shear-induced birefringence under 100-104°C. Several copolymers consisting of the nematogenic monomer, 4-[4-(6-acryloyloxyhexyloxy)benzoyloxy]benzonitrile (A6CN), and A11SOP or A11SOM possessed a smectic phase due to reduction of the steric hindrance between the potentially smectogenic A11SOP or A11SOM moieties.     

利用Ce∶KNSBN光折变晶体提高光学图像相关模式识别鉴别率

给出了在相干匹配滤波系统中利用Ce∶KNSBN光折变晶体非线性特性实现图像边缘增强光学相关模式识别的理论分析和实验结果。实验中自相关峰半最大值宽度降低了 75 % ,自相关峰与互相关峰的强度比增强了近一倍 ,自相关峰的边瓣强度和互相关峰的强度得到抑制 ,系统的信噪比和相关鉴别率得到显著提高     

Optical and Photoelectric Inhomogeneity of CdTe:V Crystals

The optical and photoelectric properties of CdTe:V crystals with the doping impurity concentration N _V = 5·10¹⁸–5·10¹⁹ cm^–3 are investigated and the possibility of their use as a photorefractive material is considered. As is seen from the spectra of optical transmission, the crystals of both types possess high transparency (50–65%), which for CdTe:V specimens with N _V = 5·10¹⁹ cm^–3 decreases sharply and in the range 12–14 m does not exceed 5%, whereas for CdTe:V crystals with vanadium concentration of 5·10¹⁸ cm^–3 such a value of transmission remains unchanged up to 25 m, implying a good optical quality of the latter crystals and their possible application in the spectral range 1.06–1.25 m in modern fiber-optic communication lines.     

载氢光纤在255.3nm激光辐照下的光折变效应

首次报道采用铜蒸气倍频２５５．３ｎｍ紫外激光辐照载氢光纤产生的光折变效应。所测到的光折变量已可满足制作光折变光纤光栅的需要。     

掺杂有机给体与受体分子的向列相液晶的光折变研究

制备了一种掺杂有机给体和受体分子的向列相液晶（nematic liquid crystals）材料。参数的给体和受体分子使液晶材料的光折变性能大为提高。用此材料做成的夹心器件进行了能量二波耦合，简单并四波混频等实验。在外加低直流电场（0．5KV/cm)条件下，观察到了光折变增益Γ为441cm^-1，二波能量耦合实验中观察到的衍射光束达到6级，简并四波混频中最大衍射效率达到58％，写入混合材料的信号光栅已可保存数小时而无明显衰减。     

Investigations of dynamic photorefractivity regime by optical polarizing microscopy

We present a technique, based on optical polarizing microscopy, and results of direct observation of the optical interference field effect on the transient domains excited by ac electric field in a nematic planar cell with photosensitive aligning layers. The light source used in a microscope operated in DC mode as well as in triggered pulse one. Obtained microscopic snapshots of transient domain structure confirmed our assumption of the transient domains reordering (trapping) by the low intensity optical interference field.     

Enhanced performance of photorefractive poly(N‐vinyl carbazole) composites

We present the enhanced photorefractive performance of high molecular weight poly(N‐vinyl carbazole) (PVCz)‐based composites. Higher diffraction efficiency with faster speed of grating build‐up was obtained by optimizing the composition of the PVCz composites. At relatively low applied electric field of E = 45 V μm^?1, diffraction efficiency of 26% for p‐polarized probe beam and corresponding that of 5.1% for s‐polarized probe beam were measured with faster grating build‐up speed of 48.3 s^?1 for the composite with 2,4,7‐trinitrofluorenone (TNF) as a sensitizer. Fastest speed of grating build‐up of 100 s^?1 and large optical gain up to 110 cm^?1 were measured at E = 80 V μm^?1 for the composite with fullerene derivative of PCBM as a sensitizer. These improved performances are due to a large orientational enhancement effect with faster response speed in addition to Pockels effect for the samples with appropriate glass transition temperature. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011