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1.
A string of four new hetero binuclear Ru(III) complexes of ferrocenecarboxaldehyde-4(N)-substituted thiosemicarbazones were synthesized and characterized by various spectral (infrared, ultraviolet–visible, Electron Paramagnetic Resonance (EPR) and High Resolution Mass Spectrometry (HR-MS) techniques. The binding abilities of the ligands/complexes with nucleic acid (calf thymus DNA, CT-DNA) and bovine serum albumin (BSA) were analyzed by absorption and emission titration methods. The complexes exhibited better DNA binding affinity than their parent ligands. The interaction with CT-DNA was found to be intercalative and with BSA static quenching mechanism was observed. All the synthesized Ru(III) complexes were subjected to study their in vitro cytotoxicity against MCF-7 (human breast cancer) and HT-29 (human colon cancer) cell lines. Among the four complexes, complex 3 [RuCp (FF-etsc)PPh3]Cl exhibited the highest cytotoxicity in MCF-7 cells and complex 4 [RuCp (FF-ptsc)PPh3]Cl was the most active on HT-29 cells. 相似文献
2.
Artūras Dubickas 《Proceedings Mathematical Sciences》2005,115(4):391-397
Suppose that α > 1 is an algebraic number and ξ > 0 is a real number. We prove that the sequence of fractional partsξα
n
, n = 1, 2, 3, …, has infinitely many limit points except when α is a PV-number and ξ ∈ ℚ(α). For ξ = 1 and α being a rational
non-integer number, this result was proved by Vijayaraghavan. 相似文献
3.
Nikolaos S. PAPAGEORGIOU Nikolaos YANNAKAKIS 《数学学报(英文版)》2005,21(5):977-996
This is the first part of a work on second order nonlinear, nonmonotone evolution inclusions defined in the framework of an evolution triple of spaces and with a multivalued nonlinearity depending on both x(t) and x(t). In this first part we prove existence and relaxation theorems. We consider the case of an usc, convex valued nonlinearity and we show that for this problem the solution set is nonempty and compact in C^1 (T, H). Also we examine the Isc, nonconvex case and again we prove the existence of solutions. In addition we establish the existence of extremal solutions and by strengthening our hypotheses, we show that the extremal solutions are dense in C^1 (T, H) to the solutions of the original convex problem (strong relaxation). An example of a nonlinear hyperbolic optimal control problem is also discussed. 相似文献
4.
Archana Devi 《European Polymer Journal》2007,43(6):2422-2432
Cardanol-based novolac-type phenolic resins were synthesized with different mole ratios of cardanol-to-formaldehyde, viz., 1:0.6, 1:0.7, and 1:0.8. These novolac resins were epoxidized with molar excess of epichlorohydrin at 120 °C in basic medium. The epoxidized novolac resins were, separately, blended with different weight ratios of carboxyl-terminated polybutadiene liquid rubber ranging between 0-25 wt% with an interval of 5 wt%. All the blends were cured at 150 °C with 40 wt% polyamide. The formation of various products during the curing of blend samples has been studied by Fourier-transform infra-red spectroscopic analysis. The tensile strength and elongation-at-break of the cured samples increased up to 15 wt% in the blend and decreased thereafter. This blend sample was also found to be most thermally stable system. The blend morphology, studied by scanning electron microscopy analysis, was finally correlated with the structural and property changes in the blends. 相似文献
5.
6.
弹性体型聚氨酯和聚碳酸酯共混物的形态结构 总被引:1,自引:0,他引:1
用DSC、WAXD和SAXS研究了溶液共混的弹性体型聚氨酯(PU)/聚碳酸酯(PC)共混物的结构。结果表明,PU/PC为部分相容体系;共混过程中,溶剂DMF的诱导作用使PC形成结晶,其长周期与PU硬段形成微相的长周期相近 相似文献
7.
本文研究分数扩散过程和其分部积分公式的关系.首先利用Bismut方法给出拉回公式,进而得到分数扩散过程的分部积分公式。反过来,证明了分数扩散过程可由其分部积分公式唯一刻画. 相似文献
8.
Sesquiterpenoids from Chloranthus spicatus (Thunb.) Makino 总被引:2,自引:0,他引:2
Two new sesquiterpenoids, namely 1β,4β-dihydroxy-5 α,8β(H)-eudesm-7(11)Z-en-8,12-olide (1) and 1β,4α-dihydroxy-5α,8β(H)-eudesm-7(11)Z-en-8,12-olide (2), along with six known ones, homalomenol A (3), oplodiol (4), 5α,7α(H)-6,8-cycloeudesma-1β,4β-diol (5), oplopanone (6), 4β,10α-dihydroxyaromadendrane (7) and spathulenol (8), were isolated from the aerial part of Chloranthus spicatus (Thunb.) Makino, and their structures were established by spectroscopic methods. 相似文献
9.
Iwan Jerjen Vincent Revol Andreas J. Brunner Philipp Schuetz Christian Kottler Rolf Kaufmann Thomas Luethi Giovanni Nicoletti Claus Urban Urs Sennhauser 《Polymer Testing》2013
The processing of thermoplastics can induce a wide range of defects such as stress whitening, cavitation and porosity, which can adversely affect the reliability of the final products. Hence, fast and effective non-destructive detection methods for such defects are highly important for quality assurance on production lines. In this paper, X-ray dark field imaging is presented as a new non-destructive testing method that allows the visualization of stress whitening or cavitation efficiently. The performance of the method is demonstrated for the case of an injection-moulded polyvinylidene fluoride part that exhibits stress whitening. Whereas the stress whitening could not be detected by conventional X-ray imaging, it was localized by an X-ray dark field image acquired within a few minutes. Once the precise location of the stress whitening was known, it was possible to verify the result by local micro X-ray computed tomography and by a micro section image. 相似文献
10.
The extraction of vein traits from venation networks is of great significance to the development of a variety of research fields, such as evolutionary biology. However, traditional studies normally target to the extraction of reticulate structure traits (ReSTs), which is not sufficient enough to distinguish the difference between vein orders. For hierarchical structure traits (HiSTs), only a few tools have made attempts with human assistance, and obviously are not practical for large-scale traits extraction. Thus, there is a necessity to develop the method of automated vein hierarchy classification, raising a new challenge yet to be addressed. We propose a novel vein hierarchy classification method based on directional morphological filtering to automatically classify vein orders. Different from traditional methods, our method classify vein orders from highly dense venation networks for the extraction of traits with ecological significance. To the best of our knowledge, this is the first attempt to automatically classify vein hierarchy. To evaluate the performance of our method, we prepare a soybean transmission image dataset (STID) composed of 1200 soybean leaf images and the vein orders of these leaves are manually coarsely annotated by experts as ground truth. We apply our method to classify vein orders of each leaf in the dataset. Compared with ground truth, the proposed method achieves great performance, while the average deviation on major vein is less than 5 pixels and the average completeness on second-order veins reaches 54.28%. 相似文献