非平衡统计断裂力学基础

非平衡统计断裂力学是用非平衡统计概念和方法结合微裂纹(或微空洞)演化动力学从微观机理推导出宏观力学量的断裂理论.它以微裂纹演化方程为核心,结合从微观机理求得的微裂纹长大速率和成核率以及最小强度原理,统一导出微裂纹分布函数、断裂概率、可靠性、失效率、损伤断裂动力学方程、强度、韧度和寿命等各种与断裂有关的力学量的统计分布函数、统计平均值和统计涨落.本文理论可广泛适用于金属和结构陶瓷的脆性、疲劳、延时和环境断裂等多种断裂类型.本文通过金属的脆性、疲劳和延时断裂,扼要综述了上述主要思想、方法和结果.      

N,Co共掺杂锐钛矿相YiO2光催化剂的第一性原理研究

采用第一性原理平面波超软赝势方法研究了N,Co共掺杂锐钛矿相TiO2的微观结构和光学性质.结果表明:N,Co共掺杂后TiO2晶格中产生的偶极矩使光生电子-空穴对更有效地分离;在TiO2导带和价带之间形成了新的杂质能级,一方面使吸收带边红移到可见光区,光吸收性能明显增强,另一方面有利于光生电子-空穴对的分离,提高TiO2的光量子效率;与纯TiO2相比,N,Co共掺杂锐钛矿相TiO2带边的氧化还原势只有微小的变化,共掺杂后TiO2的强氧化还原能力得以保持.     

Influence of ageing on the low cycle fatigue behaviour of an Al–Mg–Si alloy

Abstract

The low cycle fatigue (LCF) performance of AA6063 Al–Mg–Si alloy at under-aged (UA), peak-aged (PA) and over-aged (OA) conditions has been examined to understand the micromechanism of fatigue and the associated dynamic structural changes in this alloy. The LCF behaviour of the differently aged AA6063 alloys has been studied at strain amplitudes ranging between 0.2 and 1.0% under strain control mode. The UA state exhibits pronounced cyclic hardening unlike the PA and the OA states at strain amplitudes greater than 0.4%. The PA and the OA states show hardening only for a few cycles followed by prolonged softening. Characterisations of the micro- and the sub-structural alterations due to LCF establish that the phenomenon of dynamic precipitation results in cyclic hardening the UA alloy. The softening of PA alloy occurs due to shearing of precipitates and that in the OA alloy takes place owing to reversibility of slip by the formation and annihilation of the Orowan loops around the β (Mg₂Si) precipitates. Analyses of the hysteresis loops reveal Masing, nearly-Masing and non-Masing behaviour in the UA, OA and PA states, respectively. Analyses of the asymmetry factor of the hysteresis loops assist to infer that the Masing behaviour in the UA alloy is due to dislocation–dislocation interactions, whereas the nearly-Masing behaviour in the OA alloy and the non-Masing behaviour in the PA alloy are the consequence of varying degrees of dislocation–precipitate interactions associated with inhomogeneous deformation.     

金属材料蠕变的微观热力学机理及本构方程的研究

蠕变是金属材料的重要现象，其机理及本构方程的研究则是其重要的研究领域。虽然这方面工作已为数颇多，但迄今尚难以与实验有较好的吻合。本文在综合前人各种蠕变机理的基础上，提出金属材料蠕变的热力学机理，并进而推导出蠕变的本构方程及里面变量应力和温度所满足的约束条件。其数值结果与试验较为一致。     

NUCLEATION AND GROWTH ACTIVATION ENERGIES DURING CRYSTALLIZATION OF AMORPHOUS ALLOYS (Ⅱ)——RELATIONSHIP BETWEEN MICROSTFUCTURE OF AMORPHOUS STATE AND TEMPERATURE

By using the new method for determination of activation energies for nucleation andgrowth (E_n & E_g) developed in Part Ⅰ of this work, the E_n and E_g of some pre--annealedamorphous Ni--P alloys, as well as those of the as--quenched Ni--P glass within differenttemperature ranges are measured and studied. The results show that the values of E_n and E_gare closely related to the microstructure of amorphous alloys and the annealing temperature.The higher the ordering in the amorphous alloys, the smaller the values of E_n and E_g; thehigher the annealing temperature, the greater the E_n and E_g values. By means of the newlydeveloped crystallization micromechanism, such an experimental phenomenon which is diffi-cult to understand from the classical crystallization mechanism is reasonably explained.     

Morphology and micromechanical behaviour of styrene/butadiene block copolymers and their blends with polystyrene

The correlation between the morphology and the deformation mechanism in styrene/butadiene block copolymers having modified architecture and in blends with homopolymer polystyrene (hPS) was studied. It was demonstrated that the morphology formation in the block copolymers is highly coupled with their molecular architecture. In particular, the micromechanical behaviour of a star block copolymer and its blends with polystyrene was investigated by using electron microscopy and tensile testing. A homogeneous plastic flow of polystyrene lamellae (thin layer yielding) was observed if the lamella thickness was in the range of 20 nm. The deformation micromechanism switched to the formation of craze-like deformation zones when the average PS lamella thickness changed to about 30 nm and more.