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1.
Prof. Dr. Yoshio Teki 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(5):980-996
Recently, the potential use of organic π-radicals and related spin systems has been expanded to modern technological applications. The unique excited-state dynamics of organic π-radicals can be useful to improve the stability of photochemically unstable organic compounds, make the polarization transfer applicable to information technology, and achieve effective up-conversion of interest for luminescence bioimaging, among others. Furthermore, highly luminescent stable π-radicals have been recently reported, which are especially interesting for application in organic light-emitting devices owing to their potential to provide an internal quantum efficiency of 100 %. Thus, the excited-state nature of stable π-radicals as well as the control of their excited-state spin dynamics are emerging topics both in terms of fundamental science and related technological applications. In this minireview, we focus on the excited-state dynamics of both photostable non(weakly)-luminescent and luminescent π-radicals, which are opposites of each other. In particular, we cover the following topics: 1) effective generation of high-spin photoexcited states and control of the excited-state dynamics by using non-luminescent π-radicals, 2) unique excited-state dynamics of luminescent π-radicals and radical excimers, and 3) applications utilizing excited-state dynamics of π-radicals. 相似文献
2.
Two new divalent copper (C1) and zinc (C2) chelates having the formulae [M(PIMC)2] (where M = Cu(II), Zn(II) and PIMC = Ligand [(E)-3-(((3-hydroxypyridin-2-yl)imino)methyl)-4H-chromen-4-one] were obtained and characterized by several techniques. Structures and geometries of the synthesized complexes were judged based on the results of alternative analytical and spectral tools supporting the proposed formulae. IR spectral data confirmed the coordination of the ligands to the copper and zinc centers as monobasic tridentate in the enol form. Thermal analysis, UV-Vis spectra and magnetic moment confirmed the geometry around the copper center to be tetrahedral, square pyramidal and octahedral. Study of the binding ability of the synthesized compounds with Circulating tumor DNA (CT-DNA) bas been evaluated applying UV-Vis spectral titration and viscosity measurements. The copper and zinc oxides were achieved from the copper and zinc nano-particles structures Schiff base complexes as the raw material after calcination for 5 hr at 600°C. On the other hand, synthesized of C1 and C2 NPs were used as suitable precursors to the preparation of CuO and ZnO NPs. Finally, the synthesized of the two complexes exhibited enhanced activity against the tested bacterial (Staphylococcus aureus and Escherichia Coli) and fungal strains (Candida albicans and Aspergillus fumigatus) as compared to HPIMC. Among all these synthesized compounds, C1 exhibits good cleaving ability compared to other newly synthesized C2. 相似文献
3.
采用固相法在较低温度下合成了Eu2+激活的Ca2SiO3Cl2高亮度蓝白色发光材料,并对其发光性质进行了研究。其发射光谱由两个谱带组成,峰值分别位于420,498nm处,归结为Ca2SiO3Cl2晶体中占据两种不同Ca2+格位的Eu2+离子的5d→4f跃迁发射。改变Eu2+浓度,可以使样品的发光在蓝白色和绿白色之间变化。当Eu2+浓度为0.005mol-1时,样品呈现很亮的蓝白色发光。两个发射峰的激发光谱均分布在250~410nm的波长范围内,峰值分别位于333,369nm处。Ca2SiO3Cl2:Eu2+可被InGaN管芯产生的近紫外辐射有效激发,是一种性能良好的白光LED用单一基质蓝白色荧光粉。 相似文献
4.
The room temperature structure of perovskite CeAlO3 has been reinvestigated by X-ray powder diffraction. The Rietveld refinement has confirmed the tetragonal symmetry; but revealed a super cell, a=5.32489(6) Å and c=7.58976(10) Å, with the space group I4/mcm. In CeAlO3, the distortion from the ideal cubic perovskite is caused by the cooperative tilting of the AlO6 octahedra around the primitive cubic [001]p-axis. 相似文献
5.
Bi12TiO20纳米粉体的制备及其光吸收特性研究 总被引:3,自引:0,他引:3
以钛酸四丁酯和硝酸铋为原料 ,利用化学溶液分解法制备了Bi12 TiO2 0 纳米多晶粉体 .采用XRD和TEM对其结构和形貌进行了表征 .结合热重 差热 (TG DTA)分析 ,探讨了Bi12 TiO2 0 晶相的形成机理 .通过UV Vis漫反射谱的测定 ,研究了Bi12 TiO2 0 纳米晶粉体的光吸收特性 .结果显示 ,从组成为化学计量比的前驱液中可以很容易制得纯Bi12 TiO2 0 纳米晶粉体 ,该Bi12 TiO2 0 纳米晶粉体呈现了在很宽的波长范围内 (5 6 0~ 385nm )对光的吸收的特性 . 相似文献
6.
This paper deals with a computational analysis of the influence of the pressing method and part geometry on the final density
distribution in the cold compaction process of ceramic alumina powders. The analysis is based on the explicit finite-element
model proposed and validated in a previous study. The mechanical behavior of the processing material is described using a
multisurface elastoplastic model, the modified Drucker-Prager/Cap model
Published in Prikladnaya Mekhanika, Vol. 43, No. 10, pp. 129–134, October 2007. 相似文献
7.
8.
纳米累托石-TiO2光催化剂的制备及表征 总被引:1,自引:1,他引:0
以TiCl4和累托石为主要原料,制备出纳米累托石-TiO2粉末,并用X-衍射、透射电镜等对其进行表征.结果表明:纳米累托石-TiO2粉末平均直径为17.5nm当焙烧温度从500℃升至800℃时,累托石-TiO2粉末的比表面积从65.7m^2/g下降至3.3m^2/g,单位质量吸附剂的孔体积从0.1430cm。/u降到0.0213cm^3/g;当焙烧温度从300℃上升至500℃时,孔径变化不大,属中孔范围;当焙烧温度升至800℃时,一些孔道出现坍塌,不利于纳米累托石-TiO2粉末的光催化活性. 相似文献
9.
WANG Jiang-yun GU Wen WANG Wen-zhen LIU Xin LIAO Dai-zheng 《高等学校化学研究》2006,22(3):283-286
Introduction Itiswell knownthatcyanogroupsincyanometa latessuchas[Ag(CN)2]-unitscanbeusedasbridg ingligandsandapolymericstructurecanbeformed throughsilver silver(argentophilic)interactions.This propertyhasbeenexploredintheconstructionofmany oligomericandp… 相似文献
10.
研究了充有不同温度退火Fe基纳米晶粉芯LC回路的磁致频移特性(MFS),发现充有不同温度退火Fe基纳米晶粉芯LC回路的磁致频移不同,充有经600℃退火Fe基纳米晶粉芯LC回路的磁致频移最灵敏。 相似文献