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《Angewandte Chemie (International ed. in English)》2017,56(19):5237-5241
Nanoscale carbon‐rich molecular architectures are not only aesthetically appealing but also of practical importance for energy and biomedical technologies. Herein, we report the synthesis of cyclic‐oligophenylene‐based nanopropeller 1 by using an efficient synthon strategy involving sequential intramolecular bisboronate homocoupling and reductive aromatization by H2SnCl4. The nanopropeller molecules pack into a layered hexagonal lattice featuring long‐ranged nano‐sized channels and a total guest‐accessible volume of 48 %, as revealed by X‐ray diffraction studies. We suggest that such a solid‐state arrangement is determined by the interplay between the propeller architecture and the intermolecular van der Waals interactions. 相似文献
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Loredana Vacareanu Oana Iuliana Negru Mircea Grigoras 《Journal of polymer science. Part A, Polymer chemistry》2018,56(22):2565-2573
A simple method for synthesis of polymers containing shape persistent imine macrocycles as nanohoops in the main chain is studied. It is based on the cyclocondensation reaction carried out in solution and room temperature of triphenylamine-based tetraaldehyde compounds with (R,R)-trans-1,2-diaminocyclohexane. The pristine polymer P1 bearing long alkyl groups is soluble during the synthesis but becomes insoluble after precipitation due to the strong and multiple C H/π and π-π stacking intermolecular interactions from arene–arene species and entanglement and interpenetrating of flexible alkyl groups inside of rigid macrocycle hollow. Polymer without any solubilizing groups ( P2 ) separates during the polymerization as an insoluble material. Both polymers are amorphous and have good thermal and environmental stability. They have a low surface area because discrete nanovoids introduced by macrocycles are disconnected in the amorphous polymers and non-accessible for gas adsorption. Polymers have inherent luminescent properties due to triphenylamine groups and chirality derived from (R,R)-conformation of the cyclohexane skeleton. In presence of picric acid (PA), the polymer fluorescence in solid state or suspension is strongly quenched, thus the polymers can work as efficient fluorescent probes toward nitrophenolic compounds. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 2565–2573 相似文献
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