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1.
赵志伟 《光谱学与光谱分析》2002,22(6):895-897
在化学发光分析中,常常要用到碱性条件下鲁米诺与过氧化氢的反应系统,通过催化剂辣根过氧化物酶使反应顺利进行。如果再加入适当的增强剂,则灵敏度提高且发光时间延长,可改善测定的重现性。实验证明,对位酚类衍生物,如:对叔丁基苯酚,对甲苯酚的发光增强作用明显,其发光效率可上升几十倍,发光时间也获得有效延长。 相似文献
2.
Alison L. Parry 《Journal of polymer science. Part A, Polymer chemistry》2007,45(15):3178-3190
The ring‐opening metathesis polymerizations (ROMP), using RuCl2 (PCy3)2CHPh, of a series of peptide‐functionalized norbornene derivatives have been investigated. Incorporation of a PEG‐monomer was found to prevent premature precipitation of polymer strands during the course of polymerization reactions and yield water compatible polymers in high conversions. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3178–3190, 2007 相似文献
3.
4.
James V. Crivello Umut Bulut 《Journal of polymer science. Part A, Polymer chemistry》2005,43(21):5217-5231
Curcumin, a naturally occurring, intensely yellow dye extracted from the spice turmeric, is an efficient photosensitizer for diaryliodonium salt photoinitiators at wavelengths ranging from 340 to 535 nm. With curcumin as a photosensitizer, it is possible to carry out the cationic photopolymerization of a wide variety of epoxide, oxetane, and vinyl monomers with long‐wavelength UV and visible light. An example of the photopolymerization of an epoxide monomer with ambient solar irradiation is provided. Several other curcumin analogues were synthesized, and their use as photosensitizers is examined. With such photosensitizers, the range of spectral sensitivity can be extended well into the visible region of the electromagnetic spectrum. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5217–5231, 2005 相似文献
5.
Hiroshi Ito Masaki Okazaki Dolores C. Miller 《Journal of polymer science. Part A, Polymer chemistry》2004,42(6):1478-1505
Radical copolymerizations of electron‐deficient 2‐trifluoromethylacrylic (TFMA) monomers, such as 2‐trifluoromethylacrylic acid and t‐butyl 2‐trifluoromethylacrylate (TBTFMA), with electron‐rich norbornene derivatives and vinyl ethers with 2,2′‐azobisisobutyronitrile as the initiator were investigated in detail through the analysis of the kinetics in situ with 1H NMR and through the determination of the monomer reactivity ratios. The norbornene derivatives used in this study included bicyclo[2.2.1]hept‐2‐ene (norbornene) and 5‐(2‐trifluoromethyl‐1,1,1‐trifluoro‐2‐hydroxylpropyl)‐2‐norbornene. The vinyl ether monomers were ethyl vinyl ether, t‐butyl vinyl ether, and 3,4‐dihydro‐2‐H‐pyran. Vinylene carbonate was found to copolymerize with TBTFMA. Although none of the monomers underwent radical homopolymerization under normal conditions, they copolymerized readily, producing a copolymer containing 60–70 mol % TFMA. The copolymerization of the TFMA monomer with norbornenes and vinyl ethers deviated from the terminal model and could be described by the penultimate model. The copolymers of TFMA reported in this article were evaluated as chemical amplification resist polymers for the emerging field of 157‐nm lithography. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1478–1505, 2004 相似文献
6.
A convergent synthesis of the key synthetic intermediate of hemibrevetoxin B was achieved via the intramolecular allylation of an α-chloroacetoxy ether and subsequent ring-closing metathesis. 相似文献
7.
取代对苯二酚醚化物的合成研究 总被引:2,自引:0,他引:2
本文从取代的对苯三酚3出发、利用Williamson醚化反应合成了一系列它的醚化产物4a-4H,给出了它们的核磁共振数据(氢谱和碳谱)。讨论了影响醚化反应的一些因素,比较了不同烷化剂发生醚化反应的活泼性。 相似文献
8.
Boena N. Kolarz Maria Wojaczyska Jan Kaczmarczyk Teresa Siemieniewska Kazimierz Tomkw 《Journal of Polymer Science.Polymer Physics》1994,32(12):1977-1990
Sulfonic cation exchangers with two ion exchange group concentrations (0.5 and 2.4 mmol/g, samples A and B, respectively) were obtained by sulfonation of a porous styrene (S) and divinylbenzene (DVB) copolymer with chlorosulfonic acid. Strong thermal decomposition of the sulfonated copolymer A, accompanied by significant changes in its porous structure, starts at ca. 400°C. The char has no sulfonic groups. After heat treatment at 400°C in steam, a sorbent was obtained (yield 65%) that shows higher phenol sorption than the untreated sample when related to the bed volume. The chlorosulfonic derivatives of the initial copolymer were less thermally resistant than the sulfonic ones obtained by hydrolysis. Pyrolysis of the cation exchanger B, in its H+ and Ca2+ forms, was carried out at 900°C (yield of both chars close to 30%). By subsequent steam activation at 800°C to a 50% burn-off of the char, sorbents with well-developed, but distinctly different, porous structures were obtained. The activated char from the sulfonated copolymer in its hydrogen form was highly microporous and indicated an effective surface area of 1180 m2/g. However, because of a low contribution of mesopores, its ability to adsorb phenol from the liquid phase was not very high. The activated char from the calcium-doped copolymer, indicating a smaller surface area (580 m2/g) but characterized by a well-developed mesoporosity, was a better sorbent for phenol. © 1994 John Wiley & Sons, Inc. 相似文献
9.
Huseyin Bekir Yildiz Jaime Castillo Dmitrii A. Guschin Levent Toppare Wolfgang Schuhmann 《Mikrochimica acta》2007,159(1-2):27-34
An amperometric biosensor for the detection of phenolic compounds was developed based on the immobilization of tyrosinase
within an Os-complex functionalized electrodeposition polymer. Integration of tyrosinase within the redox polymer assures
efficient catechol recycling between the enzyme and the polymer bound redox sites. The non-manual immobilization procedure
improves the reproducibility of fabrication process, greatly reduces the desorption of the enzyme from the immobilization
layer, and, most importantly prevents fast inactivation of the enzyme by its substrate due to fast redox cycling.
A two-layer sensor architecture was developed involving ascorbic acid oxidase entrapped within an electrodeposition polymer
in a second layer on top of the redox polymer/tyrosinase layer. Using this sensor architecture it was possible to eliminate
the current interference arising from direct ascorbate oxidation up to a concentration of 630 μM ascorbic acid. The effects
of the polymer thickness, the enzyme/polymer ratio, and the applied potential were evaluated with respect to optimal sensor
properties. The sensitivity of the optimized sensors for catechol was 6.1 nA μM−1 with a detection limit of 10 nM, and for phenol 0.15 nA μM−1 with a detection limit of 100 nM. 相似文献
10.
We wish to report synthesis of perfluorinated functionalized, branched ethers from their hydrocarbon analogues by direct fluorination. Yields up to 90%, with high purities, have been obtained at ambient temperature and pressure. This technique will likely develop into a new general method for producing perfluorinated, hyperbranched and dendritic polymers. 相似文献