全文获取类型
收费全文 | 11076篇 |
免费 | 2337篇 |
国内免费 | 1091篇 |
专业分类
化学 | 7785篇 |
晶体学 | 87篇 |
力学 | 1188篇 |
综合类 | 56篇 |
数学 | 451篇 |
物理学 | 4937篇 |
出版年
2024年 | 22篇 |
2023年 | 127篇 |
2022年 | 259篇 |
2021年 | 281篇 |
2020年 | 409篇 |
2019年 | 408篇 |
2018年 | 448篇 |
2017年 | 412篇 |
2016年 | 507篇 |
2015年 | 573篇 |
2014年 | 782篇 |
2013年 | 1035篇 |
2012年 | 811篇 |
2011年 | 886篇 |
2010年 | 679篇 |
2009年 | 777篇 |
2008年 | 726篇 |
2007年 | 662篇 |
2006年 | 655篇 |
2005年 | 601篇 |
2004年 | 544篇 |
2003年 | 514篇 |
2002年 | 350篇 |
2001年 | 252篇 |
2000年 | 272篇 |
1999年 | 225篇 |
1998年 | 203篇 |
1997年 | 186篇 |
1996年 | 135篇 |
1995年 | 143篇 |
1994年 | 108篇 |
1993年 | 86篇 |
1992年 | 77篇 |
1991年 | 29篇 |
1990年 | 55篇 |
1989年 | 37篇 |
1988年 | 29篇 |
1987年 | 34篇 |
1986年 | 19篇 |
1985年 | 21篇 |
1984年 | 27篇 |
1982年 | 21篇 |
1981年 | 9篇 |
1980年 | 6篇 |
1979年 | 13篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1973年 | 6篇 |
1971年 | 5篇 |
1957年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Cavitation erosion is caused in solids exposed to strong pressure waves developing in an adjacent fluid field. The knowledge of the transient distribution of stresses in the solid is important to understand the cause of damaging by comparisons with breaking points of the material. The modeling of this problem requires the coupling of the models for the fluid and the solid. For this purpose, we use a strategy based on the solution of coupled Riemann problems that has been originally developed for the coupling of 2 fluids. This concept is exemplified for the coupling of a linear elastic structure with an ideal gas. The coupling procedure relies on the solution of a nonlinear equation. Existence and uniqueness of the solution is proven. The coupling conditions are validated by means of quasi‐1D problems for which an explicit solution can be determined. For a more realistic scenario, a 2D application is considered where in a compressible single fluid, a hot gas bubble at low pressure collapses in a cold gas at high pressure near an adjacent structure. 相似文献
2.
Nano palladium supported on high‐surface‐area metal–organic framework MIL‐101: an efficient catalyst for Sonogashira coupling of aryl and heteroaryl bromides with alkynes 下载免费PDF全文
Manne Annapurna T. Parsharamulu P. Vishnuvardhan Reddy M. Suresh Pravin R. Likhar Mannepalli Lakshmi Kantam 《应用有机金属化学》2015,29(4):234-239
Palladium nanoparticle‐incorporated metal–organic framework MIL‐101 (Pd/MIL‐101) was successfully synthesized and characterized using X‐ray diffraction, nitrogen physisorption, X‐ray photoelectron, UV–visible and infrared spectroscopies, and transmission electron microscopy. The characterization techniques confirmed high porosity and high surface area of MIL‐101 and high stability of nano‐size palladium particles. Pd/MIL‐101 nanocomposite was investigated for the Sonogashira cross‐coupling reaction of aryl and heteroaryl bromides with various alkynes under copper‐free conditions. The reusability of the catalyst was tested for up to four cycles without any significant loss in catalytic activity. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
3.
We study the full counting statistics of transport electrons through a semiconductor two-level quantum dot with Rashba spin–orbit (SO) coupling, which acts as a nonabelian gauge field and thus induces the electron transition between two levels along with the spin flip. By means of the quantum master equation approach, shot noise and skewness are obtained at finite temperature with two-body Coulomb interaction. We particularly demonstrate the crucial effect of SO coupling on the super-Poissonian fluctuation of transport electrons, in terms of which the SO coupling can be probed by the zero-frequency cumulants. While the charge currents are not sensitive to the SO coupling. 相似文献
4.
Single Crystal to Single Crystal (SC‐to‐SC) Transformation from a Nonporous to Porous Metal–Organic Framework and Its Application Potential in Gas Adsorption and Suzuki Coupling Reaction through Postmodification 下载免费PDF全文
Dr. Rupam Sen Debraj Saha Dr. Subratanath Koner Dr. Paula Brandão Dr. Zhi Lin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(15):5962-5971
A new amino‐functionalized strontium–carboxylate‐based metal–organic framework (MOF) has been synthesized that undergoes single crystal to single crystal (SC‐to‐SC) transformation upon desolvation. Both structures have been characterized by single‐crystal X‐ray analysis. The desolvated structure shows an interesting 3D porous structure with pendent ?NH2 groups inside the pore wall, whereas the solvated compound possesses a nonporous structure with DMF molecules on the metal centers. The amino group was postmodified through Schiff base condensation by pyridine‐2‐carboxaldehyde and palladium was anchored on that site. The modified framework has been utilized for the Suzuki cross‐coupling reaction. The compound shows high activity towards the C?C cross‐coupling reaction with good yields and turnover frequencies. Gas adsorption studies showed that the desolvated compound had permanent porosity and was microporous in nature with a BET surface area of 2052 m2 g?1. The material also possesses good CO2 (8 wt %) and H2 (1.87 wt %) adsorption capabilities. 相似文献
5.
In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation. 相似文献
6.
7.
Back Cover: Reactions of Group 4 Metallocenes with Monosubstituted Acetonitriles: Keteniminate Formation versus CC Coupling (Chem. Eur. J. 8/2015) 下载免费PDF全文
8.
9.
High-temperature series expansions of the susceptibility and second moment to 15th order are calculated for zero external field on the linear chain (LC), plane square (PSQ), simple cubic (SC), and body-centered cubic (BCC) lattices. Checks for specific models against pertinent work in the literature are detailed. 相似文献
10.
用经验赝势方法计算了体ZnSe以及ZnSe/GaAs单异质结系统中ZnSe外延层г、X、L等特殊对称点导带底能量随压力的变化。结果表明,同Si、Ge、GaAs等半导体材料不同,ZnSe的X点导带底具有正的压力系数,但比г点的压力系数小,这是ZnSe材料以及ZnSe基异质结构材料发生直接禁带向间接禁带的转变时所需转变压力较大的根本原因。研究了ZnSe/GaAs异质结构中晶格失配造成的应变对外延层г、X、L对称点压力系数的影响,表明这种晶格失配造成的应变可以极大地减小ZnSe外延层材料由直接禁带向间接禁带的转变压力。 相似文献