Studies on basicity of alkali metal catron exchanged β and X zeolites by pyrrole-IR spectroscopy

The strength of basic sites has been measured by pyrrole-IR on alkali metal cation exchanged β and X zeolites, as well as NaOH loaded Naβ. The influence of cation type and the structure of zeolites on their basicity has been studied. The acidic and basic properties of the samples were investigated by NH3-TPD and isopropanol reaction. It was shown that the strength of basic sites on samples could be characterized by the shift of vNH band in the pyrrole-IR spectra. The framework oxygen charges were calculated from the Sanderson electronegativity. The changes in basic properties with various alkali metal cation are consistent with the changes of local oxygen charges of the zeolite framework.     

Dissociative excitation cross sections of the lead atom in collisions between electrons and PbI2 molecules

Dissociative excitation of the lead atom in e-PbI₂ collisions has been studied experimentally. 27 excitation cross sections were measured for an energy of the exciting electrons equal to 100 eV. Nine optical excitation functions were recorded with variation of the electron energy in the range 0–100 eV. The most probable reaction channels for low electron energies are discussed, as well as the ratio of the dissociative excitation cross sections for the lead atom in e-PbI₂ and e-PbCl₂ collisions. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 6, pp. 701–706, November–December, 2006.     

Radiochemical proton activation analysis for the determination of cadmium and lead in sediment reference materials

Proton activation analysis was used for the determination of cadmium and lead in three sediment reference materials. The method is based on the^111,112Cd(p, xn)¹¹¹ In and the^206,207,208Pb(p, xn)²⁰⁶Bi reactions.¹¹¹In and²⁰⁶Bi were chemically separated by anion exchange. The results obtained were taken into account for the certification of the materials and are in the excellent agreement with the certified values.     

The synthesis of azo compounds from nitro compounds using lead and triethylammonium formate

Aromatic nitro compounds were reduced to the corresponding symmetrically substituted azo compounds using lead as catalyst and triethylammonium formate as hydrogen donor. Various azo compounds containing additional reducible substituents including halogens, nitrile, acid, phenol, ester, methoxy functions, etc, have been synthesized in a single step by the use of this reagent. The conversion is reasonably fast, clean, high yielding and occurs at room temperature in methanol.     

EFFICIENT SIXTH ORDER P-STABLE METHODS WITH MINIMAL LOCAL TRUNCATION ERROR FOR y"=f(x,y)

1. IntroductionWe consider a class of direct hybrid methods proposed in [11 for solving the second orderinitial value problemy" = f(t,y), y(0),y'(0) given (1.1)The basic method has the formandHere t. = nh and we define t.l.. = t. I aih, i = 1, 2 and n=0,1…     

Preparation of Phosphoric-Carboxylic Cation Exchangers from Wood Cellulose

Phosphorus-containing cellulose cation exchangers were synthesized by reaction of wood cellulose with orthophosphoric acid and the ternary polymer from glycidylmethacrylate, styrene, and maleic anhydride. The effects of the ratio of reactants, temperature, and duration of the reaction on the phosphorylation and exchange capacity of the modified cellulose material were studied.     

Hydrothermal Synthesis and Structure of [（PbCl2）μ-PyZ）1/2]n （Pyz = Pyrazine）

1 INTRODUCTION Because of the flexibility of Pb(II) coordination sphere and the nonstereospecific nature of halide anions[1], the chemistry of lead halide complexes has been developed in recent years. Especially PbX2- based coordination polymers with nitrogen-contain- ing Lewis bases have attracted renewed interest[2～11]. The choice of ligand and the reaction condition are of great importance in determining the final topo- logy of the supramolecular materials. But the avail- able struc…     

Crystallographic report: Bis(norfloxacin)dilead(II) tetranitrate, [Pb2(H‐Norf)2(ONO2)4]

The centrosymmetric binuclear structure of [Pb₂(H‐Norf)₂(ONO₂)₄]shows the geometry around each lead(II) atom to be distorted trigonal bipyramidal with Pb–O distances ranging from 2.357(3) to 2.769(4) Å. Copyright © 2003 John Wiley & Sons, Ltd.     

液态铅的电阻率

采用精确的结构因数实验数据和Ｂｅｈａｖｉ模型赝势，用Ｚｉｍａｎ理论计算了液态铅的电阻率．计算结果和实验数据符合很好．讨论了Ｚｉｍａｎ理论对液态铅的适用性以及适合于液态铅的赝势的特征．     

Precipitation and characterization of uniform submicrometer lead titanate particles. Part II: Reaction mechanism

The chemical mechanism of the precipitation of lead titanium peroxohydroxide particles in a solution of nitrilotriacetate (NTA) complexes of lead and titanium peroxo-hydroxide is envisioned as the interaction between cations of lead hydroxide and anions of polymeric titanium peroxo-hydroxide.