全文获取类型
收费全文 | 5499篇 |
免费 | 524篇 |
国内免费 | 526篇 |
专业分类
化学 | 3758篇 |
晶体学 | 82篇 |
力学 | 373篇 |
综合类 | 39篇 |
数学 | 710篇 |
物理学 | 1587篇 |
出版年
2024年 | 8篇 |
2023年 | 42篇 |
2022年 | 103篇 |
2021年 | 104篇 |
2020年 | 141篇 |
2019年 | 110篇 |
2018年 | 145篇 |
2017年 | 154篇 |
2016年 | 235篇 |
2015年 | 195篇 |
2014年 | 299篇 |
2013年 | 436篇 |
2012年 | 246篇 |
2011年 | 287篇 |
2010年 | 274篇 |
2009年 | 308篇 |
2008年 | 319篇 |
2007年 | 313篇 |
2006年 | 371篇 |
2005年 | 312篇 |
2004年 | 293篇 |
2003年 | 271篇 |
2002年 | 230篇 |
2001年 | 160篇 |
2000年 | 133篇 |
1999年 | 180篇 |
1998年 | 120篇 |
1997年 | 133篇 |
1996年 | 82篇 |
1995年 | 85篇 |
1994年 | 85篇 |
1993年 | 42篇 |
1992年 | 49篇 |
1991年 | 41篇 |
1990年 | 33篇 |
1989年 | 24篇 |
1988年 | 38篇 |
1987年 | 33篇 |
1986年 | 19篇 |
1985年 | 23篇 |
1984年 | 32篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 1篇 |
排序方式: 共有6549条查询结果,搜索用时 17 毫秒
1.
A simple scheme is developed for treatment of vertical bed topography in shallow water flows. The effect of the vertical step on flows is modelled with the shallow water equations including local energy loss terms. The bed elevation is denoted with zb‐ for the left and zb+ for the right values at each grid point, hence exactly representing a discontinuity in the bed topography. The surface gradient method (SGM) is generalized to reconstruct water depths at cell interfaces involving a vertical step so that the fluxes at the cell interfaces can accurately be calculated with a Riemann solver. The scheme is verified by predicting a surge crossing a step, a tidal flow over a step and dam‐break flows on wet/dry beds. The results have shown good agreements compared with analytical solutions and available experimental data. The scheme is efficient, robust, and may be used for practical flow calculations. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
2.
本文提出从高分辨电子显微像中,利用光学、全息和部分相干等方法,提取传递函数,制作相位和振幅滤波器,实现解卷,提高高分辨电子显微像的分辨率. 相似文献
3.
Katsunari Inoue Kazuaki Kato Norimitsu Tohnai Mikiji Miyata 《Journal of polymer science. Part A, Polymer chemistry》2004,42(18):4648-4655
We studied simulations by computer graphics to estimate the steric mechanism of the asymmetric polymerization of prochiral diene monomers in channels of inclusion compounds of steroidal bile acids, such as deoxycholic acid (DCA) and cholic acid. We applied a hierarchization method to interpret the crystal structures of bile acids, clarifying that the chiral host molecules associated to form characteristic 21-helical assemblies with uneven surfaces. A detailed analysis of the uneven channels in a close-packing state indicated that there were many possible arrangements of the monomers in the channels. The plausible arrangements in the channel could explain a previous study, which showed that the polymerization in the DCA channel yielded chiral polymers with a predominant configuration from prochiral diene monomers, such as 2-methyl-trans-1,3-pentadiene. On the basis of such simulation studies of the arrangements of guest monomers in the channel, we examined a plausible steric mechanism for asymmetric inclusion polymerization. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4648–4655, 2004 相似文献
4.
Thorsten Brand Kyle Ratinac Jeffrey V. Castro Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5706-5713
A method was developed for free‐radical polymerization in the confines of a hollow latex particle. Hollow particles were prepared via the dynamic swelling method from polystyrene seed and divinylbenzene and had hollows of 500–1000 nm. So that these hollow poly(divinylbenzene) particles could function as submicrometer reactors, the particles were filled with a monomer (N‐isopropylacrylamide) via the dispersion of the dried particles in the molten monomer. The monomer that was not contained in the hollows was removed by washing and gentle abrasion. Free‐radical polymerization was then initiated by γ radiolysis in the solid state. Transmission electron microscopy showed that poly(N‐isopropylacrylamide) formed in the hollow interior of the particles, which functioned as submicrometer reactors. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5706–5713, 2004 相似文献
5.
基于无穷维空间中的生存定理,我们研究了集值映象的不动点,得到了一个新的不动点定理,推广和改进了[1]和[5]中的相应结果。 相似文献
6.
Several α-ketoalcohols of synthetic value were resolved using lipase as a catalyst. Lipoprotein lipase (LPL) provided the best rate of hydrolysis and kinetic differentiation. One of these optically pure α-ketoalcohol was converted to (5)-ibuprofen in good optical purity. The stereospecific inversion of (R)-alcohol to (S)-alcohol is described. 相似文献
7.
In this paper, the deconvolution of SIMS profiles analysed at very low primary energy (0.5 keV/O2+) is addressed. The depth resolution function (DRF) of the SIMS analysis in presence of roughness is established and a deconvolution procedure is implemented without or in presence of roughness on samples containing delta-doped layers of boron in silicon. It is shown that the deconvolution procedure can lead to a great improvement of the full width at half maximum (FWHM) of the measured peaks in the case where no roughness in detected in the crater bottom. In the case where it is present, the conditions required to use a deconvolution procedure are discussed, and the deconvolution is implemented using precise and restrictive assumptions. 相似文献
8.
G. Gargaro F. Gasparrini D. Misiti G. Palmieri M. Pierini C. Villani 《Chromatographia》1987,24(1):505-509
Summary Enantiomers of several sulfoxides and some selenoxides can be easily separated by using a new chiral stationary phase (CSP-DACH-DNB)
containing the 3,5-dinitrobenzoyl derivative of R,R-(-)1,2-diamino-cyclohexane as selector, covalently bonded to the siliceous
matrix. The easy operative conditions and the high enantioselectivity values (α) allow a direct transfer of the analytical
separations to a semi-preparative and preparative scale. 相似文献
9.
10.
B. Satco 《Journal of Mathematical Analysis and Applications》2007,332(2):919-933
Existence theorems and some properties of solutions set of three boundary value second order differential equations and inclusions in Banach spaces are obtained under Henstock, respectively Henstock-Kurzweil-Pettis integrability assumptions. Our results extend those obtained by Azzam, Castaing and Thibault in the Bochner integrability setting and in the Pettis integrability one. The continuity of the (unique) solution with respect to a parameter in the single-valued case is also studied. 相似文献